Organic Chemistry Research Laboratory — Sacramento, California. Vial containing an egg sample
Corey Sanders
Corey Sanders - California Water Science Center
Science and Products
Pesticide Fate Research Group (PFRG)
Pesticides are used in both agricultural and urban settings to manage unwanted plants, insects, fungi, and other pests. However, these substances and their breakdown products can move beyond their intended application sites through various means, ending up in areas where they weren't meant to be. This movement can happen via the air, through water (both surface and groundwater), and by sticking to...
Pesticide Concentrations Measured in Zooplankton Samples Collected from the Sacramento River and Yolo Bypass, California, 2021
Zooplankton samples were collected at one site upstream of the Yolo Bypass in Northern California, three sites within the Bypass, and at a comparison site on the Sacramento River below the city of Sacramento and analyzed for a large suite of current-use pesticides and degradates. Samples were collected every two weeks from early August 2021 to mid-October 2021. Samples were collected by towing a 1
Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive extraction with analysis by gas and liquid chromatography tandem mass spectroscopy
A multiresidue method for solids (i.e., soil, sediment, sludge) was developed and evaluated for the analysis of pesticides and pesticide degradates. Initially, a well characterized soil was used to determine the recovery of target compounds using an Energized Dispersive Guided Extraction (EDGE) system with two extraction solvents, acetonitrile and 1:1 (v/v) hexane:acetone. Extracts were cleaned us
Current-use pesticides, nutrients, chloride, and metals in ponds and stormwater basins of the New Jersey Pinelands, 2018-20
The data presented in this data release include concentrations of current-use pesticides, nutrients, chloride, and metals in surface water collected from 60 wetlands including natural ponds, excavated ponds (Xponds), and stormwater basins in the New Jersey Pinelands, 2018-20. Site information, basic water-quality parameters, and method information also are included.
Pesticide Concentrations Measured in Zooplankton Samples Collected from the Sacramento River and Yolo Bypass, California, 2017-2020
Zooplankton samples were collected at a site in the Yolo Bypass in Northern California and at a comparison site on the Sacramento River below the city of Sacramento and analyzed for a large suite of current-use pesticides and degradates. Samples were collected biweekly in the summer/fall 2017 and 2018, and from May 2019-March 2020. Samples were collected by towing a 150-micron conical plankton net
A Multiresidue Method for the Analysis of Pesticides in Water using Solid-Phase Extraction with Gas and Liquid Chromatography-Tandem Mass Spectrometry (ver. 2.0, April 2023)
Applications of pesticides in agricultural and urban settings play an essential role in increasing crop yields, preserving food and materials, reducing pest-borne diseases, and eradicating or deterring pests. Pesticides are transported from their point of application to environmental media, including surface water. To better understand the fate of fate and transport of pesticides in the environmen
Pesticide detections in streams throughout the foothills of the Sierra Nevada range using passive samplers from 2017 to 2019
This dataset was produced from analyzing Affinisep SDB-RPS, Affinisep HLB, and Restek Resprep C18 disks that were deployed with the use of Chemcatcher� passive sampling devices. Silicone bands were also deployed and used for exploring economical methods of sampling for pesticides in surface water. Sampling assemblies were deployed in streams throughout the foothills of the Sierra Nevada range and
Fungicides in nectar and pollen collected by bumble bees in a cherry orchard
Lab-reared colonies of Bombus huntii (Hunt bumble bee) were deployed in a commercial cherry orchard in the spring of 2016. A fungicide formulation containing boscalid (25.2%) and pyraclostrobin (12.8%) was applied one time at the recommended label rate. Nectar and pollen were collected daily, beginning two days before spray application and continuing for ten days following. Nectar samples were ext
Current-use pesticides and emerging amphibian pathogens in natural ponds, excavated ponds, and stormwater basins from 24 sites varying in land-use classifications throughout the New Jersey Pinelands, 2014-2016
Water, sediment, anuran food (leaf litter and detritus) and whole body larval amphibian composites were analyzed for over 100 current-use pesticides from 24 wetlands representing land-use gradients in the New Jersey Pinelands, USA during 2014-2016. Emerging amphibian pathogens, Ranavirus and Batrachochytrium dendrobatidis (Bd) were also assessed in individual larvae at the 24 wetlands. Tables in t
Vial containing an egg sample that will undergo chemical extraction
Organic Chemistry Research Laboratory — Sacramento, California. Vial containing an egg sample
Pesticide concentrations of surface water and suspended sediment in Yolo By-Pass and Cache Slough Complex, California, 2019–2021
Managed flow pulses in the north Sacramento-San Joaquin Delta are an adaptive management tool used in efforts to enhance food availability in delta smelt (Hypomesus transpacificus) habitat as part of the North Delta Food Subsidies Action. The California Department of Water Resources (DWR) monitors non-managed seasonal and local flow pulses and managed flow pulses from agricultural drainage or main
Authors
Matthew Uychutin, James L. Orlando, Michelle L. Hladik, Corey J. Sanders, Michael S. Gross, Matthew D. De Parsia, Elisabeth M. LaBarbera, Laura Twardochleb, Brittany E. Davis
Methods of analysis—Determination of pesticides in filtered water and suspended sediment using liquid chromatography- and gas chromatography-tandem mass spectrometry
The widespread application of pesticides in agricultural and urban areas leads to their presence in surface waters. Presence of these biologically active chemicals in environmental waters potentially has adverse effects on nontarget organisms. To better understand the environmental fate of these contaminants, a robust method to capture chemicals with wide-ranging physicochemical properties has bee
Authors
Michael S. Gross, Corey J. Sanders, Matthew D. De Parsia, Michelle L. Hladik
Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive guided extraction with analysis by gas and liquid chromatography tandem mass spectroscopy
The development of sample processing techniques that recover a broad suite of pesticides from solid matrices, while mitigating coextracted matrix interferences, and reducing processing time is beneficial for high throughput analyses. The objective of this study was to evaluate the effectiveness of an automated extraction system for pesticide analyses in solid environmental samples. An Energized Di
Authors
Gabrielle Pecora Black, Emily Woodward, Corey Sanders, Michael S. Gross, Michelle Hladik
Measured efficacy, bioaccumulation, and leaching of a transfluthrin-based insecticidal paint: A case study with a nuisance, nonbiting aquatic insect
BACKGROUNDPest management professionals will require a diverse, adaptive abatement toolbox to combat advanced challenges from disease vector and nuisance insect populations. Designed for post-application longevity, insecticidal paints offer extended residual effects on targeted insect pest populations; a measured understanding of active ingredient bioavailability over time is valuable to fully ass
Authors
Michael C. Cavallaro, Corey Sanders, Michelle Hladik
Pesticide concentrations associated with augmented flow pulses in the Yolo Bypass and Cache Slough Complex, California
Surface-water and suspended-sediment samples were collected and analyzed by the U.S. Geological Survey for multiple current-use pesticides and pesticide degradates approximately every 2 weeks at up to five sites in the Yolo Bypass and Cache Slough Complex before, during, and after augmented flow pulses in summer and fall 2016 and 2018 as well as during ambient flow conditions in summer and fall 20
Authors
James L. Orlando, Matt De Parsia, Corey J. Sanders, Michelle L. Hladik, Jared Frantzich
Dissolved pesticide concentrations in the lower Sacramento River and its source waters, California, 2016
As part of a collaborative study designed to better understand water-quality conditions in the Sacramento River, surface-water samples were collected from the lower Sacramento River and five of its tributaries and then analyzed by the U.S. Geological Survey for a suite of 162 current-use pesticides and pesticide degradates. Samples were collected in May and October 2016 at 16 sites on the Sacramen
Authors
Sean M. Stout, James L. Orlando, Megan McWayne-Holmes, Corey Sanders, Michelle L. Hladik
An initial comparison of pesticides and amphibian pathogens between natural and created wetlands in the New Jersey Pinelands, 2014–16
A study conducted by the U.S. Geological Survey, in cooperation with the New Jersey Pinelands Commission and Montclair State University, was designed to compare pesticide concentrations and the presence and prevalence of amphibian pathogens between natural ponds and two types of created wetlands, excavated ponds and stormwater basins, throughout the New Jersey Pinelands. The study described herein
Authors
Kelly L. Smalling, John F. Bunnell, Jonathan Cohl, Kristin M. Romanok, Lisa Hazard, Kirsten Monsen, Denise M. Akob, Angela M. Hansen, Michelle L. Hladik, Nicole Abdallah, Quratulain Ahmed, Araba Assan, Matthew D. De Parsia, Amaryl Griggs, Megan McWayne-Holmes, Naisargi Patel, Corey Sanders, Yesha Shrestha, Sean M. Stout, Brianna Williams
Detections of current-use pesticides at 12 surface water sites in California during a 2-year period beginning in 2015
Surface water samples were collected by the U.S. Geological Survey and multiple cooperators during base flow/irrigation runoff and storm runoff conditions from 12 sites throughout California, over 2 consecutive years beginning in April 2015, from both urban and agriculturally dominated watersheds. Water samples were analyzed by gas chromatography/mass spectrometry and liquid chromatrography/tandem
Authors
Corey J. Sanders, James L. Orlando, Michelle L. Hladik
Leaching and sorption of neonicotinoid insecticides and fungicides from seed coatings
Seed coatings are a treatment used on a variety of crops to improve production and offer protection against pests and fungal outbreaks. The leaching of the active ingredients associated with the seed coatings and the sorption to soil was evaluated under laboratory conditions using commercially available corn and soybean seeds to study the fate and transport of these pesticides under controlled con
Authors
Kelly L. Smalling, Michelle L. Hladik, Corey Sanders, Kathryn Kuivila
Dissolved pesticide concentrations entering the Sacramento-San Joaquin Delta from the Sacramento and San Joaquin Rivers, California, 2012-13
Surface-water samples were collected from the Sacramento and San Joaquin Rivers where they enter the Sacramento–San Joaquin Delta, and analyzed by the U.S. Geological Survey for a suite of 99 current-use pesticides and pesticide degradates. Samples were collected twice per month from May 2012 through July 2013 and from May 2012 through April 2013 at the Sacramento River at Freeport, and the San Jo
Authors
James L. Orlando, Megan McWayne, Corey Sanders, Michelle Hladik
Dissolved pesticide concentrations in the Sacramento-San Joaquin Delta and Grizzly Bay, California, 2011-12
Surface-water samples were collected from sites within the Sacramento-San Joaquin Delta and Grizzly Bay, California, during the spring in 2011 and 2012, and they were analyzed by the U.S. Geological Survey for a suite of 99 current-use pesticides and pesticide degradates. Samples were collected and analyzed as part of a collaborative project studying the occurrence and characteristics of phytoplan
Authors
James L. Orlando, Megan McWayne, Corey Sanders, Michelle Hladik
Science and Products
Pesticide Fate Research Group (PFRG)
Pesticides are used in both agricultural and urban settings to manage unwanted plants, insects, fungi, and other pests. However, these substances and their breakdown products can move beyond their intended application sites through various means, ending up in areas where they weren't meant to be. This movement can happen via the air, through water (both surface and groundwater), and by sticking to...
Pesticide Concentrations Measured in Zooplankton Samples Collected from the Sacramento River and Yolo Bypass, California, 2021
Zooplankton samples were collected at one site upstream of the Yolo Bypass in Northern California, three sites within the Bypass, and at a comparison site on the Sacramento River below the city of Sacramento and analyzed for a large suite of current-use pesticides and degradates. Samples were collected every two weeks from early August 2021 to mid-October 2021. Samples were collected by towing a 1
Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive extraction with analysis by gas and liquid chromatography tandem mass spectroscopy
A multiresidue method for solids (i.e., soil, sediment, sludge) was developed and evaluated for the analysis of pesticides and pesticide degradates. Initially, a well characterized soil was used to determine the recovery of target compounds using an Energized Dispersive Guided Extraction (EDGE) system with two extraction solvents, acetonitrile and 1:1 (v/v) hexane:acetone. Extracts were cleaned us
Current-use pesticides, nutrients, chloride, and metals in ponds and stormwater basins of the New Jersey Pinelands, 2018-20
The data presented in this data release include concentrations of current-use pesticides, nutrients, chloride, and metals in surface water collected from 60 wetlands including natural ponds, excavated ponds (Xponds), and stormwater basins in the New Jersey Pinelands, 2018-20. Site information, basic water-quality parameters, and method information also are included.
Pesticide Concentrations Measured in Zooplankton Samples Collected from the Sacramento River and Yolo Bypass, California, 2017-2020
Zooplankton samples were collected at a site in the Yolo Bypass in Northern California and at a comparison site on the Sacramento River below the city of Sacramento and analyzed for a large suite of current-use pesticides and degradates. Samples were collected biweekly in the summer/fall 2017 and 2018, and from May 2019-March 2020. Samples were collected by towing a 150-micron conical plankton net
A Multiresidue Method for the Analysis of Pesticides in Water using Solid-Phase Extraction with Gas and Liquid Chromatography-Tandem Mass Spectrometry (ver. 2.0, April 2023)
Applications of pesticides in agricultural and urban settings play an essential role in increasing crop yields, preserving food and materials, reducing pest-borne diseases, and eradicating or deterring pests. Pesticides are transported from their point of application to environmental media, including surface water. To better understand the fate of fate and transport of pesticides in the environmen
Pesticide detections in streams throughout the foothills of the Sierra Nevada range using passive samplers from 2017 to 2019
This dataset was produced from analyzing Affinisep SDB-RPS, Affinisep HLB, and Restek Resprep C18 disks that were deployed with the use of Chemcatcher� passive sampling devices. Silicone bands were also deployed and used for exploring economical methods of sampling for pesticides in surface water. Sampling assemblies were deployed in streams throughout the foothills of the Sierra Nevada range and
Fungicides in nectar and pollen collected by bumble bees in a cherry orchard
Lab-reared colonies of Bombus huntii (Hunt bumble bee) were deployed in a commercial cherry orchard in the spring of 2016. A fungicide formulation containing boscalid (25.2%) and pyraclostrobin (12.8%) was applied one time at the recommended label rate. Nectar and pollen were collected daily, beginning two days before spray application and continuing for ten days following. Nectar samples were ext
Current-use pesticides and emerging amphibian pathogens in natural ponds, excavated ponds, and stormwater basins from 24 sites varying in land-use classifications throughout the New Jersey Pinelands, 2014-2016
Water, sediment, anuran food (leaf litter and detritus) and whole body larval amphibian composites were analyzed for over 100 current-use pesticides from 24 wetlands representing land-use gradients in the New Jersey Pinelands, USA during 2014-2016. Emerging amphibian pathogens, Ranavirus and Batrachochytrium dendrobatidis (Bd) were also assessed in individual larvae at the 24 wetlands. Tables in t
Vial containing an egg sample that will undergo chemical extraction
Vial containing an egg sample that will undergo chemical extraction
Organic Chemistry Research Laboratory — Sacramento, California. Vial containing an egg sample
Organic Chemistry Research Laboratory — Sacramento, California. Vial containing an egg sample
Pesticide concentrations of surface water and suspended sediment in Yolo By-Pass and Cache Slough Complex, California, 2019–2021
Managed flow pulses in the north Sacramento-San Joaquin Delta are an adaptive management tool used in efforts to enhance food availability in delta smelt (Hypomesus transpacificus) habitat as part of the North Delta Food Subsidies Action. The California Department of Water Resources (DWR) monitors non-managed seasonal and local flow pulses and managed flow pulses from agricultural drainage or main
Authors
Matthew Uychutin, James L. Orlando, Michelle L. Hladik, Corey J. Sanders, Michael S. Gross, Matthew D. De Parsia, Elisabeth M. LaBarbera, Laura Twardochleb, Brittany E. Davis
Methods of analysis—Determination of pesticides in filtered water and suspended sediment using liquid chromatography- and gas chromatography-tandem mass spectrometry
The widespread application of pesticides in agricultural and urban areas leads to their presence in surface waters. Presence of these biologically active chemicals in environmental waters potentially has adverse effects on nontarget organisms. To better understand the environmental fate of these contaminants, a robust method to capture chemicals with wide-ranging physicochemical properties has bee
Authors
Michael S. Gross, Corey J. Sanders, Matthew D. De Parsia, Michelle L. Hladik
Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive guided extraction with analysis by gas and liquid chromatography tandem mass spectroscopy
The development of sample processing techniques that recover a broad suite of pesticides from solid matrices, while mitigating coextracted matrix interferences, and reducing processing time is beneficial for high throughput analyses. The objective of this study was to evaluate the effectiveness of an automated extraction system for pesticide analyses in solid environmental samples. An Energized Di
Authors
Gabrielle Pecora Black, Emily Woodward, Corey Sanders, Michael S. Gross, Michelle Hladik
Measured efficacy, bioaccumulation, and leaching of a transfluthrin-based insecticidal paint: A case study with a nuisance, nonbiting aquatic insect
BACKGROUNDPest management professionals will require a diverse, adaptive abatement toolbox to combat advanced challenges from disease vector and nuisance insect populations. Designed for post-application longevity, insecticidal paints offer extended residual effects on targeted insect pest populations; a measured understanding of active ingredient bioavailability over time is valuable to fully ass
Authors
Michael C. Cavallaro, Corey Sanders, Michelle Hladik
Pesticide concentrations associated with augmented flow pulses in the Yolo Bypass and Cache Slough Complex, California
Surface-water and suspended-sediment samples were collected and analyzed by the U.S. Geological Survey for multiple current-use pesticides and pesticide degradates approximately every 2 weeks at up to five sites in the Yolo Bypass and Cache Slough Complex before, during, and after augmented flow pulses in summer and fall 2016 and 2018 as well as during ambient flow conditions in summer and fall 20
Authors
James L. Orlando, Matt De Parsia, Corey J. Sanders, Michelle L. Hladik, Jared Frantzich
Dissolved pesticide concentrations in the lower Sacramento River and its source waters, California, 2016
As part of a collaborative study designed to better understand water-quality conditions in the Sacramento River, surface-water samples were collected from the lower Sacramento River and five of its tributaries and then analyzed by the U.S. Geological Survey for a suite of 162 current-use pesticides and pesticide degradates. Samples were collected in May and October 2016 at 16 sites on the Sacramen
Authors
Sean M. Stout, James L. Orlando, Megan McWayne-Holmes, Corey Sanders, Michelle L. Hladik
An initial comparison of pesticides and amphibian pathogens between natural and created wetlands in the New Jersey Pinelands, 2014–16
A study conducted by the U.S. Geological Survey, in cooperation with the New Jersey Pinelands Commission and Montclair State University, was designed to compare pesticide concentrations and the presence and prevalence of amphibian pathogens between natural ponds and two types of created wetlands, excavated ponds and stormwater basins, throughout the New Jersey Pinelands. The study described herein
Authors
Kelly L. Smalling, John F. Bunnell, Jonathan Cohl, Kristin M. Romanok, Lisa Hazard, Kirsten Monsen, Denise M. Akob, Angela M. Hansen, Michelle L. Hladik, Nicole Abdallah, Quratulain Ahmed, Araba Assan, Matthew D. De Parsia, Amaryl Griggs, Megan McWayne-Holmes, Naisargi Patel, Corey Sanders, Yesha Shrestha, Sean M. Stout, Brianna Williams
Detections of current-use pesticides at 12 surface water sites in California during a 2-year period beginning in 2015
Surface water samples were collected by the U.S. Geological Survey and multiple cooperators during base flow/irrigation runoff and storm runoff conditions from 12 sites throughout California, over 2 consecutive years beginning in April 2015, from both urban and agriculturally dominated watersheds. Water samples were analyzed by gas chromatography/mass spectrometry and liquid chromatrography/tandem
Authors
Corey J. Sanders, James L. Orlando, Michelle L. Hladik
Leaching and sorption of neonicotinoid insecticides and fungicides from seed coatings
Seed coatings are a treatment used on a variety of crops to improve production and offer protection against pests and fungal outbreaks. The leaching of the active ingredients associated with the seed coatings and the sorption to soil was evaluated under laboratory conditions using commercially available corn and soybean seeds to study the fate and transport of these pesticides under controlled con
Authors
Kelly L. Smalling, Michelle L. Hladik, Corey Sanders, Kathryn Kuivila
Dissolved pesticide concentrations entering the Sacramento-San Joaquin Delta from the Sacramento and San Joaquin Rivers, California, 2012-13
Surface-water samples were collected from the Sacramento and San Joaquin Rivers where they enter the Sacramento–San Joaquin Delta, and analyzed by the U.S. Geological Survey for a suite of 99 current-use pesticides and pesticide degradates. Samples were collected twice per month from May 2012 through July 2013 and from May 2012 through April 2013 at the Sacramento River at Freeport, and the San Jo
Authors
James L. Orlando, Megan McWayne, Corey Sanders, Michelle Hladik
Dissolved pesticide concentrations in the Sacramento-San Joaquin Delta and Grizzly Bay, California, 2011-12
Surface-water samples were collected from sites within the Sacramento-San Joaquin Delta and Grizzly Bay, California, during the spring in 2011 and 2012, and they were analyzed by the U.S. Geological Survey for a suite of 99 current-use pesticides and pesticide degradates. Samples were collected and analyzed as part of a collaborative project studying the occurrence and characteristics of phytoplan
Authors
James L. Orlando, Megan McWayne, Corey Sanders, Michelle Hladik