Field sampling in the Hells Canyon Reservoir Complex, with Dr. M. Marvin-DiPasquale at the bow of the sediment collection boat. Photographer: D. Krabbenhoft.
Studies of contaminant biogeochemistry and microbial processes in surface sediments.
Ecosystem restoration research.
Studies of contaminant biogeochemistry and microbial processes in surface waters.
Laboratory approaches for quantifying microbial process rates and analyte concentrations.
Studies of contaminant biogeochemistry and microbial processes in wetland environments.
About the Research
The Microbial Biogeochemistry Laboratory Core Technology Team (CTT) as part of the Environmental Health Program focuses on environmental questions in aquatic systems (sediment and water) involving the linkages between major biogeochemical cycles (those involving carbon, sulfur, iron and nitrogen) and those associated with contaminants of concern.
The research interests and analytical capabilities of the Microbial Biogeochemistry Laboratory CTT bridge the intersection of fundamental microbial biogeochemistry and ecosystem contaminants science.
The mobility, transport, and chemical transformation of many contaminants in aquatic systems are ultimately mediated by microbial process, which are in turn mediated and defined by the availability of specific electron donors (such as various forms of organic carbon) and electron acceptors (such as oxygen, iron, manganese, nitrogen and sulfur).
The Microbial Biogeochemistry Laboratory has a long history of focusing on the intersection of microbial biogeochemistry and contaminants in mercury specific studies, in a wide range of aquatic systems (streams/rivers, wetlands, reservoirs, tidal estuaries and hypersaline salt ponds). In recent years their analytical capabilities have expanded to a much wider range of elements of concern (including Al, As, Cd, Cr, Cu, Fe, Mn, Pb, Se, U, and Zn) and energy production associated waste streams (oil and gas production wastewater, and coal mining regions).
Key Analytical Capabilities include:
- Measurement of microbial reaction rates using isotopic tracer methods
- Mercury speciation in a range of matrices
- Nutrients, anions/cations and trace elements
- Chemical speciation and quantification of major biogeochemical cycle constituents associated with carbon, sulfur, iron, and nitrogen
Key Instrumentation:
- Quadrupole Inductively coupled plasma mass spectrometer (ICP-MS)
- Ion, liquid and gas chromatography
- Total mercury analyzer
- Methylmercury analyzer
- Nutrient analyzer
- Chlorophyll analyzer
- Field fluorometry and other in-situ sensor technology
- Total carbon analyzer (with 13C isotopes)
Science Team Collaborators
-
Energy Integrated Science Team
The Energy Lifecycle Integrated Science Team focuses on the potential for contaminant exposures in the environment that might originate from energy resource activities including, extraction, production, transportation, storage, extraction, waste management and restoration. Perceived health risks to humans and other organisms will be distinguished from actual risks, if any. If actual risks are...Ecologically-Driven Exposure Pathways Science Team
The Ecologically-Driven Exposure Pathways Integrated Science Team identifies how ecological pathways and physiological processes within a single organism can alter exposure and toxicity of contaminants and pathogens and seek to understand outcomes at different scales from individuals to populations and ecosystems.Proxies Project
The Proxies Project is a series of studies to improve our understanding of water contaminants and water quality hazards. These studies develop models and technical approaches for estimating concentrations and assessing risk associated with: - harmful algal blooms (HABs) - per- and polyfluoroalkyl substances (PFAS) - 12 elements of concern (EoC)
Data related to the Microbial Biogeochemistry Core Technology Team can be found below.
Geochemical data for water, sediment, and biota in Lake Combie, California, 2017-2021
Mercury concentration data for soil, surface water and rice grain from six commercial rice growing fields in the Sacramento Valley of California (USA)
Geochemistry Data for Wastewater Samples Collected at a Separator Tank and from an On-Site Storage Tank at the Marcellus Shale Energy and Environment Laboratory (MSEEL) 2015-2019, Morgantown Industrial Park (MIP), West Virginia (ver. 2.0, May 2023)
Geochemical data including mercury for subsamples of deep cores from the Cache Creek Settling Basin, Yolo County, California
The Geochemistry of Mercury and Other Constituents in Redox Manipulated Sediment cores from Clear Lake, Lake County, California
Shallow Sediment Geochemistry in a Mercury-Contaminated Multi-Habitat Floodplain: Cache Creek Settling Basin, Yolo County, California (version 2.0, August 2021)
Chemical characterization of water and suspended sediment of the Snake River and Hells Canyon Complex (Idaho, Oregon) (ver. 3.0, November 2023)
Sediment Biogeochemistry and Subsequent Mercury Biomagnification in Wetland Food Webs of the San Francisco Bay, CA (ver. 2.0, December 2023)
Biogeochemical Data for Mercury and other Constituents in Surface Sediment and Deep Cores from the Hells Canyon Reservoir Complex, Idaho and Oregon 2014-2018
Surface-Water Geochemistry of Mercury, Methylmercury, Nutrients, and other Constituents in Clear Lake, Lake County, California, July 2019
Mercury speciation and other constituent data from deep sediment cores in Alviso Slough, South San Francisco Bay, California, 2006-16
Data for Biogeochemical and Physical Processes Controlling Mercury Methylation and Bioaccumulation in Lake Powell, Glen Canyon National Recreation Area, Utah and Arizona
Multimedia items related to the Microbial Biogeochemistry Core Technology Team can be found below.
Field sampling in the Hells Canyon Reservoir Complex, with Dr. M. Marvin-DiPasquale at the bow of the sediment collection boat. Photographer: D. Krabbenhoft.
Left: USGS Employee L. Windham-Myers showing a surface water sample collected in acid-cleaned mason jar (deployed for 24 hours) for a mercury study conducted at the Cosumnes River Nature Preserve (CA). Photographer: M. Marvin-DiPasquale. Date: 10/29/2014.
Left: USGS Employee L. Windham-Myers showing a surface water sample collected in acid-cleaned mason jar (deployed for 24 hours) for a mercury study conducted at the Cosumnes River Nature Preserve (CA). Photographer: M. Marvin-DiPasquale. Date: 10/29/2014.
Left: Distillation rig used in the measurement of microbial sulfate reduction rates associated with a method based on the incubation of sediment samples with radioactively labeled sulfate. Photographer: M. Marvin-DiPasquale. Date: 3/5/2001.
Left: Distillation rig used in the measurement of microbial sulfate reduction rates associated with a method based on the incubation of sediment samples with radioactively labeled sulfate. Photographer: M. Marvin-DiPasquale. Date: 3/5/2001.
USGS researcher Jennifer Agee taking surface sediment oxidation-reduction and pH measurements at Crissy Marsh, a vegetated saltmarsh near the Golden Gate Bridge (background) in San Francisco, CA. Photographer: L. Windham-Myers.
USGS researcher Jennifer Agee taking surface sediment oxidation-reduction and pH measurements at Crissy Marsh, a vegetated saltmarsh near the Golden Gate Bridge (background) in San Francisco, CA. Photographer: L. Windham-Myers.
Left Image: Managed wetland at the Yolo Bypass Wildlife Preserve (California Central Valley) showing mixed flocks of foraging birds. Photographer: M. Marvin-DiPasquale.
Left Image: Managed wetland at the Yolo Bypass Wildlife Preserve (California Central Valley) showing mixed flocks of foraging birds. Photographer: M. Marvin-DiPasquale.
Left: USGS Employee Sherry Wren removing a square meter of surface sediment in pickleweed dominated marsh along the Petaluma River (California), for a study designed to investigate the role of marsh plant root zone on the cycling of mercury. Photographer: L. Windham-Myers. Date: 4/4/2006
Left: USGS Employee Sherry Wren removing a square meter of surface sediment in pickleweed dominated marsh along the Petaluma River (California), for a study designed to investigate the role of marsh plant root zone on the cycling of mercury. Photographer: L. Windham-Myers. Date: 4/4/2006
Hilltop view of the Ravenswood ponds (right side of levee) in South San Francisco Bay. These former salt-production ponds were subsequently slated for a major wetland restoration project.
Hilltop view of the Ravenswood ponds (right side of levee) in South San Francisco Bay. These former salt-production ponds were subsequently slated for a major wetland restoration project.
USGS researchers Jennifer Agee and Le Kieu sampling surface sediment in a vegetated Louisiana saltmarsh. Photographer: M. Marvin-DiPasquale.
USGS researchers Jennifer Agee and Le Kieu sampling surface sediment in a vegetated Louisiana saltmarsh. Photographer: M. Marvin-DiPasquale.
Scientific publications related to the Microbial Biogeochemistry Core Technology Team can be found below.
South San Francisco Bay Salt Pond Restoration Project—A synthesis of Phase-1 mercury studies
Disentangling the effects of habitat biogeochemistry, food web structure, and diet composition on mercury bioaccumulation in a wetland bird
Wetland management strategy to reduce mercury export in water and bioaccumulation in fish
Biogeochemical and physical processes controlling mercury methylation and bioaccumulation in Lake Powell, Glen Canyon National Recreation Area, Utah and Arizona, 2014 and 2015
Slough evolution and legacy mercury remobilization induced by wetland restoration in South San Francisco Bay
Methylmercury dynamics in Upper Sacramento Valley rice fields with low background soil mercury levels
Mercury on a landscape scale—Balancing regional export with wildlife health
Long-term trends of surface-water mercury and methylmercury concentrations downstream of historic mining within the Carson River watershed
Mercury and methylmercury in aquatic sediment across western North America
Mercury cycling in the Hells Canyon Complex of the Snake River, Idaho and Oregon
Mercury in western North America: A synthesis of environmental contamination, fluxes, bioaccumulation, and risk to fish and wildlife
Web tools related to the Microbial Biogeochemistry Core Technology Team can be found below.
Catalog of Geospatial Datasets for the USGS Water Quality Program, Proxies Project
The Proxies Project is a series of studies to improve our understanding of water contaminants and water quality hazards. These studies develop models and technical approaches for estimating concentrations and assessing risk associated with:
- harmful algal blooms (HABs)
- per- and polyfluoroalkyl substances (PFAS)
-12 elements of concern (EoC) The Proxies Project is a series of studies to impro
Connect with members of the Microbial Biogeochemistry Core Technology Team below.
About the Research
The Microbial Biogeochemistry Laboratory Core Technology Team (CTT) as part of the Environmental Health Program focuses on environmental questions in aquatic systems (sediment and water) involving the linkages between major biogeochemical cycles (those involving carbon, sulfur, iron and nitrogen) and those associated with contaminants of concern.
The research interests and analytical capabilities of the Microbial Biogeochemistry Laboratory CTT bridge the intersection of fundamental microbial biogeochemistry and ecosystem contaminants science.
The mobility, transport, and chemical transformation of many contaminants in aquatic systems are ultimately mediated by microbial process, which are in turn mediated and defined by the availability of specific electron donors (such as various forms of organic carbon) and electron acceptors (such as oxygen, iron, manganese, nitrogen and sulfur).
The Microbial Biogeochemistry Laboratory has a long history of focusing on the intersection of microbial biogeochemistry and contaminants in mercury specific studies, in a wide range of aquatic systems (streams/rivers, wetlands, reservoirs, tidal estuaries and hypersaline salt ponds). In recent years their analytical capabilities have expanded to a much wider range of elements of concern (including Al, As, Cd, Cr, Cu, Fe, Mn, Pb, Se, U, and Zn) and energy production associated waste streams (oil and gas production wastewater, and coal mining regions).
Key Analytical Capabilities include:
- Measurement of microbial reaction rates using isotopic tracer methods
- Mercury speciation in a range of matrices
- Nutrients, anions/cations and trace elements
- Chemical speciation and quantification of major biogeochemical cycle constituents associated with carbon, sulfur, iron, and nitrogen
Key Instrumentation:
- Quadrupole Inductively coupled plasma mass spectrometer (ICP-MS)
- Ion, liquid and gas chromatography
- Total mercury analyzer
- Methylmercury analyzer
- Nutrient analyzer
- Chlorophyll analyzer
- Field fluorometry and other in-situ sensor technology
- Total carbon analyzer (with 13C isotopes)
Science Team Collaborators
-
Energy Integrated Science Team
The Energy Lifecycle Integrated Science Team focuses on the potential for contaminant exposures in the environment that might originate from energy resource activities including, extraction, production, transportation, storage, extraction, waste management and restoration. Perceived health risks to humans and other organisms will be distinguished from actual risks, if any. If actual risks are...Ecologically-Driven Exposure Pathways Science Team
The Ecologically-Driven Exposure Pathways Integrated Science Team identifies how ecological pathways and physiological processes within a single organism can alter exposure and toxicity of contaminants and pathogens and seek to understand outcomes at different scales from individuals to populations and ecosystems.Proxies Project
The Proxies Project is a series of studies to improve our understanding of water contaminants and water quality hazards. These studies develop models and technical approaches for estimating concentrations and assessing risk associated with: - harmful algal blooms (HABs) - per- and polyfluoroalkyl substances (PFAS) - 12 elements of concern (EoC)
Data related to the Microbial Biogeochemistry Core Technology Team can be found below.
Geochemical data for water, sediment, and biota in Lake Combie, California, 2017-2021
Mercury concentration data for soil, surface water and rice grain from six commercial rice growing fields in the Sacramento Valley of California (USA)
Geochemistry Data for Wastewater Samples Collected at a Separator Tank and from an On-Site Storage Tank at the Marcellus Shale Energy and Environment Laboratory (MSEEL) 2015-2019, Morgantown Industrial Park (MIP), West Virginia (ver. 2.0, May 2023)
Geochemical data including mercury for subsamples of deep cores from the Cache Creek Settling Basin, Yolo County, California
The Geochemistry of Mercury and Other Constituents in Redox Manipulated Sediment cores from Clear Lake, Lake County, California
Shallow Sediment Geochemistry in a Mercury-Contaminated Multi-Habitat Floodplain: Cache Creek Settling Basin, Yolo County, California (version 2.0, August 2021)
Chemical characterization of water and suspended sediment of the Snake River and Hells Canyon Complex (Idaho, Oregon) (ver. 3.0, November 2023)
Sediment Biogeochemistry and Subsequent Mercury Biomagnification in Wetland Food Webs of the San Francisco Bay, CA (ver. 2.0, December 2023)
Biogeochemical Data for Mercury and other Constituents in Surface Sediment and Deep Cores from the Hells Canyon Reservoir Complex, Idaho and Oregon 2014-2018
Surface-Water Geochemistry of Mercury, Methylmercury, Nutrients, and other Constituents in Clear Lake, Lake County, California, July 2019
Mercury speciation and other constituent data from deep sediment cores in Alviso Slough, South San Francisco Bay, California, 2006-16
Data for Biogeochemical and Physical Processes Controlling Mercury Methylation and Bioaccumulation in Lake Powell, Glen Canyon National Recreation Area, Utah and Arizona
Multimedia items related to the Microbial Biogeochemistry Core Technology Team can be found below.
Field sampling in the Hells Canyon Reservoir Complex, with Dr. M. Marvin-DiPasquale at the bow of the sediment collection boat. Photographer: D. Krabbenhoft.
Field sampling in the Hells Canyon Reservoir Complex, with Dr. M. Marvin-DiPasquale at the bow of the sediment collection boat. Photographer: D. Krabbenhoft.
Left: USGS Employee L. Windham-Myers showing a surface water sample collected in acid-cleaned mason jar (deployed for 24 hours) for a mercury study conducted at the Cosumnes River Nature Preserve (CA). Photographer: M. Marvin-DiPasquale. Date: 10/29/2014.
Left: USGS Employee L. Windham-Myers showing a surface water sample collected in acid-cleaned mason jar (deployed for 24 hours) for a mercury study conducted at the Cosumnes River Nature Preserve (CA). Photographer: M. Marvin-DiPasquale. Date: 10/29/2014.
Left: Distillation rig used in the measurement of microbial sulfate reduction rates associated with a method based on the incubation of sediment samples with radioactively labeled sulfate. Photographer: M. Marvin-DiPasquale. Date: 3/5/2001.
Left: Distillation rig used in the measurement of microbial sulfate reduction rates associated with a method based on the incubation of sediment samples with radioactively labeled sulfate. Photographer: M. Marvin-DiPasquale. Date: 3/5/2001.
USGS researcher Jennifer Agee taking surface sediment oxidation-reduction and pH measurements at Crissy Marsh, a vegetated saltmarsh near the Golden Gate Bridge (background) in San Francisco, CA. Photographer: L. Windham-Myers.
USGS researcher Jennifer Agee taking surface sediment oxidation-reduction and pH measurements at Crissy Marsh, a vegetated saltmarsh near the Golden Gate Bridge (background) in San Francisco, CA. Photographer: L. Windham-Myers.
Left Image: Managed wetland at the Yolo Bypass Wildlife Preserve (California Central Valley) showing mixed flocks of foraging birds. Photographer: M. Marvin-DiPasquale.
Left Image: Managed wetland at the Yolo Bypass Wildlife Preserve (California Central Valley) showing mixed flocks of foraging birds. Photographer: M. Marvin-DiPasquale.
Left: USGS Employee Sherry Wren removing a square meter of surface sediment in pickleweed dominated marsh along the Petaluma River (California), for a study designed to investigate the role of marsh plant root zone on the cycling of mercury. Photographer: L. Windham-Myers. Date: 4/4/2006
Left: USGS Employee Sherry Wren removing a square meter of surface sediment in pickleweed dominated marsh along the Petaluma River (California), for a study designed to investigate the role of marsh plant root zone on the cycling of mercury. Photographer: L. Windham-Myers. Date: 4/4/2006
Hilltop view of the Ravenswood ponds (right side of levee) in South San Francisco Bay. These former salt-production ponds were subsequently slated for a major wetland restoration project.
Hilltop view of the Ravenswood ponds (right side of levee) in South San Francisco Bay. These former salt-production ponds were subsequently slated for a major wetland restoration project.
USGS researchers Jennifer Agee and Le Kieu sampling surface sediment in a vegetated Louisiana saltmarsh. Photographer: M. Marvin-DiPasquale.
USGS researchers Jennifer Agee and Le Kieu sampling surface sediment in a vegetated Louisiana saltmarsh. Photographer: M. Marvin-DiPasquale.
Scientific publications related to the Microbial Biogeochemistry Core Technology Team can be found below.
South San Francisco Bay Salt Pond Restoration Project—A synthesis of Phase-1 mercury studies
Disentangling the effects of habitat biogeochemistry, food web structure, and diet composition on mercury bioaccumulation in a wetland bird
Wetland management strategy to reduce mercury export in water and bioaccumulation in fish
Biogeochemical and physical processes controlling mercury methylation and bioaccumulation in Lake Powell, Glen Canyon National Recreation Area, Utah and Arizona, 2014 and 2015
Slough evolution and legacy mercury remobilization induced by wetland restoration in South San Francisco Bay
Methylmercury dynamics in Upper Sacramento Valley rice fields with low background soil mercury levels
Mercury on a landscape scale—Balancing regional export with wildlife health
Long-term trends of surface-water mercury and methylmercury concentrations downstream of historic mining within the Carson River watershed
Mercury and methylmercury in aquatic sediment across western North America
Mercury cycling in the Hells Canyon Complex of the Snake River, Idaho and Oregon
Mercury in western North America: A synthesis of environmental contamination, fluxes, bioaccumulation, and risk to fish and wildlife
Web tools related to the Microbial Biogeochemistry Core Technology Team can be found below.
Catalog of Geospatial Datasets for the USGS Water Quality Program, Proxies Project
The Proxies Project is a series of studies to improve our understanding of water contaminants and water quality hazards. These studies develop models and technical approaches for estimating concentrations and assessing risk associated with:
- harmful algal blooms (HABs)
- per- and polyfluoroalkyl substances (PFAS)
-12 elements of concern (EoC) The Proxies Project is a series of studies to impro
Connect with members of the Microbial Biogeochemistry Core Technology Team below.