A Nd, Sr and O isotopic investigation into the causes of chemical and isotopic zonation in the Bishop Tuff, California

The Bishop Tuff represents a single eruption of chemically zoned rhyolitic magma. Six whole rock samples spanning the compositional and temperature range yield initial⁸⁷Sr/⁸⁶Sr of 0.7060–0.7092 andδ¹⁸O of 5.9–10.3‰. Six constituent sanidines yield smaller ranges of initial⁸⁷Sr/⁸⁶Sr of 0.7061–0.7069 andδ¹⁸O of 6.7–7.9. In contrast¹⁴³Nd/¹⁴⁴Nd ratios for the six whole rocks and two constituent magnetites exhibit negligible variation with a mean of0.51258 ± 1. These data are used to show that the phenocrysts were precipitated from an already chemically zoned liquid, that the zoning process involved negligible assimilation of, or exchange with, country rocks and that the extreme Sr and O isotopic disequilibria are probably the result of post-eruptive interaction with meteoric water. The parent magma hadɛNd = −0.9, ɛSr = +23 andδ¹⁸O = 7‰ and was formed from mantle-derived magmas and/or melts of lower crustal rocks isotopically similar to parts of the Sierra Nevada Batholith.