Geology, hydrology, and groundwater contamination in the vicinity of Central Chemical facility, Hagerstown, Maryland

The soil and groundwater at the Central Chemical facility, Hagerstown, Maryland, are contaminated due to the blending and production of pesticides and fertilizers during much of the 20th century. Remedial investigations focus on two operable units (OU) consisting of the surface soils and waste disposal lagoon (OU-1) and the groundwater (OU-2). The contaminants of concern (COC) for groundwater include 41 compounds categorized within the subgroups of volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), pesticides, and metals. The purpose of this report is to provide a conceptual site model of the hydrogeology and groundwater contaminant transport at and near the Central Chemical facility. The conceptual model was developed through review, synthesis, and interpretation of the results of hydrogeologic, soil, and other environmental investigations conducted at and in the vicinity of the facility in recent decades and is intended to support plans for environmental remediation of the groundwater in OU-2.

The extent and nature of the groundwater contaminant plume associated with the bedrock was characterized for OU-2 of the site. Lithologic and structural comparisons between shallow soil, weathered rock, and epikarst and deeper competent but bedded, dipping, fractured, and karstic limestones illustrate two connected flow systems—a surficial flow system consisting of the unconsolidated overburden and epikarst and a structurally dominant bedrock flow system below the epikarst. Uncertainties exist regarding the nature and transport of contaminants within the epikarst system particularly within voids and perched epikarst water tables. Karst dissolution features are observed within the site including sinkholes and dissolution voids within wells at the site. Of interest, one well in the northern part of the study area (MW-J-71) appears to have a dissolution void connected to an offsite well (OW-2-115) farther to the north. This connection is supported by groundwater level data and elevated concentrations of total suspended solids (TSS) and chlorobenzene in both wells. The high level of TSS supports the possibility of offsite transport of particle-bound contaminants within the conduit system. Episodically elevated concentrations of COC from different groups also were observed within select wells in the epikarst near the waste disposal lagoon (particularly MW-A-51). The variability observed between different COC within the same well may be the result of additional contaminated source materials unrelated to the disposal lagoon. Storage and episodic transport of contaminated material within the epikarst system has the potential to hinder remediation efforts if not considered in the remedial action.