Why is Groundwater Quality Changing?
Increased Pumping in California’s Central Valley During Drought Worsens Groundwater Quality in Public Drinking Water Wells
Pumping during drought pulled shallow, contaminated groundwater down to depths commonly tapped for public drinking-water supply.
Pumping during drought pulled shallow, contaminated groundwater down to depths commonly tapped for public drinking-water supply.
Natural Fluoride Concentration Patterns Are Changing Because of Water Use
Intensive use and management of groundwater, especially in the southern part of the State, is causing changes in the natural fluoride patterns.
Intensive use and management of groundwater, especially in the southern part of the State, is causing changes in the natural fluoride patterns.
Managed Aquifer Recharge in the Coachella Valley Using Colorado River Water is the Primary Source of Increasing Salinity Concentrations in the Indio Subbasin
One third of the water supply wells are delivering saltier water than in the past.
One third of the water supply wells are delivering saltier water than in the past.
Defining Natural Background Levels of Hexavalent Chromium Cr(VI) in Hinkley, California
Scientists map the extent of human-introduced hexavalent chromium, a known carcinogen under specific circumstances, in California’s Hinkley Valley.
Scientists map the extent of human-introduced hexavalent chromium, a known carcinogen under specific circumstances, in California’s Hinkley Valley.
Artificial Recharge Can Cause Mixing with Septic Effluent Stored in the Unsaturated Zone
Artificial recharge by the Hi Desert Water District in the Warren Subbasin raised the water table to the point where septic discharge started mixing into groundwater.
Artificial recharge by the Hi Desert Water District in the Warren Subbasin raised the water table to the point where septic discharge started mixing into groundwater.
Groundwater Quality Tapped by Public Supply Wells Changes Over Time
The USGS has compiled all of the analytical data submitted by drinking water suppliers and USGS sampling from 1974–2022 into a tool that maps trends in groundwater quality.
The USGS has compiled all of the analytical data submitted by drinking water suppliers and USGS sampling from 1974–2022 into a tool that maps trends in groundwater quality.
Groundwater is a critical resource in California and water quality a key factor in water supply reliability. This web page presents a number of case studies that explain why and how groundwater quality is changing as a result of water use and management practices.
Defining Natural Background Levels of Hexavalent Chromium Cr(VI) in Hinkley, California
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- Natural background concentrations of Cr(VI) in groundwater are controlled by a number of factors including pH and oxygen, time since recharge, and local geology.
- The local community participated in the science by describing the meaning of “background” and by observing USGS sampling and on-site chemical analysis in the mobile lab.
Managed Aquifer Recharge in the Coachella Valley Using Colorado River Water is the Primary Source of Increasing Salinity Concentrations in the Indio Subbasin
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- Salinity in the Indio groundwater basin in the Coachella Valley is increasing. One third of the water supply wells are delivering saltier water than in the past.
- Imported Colorado River water is used to replenish the aquifer and is the dominant source of salinity responsible for these trends both basin-wide and in 3/4 of the water supply wells delivering highest salinity water.
- Treated wastewater and agricultural return flows also contribute salinity to some shallow areas.
- Salinity trends and concentrations are not homogenous.
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Artificial Recharge Can Cause Mixing with Septic Effluent Stored in the Unsaturated Zone
- Artificial recharge by the Hi Desert Water District in the Warren Subbasin raised the water table to the point where septic discharge started mixing into groundwater.
- The USGS provided a solute-transport model coupled with groundwater-flow models so water managers could simulate changes in groundwater quality at specific sites as recharge and septic sources mix.
- Cost-effective monitoring networks can be designed using modeled information.
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Increased Pumping in California’s Central Valley During Drought Worsens Groundwater Quality in Public Drinking Water Wells
- Increased pumping from wells in the Central Valley during drought pulled shallow, contaminated groundwater down to depths commonly tapped for public drinking-water supply.
- Water-quality problems from legacy groundwater pollution can get worse, faster, when pumping increases during drought.
- This is a regional scale pattern occurring over 30 years. Water quality delivered by individual wells can differ.
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Natural Fluoride Concentration Patterns Are Changing Because of Water Use
- Intensive use and management of groundwater, especially in the southern part of the State, is causing changes in the natural fluoride patterns.
- In areas like the Coachella Valley where recharge consists of imported, salty water from the Colorado River, fluoride concentrations are generally decreasing.
- In locations like Orange County, recharge with treated wastewater creates aquifer conditions that increase fluoride concentrations.
- Statewide, natural fluoride concentrations are decreasing in 9.6% of the groundwater resources used for public supply in the state and increasing in 4.6% of the resources.
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Groundwater Quality Tapped by Public Supply Wells Changes Over Time
- The USGS has compiled all of the analytical data submitted by drinking water suppliers and USGS sampling from 1974–2022 into a tool that maps trends in groundwater quality.
- Some noteworthy findings:
- Groundwater quality can change seasonally and over long periods of time.
- Trends can reverse.
Related
Below are additional publications on groundwater quality change.
Filter Total Items: 15
Arsenic, chromium, uranium, and vanadium in rock, alluvium, and groundwater, Mojave River and Morongo Areas, western Mojave Desert, southern California
Trace elements within groundwater that originate from aquifer materials and pose potential public-health hazards if consumed are known as geogenic contaminants. The geogenic contaminants arsenic, chromium, and vanadium can form negatively charged ions with oxygen known as oxyanions. Uranium complexes with bicarbonate and carbonate to form negatively charged ions having aqueous chemistry...
Authors
John A. Izbicki, Krishangi D. Groover, Whitney A. Seymour
Modeling the dynamic penetration depth of post-1950s water in unconfined aquifers using environmental tracers: Central Valley, California
The penetration depth of post-1950s recharge (D-1950) in aquifers is a marker that is frequently used to identify groundwater that is susceptible to anthropogenic contamination. Here, we compute D-1950 values at wells, interpolate them in space, and project them across time to map the moving front of modern recharge in four dimensions in the Central Valley aquifer system, California, USA...
Authors
Kirsten Faulkner, Bryant Jurgens, Stefan Voss, Danielle Dupuy, Zeno Levy
Mapping aquifer salinity gradients and effects of oil field produced water disposal using geophysical logs: Elk Hills, Buena Vista and Coles Levee Oil Fields, San Joaquin Valley, California
The effects of oil and gas production on adjacent groundwater quality are becoming a concern in many areas of the United States. As a result, it has become increasingly important to identify which aquifers require monitoring and protection. In this study, we map the extent of groundwater with less than 10,000 mg/L TDS both laterally and vertically near the Elk Hills, Buena Vista and...
Authors
Janice M. Gillespie, Michael J. Stephens, Will Chang, John G. Warden
Simulation of groundwater and surface-water resources of the San Antonio Creek Valley watershed, Santa Barbara County, California
In the San Antonio Creek Valley watershed (SACVW), western Santa Barbara County, California, groundwater is the primary source of water for agricultural irrigation, the town of Los Alamos, and supplemental water to Vandenberg Space Force Base (VSFB). Groundwater pumpage has increased since the 1970s as non-irrigated agricultural land has been converted to irrigated land and as local...
Authors
Linda R. Woolfenden, John A. Engott, Joshua Larsen, Geoffrey Cromwell
Machine learning predictions of nitrate in groundwater used for drinking supply in the conterminous United States
Groundwater is an important source of drinking water supplies in the conterminous United State (CONUS), and presence of high nitrate concentrations may limit usability of groundwater in some areas because of the potential negative health effects. Prediction of locations of high nitrate groundwater is needed to focus mitigation and relief efforts. A three-dimensional extreme gradient...
Authors
Katherine Marie Ransom, Bernard T. Nolan, Paul Stackelberg, Kenneth Belitz, Miranda S. Fram
Geologic influences on the quality of groundwater used for domestic supply in the northern Sierra Nevada Foothills
Approximately 2 million California residents depend on groundwater from domestic wells for their drinking-water supply. The State of California, in collaboration with the U.S. Geological Survey, created the Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) to assess the quality of groundwater used for domestic supply throughout the state and...
Authors
Zeno F. Levy, Miranda S. Fram
Groundwater quality of aquifers overlying the Oxnard Oil Field, Ventura County, California
Groundwater samples collected from irrigation, monitoring, and municipal supply wells near the Oxnard Oil Field were analyzed for chemical and isotopic tracers to evaluate if thermogenic gas or water from hydrocarbon-bearing formations have mixed with surrounding groundwater. New and historical data show no evidence of water from hydrocarbon-bearing formations in groundwater overlying...
Authors
Celia Z. Rosecrans, Matthew K. Landon, Katherine Marie Ransom, Janice M. Gillespie, Justin T. Kulongoski, Michael J. Stephens, Andrew G. Hunt, David H. Shimabukuro, Tracy Davis
Anthropogenic and geologic causes of anomalously high uranium concentrations in groundwater used for drinking water supply in the southeastern San Joaquin Valley, CA
Concentrations of uranium (U) >30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where complex interactions of aquifer materials and anthropogenic alterations of the natural flow regime mobilize uranium. High concentrations (>30 µg/L) of U in the southeastern San Joaquin Valley, California, USA, have been detected...
Authors
Michael R. Rosen, Karen R. Burow, Miranda Fram
Groundwater salinity and the effects of produced water disposal in the Lost Hills-Belridge oilfields, Kern County, California
Increased oil and gas production in many areas has led to concerns over the effects these activities may be having on nearby groundwater quality. In this study we determine the lateral and vertical extent of groundwater with less than 10,000 milligrams per liter (mg/l) total dissolved solids (TDS) near the Lost Hills-Belridge oilfields in northwestern Kern County, California and document...
Authors
Janice M. Gillespie, Tracy Davis, Michael J. Stephens, Lyndsay B. Ball, Matthew K. Landon
A novel high-frequency groundwater quality monitoring system
High-frequency, long-term monitoring of water quality has revolutionized the study of surface waters in recent years. However, application of these techniques to groundwater has been limited by the ability to remotely pump and analyze groundwater. This paper describes a novel autonomous groundwater quality monitoring system which samples multiple wells to evaluate temporal changes and...
Authors
John Franco Saraceno, Justin T. Kulongoski, Timothy M. Mathany
Hydrogeologic controls and geochemical indicators of groundwater movement in the Niles Cone and southern East Bay Plain groundwater subbasins, Alameda County, California
Beginning in the 1970s, Alameda County Water District began infiltrating imported water through ponds in repurposed gravel quarries at the Quarry Lakes Regional Park, in the Niles Cone groundwater subbasin, to recharge groundwater and to minimize intrusion of saline, San Francisco Bay water into freshwater aquifers. Hydraulic connection between distinct aquifers underlying Quarry Lakes...
Authors
Nicholas F. Teague, John A. Izbicki, Jim Borchers, Justin T. Kulongoski, Bryant C. Jurgens
Selected techniques for monitoring water movement through unsaturated alluvium during managed aquifer recharge
Managed aquifer recharge is used to augment natural recharge to aquifers. It can be used to replenish aquifers depleted by pumping or to store water during wetter years for withdrawal during drier years. Infiltration from ponds is a commonly used, inexpensive approach for managed aquifer recharge.At some managed aquifer-recharge sites, the time when infiltrated water arrives at the water...
Authors
Joseph M. Nawikas, David R. O'Leary, John A. Izbicki, Matthew K. Burgess
Below are web tools related to groundwater quality change.
Denitrification Only Removes Minor Amounts of Nitrate in Eastern San Joaquin Valley Groundwater
Nitrate is a major concern to water-resource managers in the eastern San Joaquin Valley, and there are extensive regulatory programs in place that seek to reduce nonpoint-source loading and eventually reduce concentrations in groundwater.
Trends in Arsenic Concentrations in the San Joaquin Valley
Arsenic is known to be a problem in groundwater used for drinking water supplies in the San Joaquin Valley. About 10% of the are of groundwater resources used for public supply contain more than the USEPA MCL of 10 µg/L. Most public-supply and domestic wells currently yield groundwater with arsenic levels below 3 µg/L and do not exhibit trends in concentration.
Nothing Happens Right Away—Predicting Decreases in Nitrate Concentrations After Zero Loading is Achieved
This focuses on how we use groundwater age to predict changes in nitrate concentrations over time. Typically, deep public supply wells draw from deeper parts of the aquifer where water is decades, centuries, or even millenia old.
Irrigation Causes Naturally Occurring Uranium to Dissolve into Groundwater in the Eastern San Joaquin Valley
The USGS first identified uranium as a potential issue in California's groundwater during studies conducted in the Modesto area funded by the USGS National Water Quality Assessment Program. Subsequently, the GAMA program undertook a broader analysis of uranium concentrations across the State.
Related
Below are additional publications on groundwater quality change.
Filter Total Items: 15
Arsenic, chromium, uranium, and vanadium in rock, alluvium, and groundwater, Mojave River and Morongo Areas, western Mojave Desert, southern California
Trace elements within groundwater that originate from aquifer materials and pose potential public-health hazards if consumed are known as geogenic contaminants. The geogenic contaminants arsenic, chromium, and vanadium can form negatively charged ions with oxygen known as oxyanions. Uranium complexes with bicarbonate and carbonate to form negatively charged ions having aqueous chemistry...
Authors
John A. Izbicki, Krishangi D. Groover, Whitney A. Seymour
Modeling the dynamic penetration depth of post-1950s water in unconfined aquifers using environmental tracers: Central Valley, California
The penetration depth of post-1950s recharge (D-1950) in aquifers is a marker that is frequently used to identify groundwater that is susceptible to anthropogenic contamination. Here, we compute D-1950 values at wells, interpolate them in space, and project them across time to map the moving front of modern recharge in four dimensions in the Central Valley aquifer system, California, USA...
Authors
Kirsten Faulkner, Bryant Jurgens, Stefan Voss, Danielle Dupuy, Zeno Levy
Mapping aquifer salinity gradients and effects of oil field produced water disposal using geophysical logs: Elk Hills, Buena Vista and Coles Levee Oil Fields, San Joaquin Valley, California
The effects of oil and gas production on adjacent groundwater quality are becoming a concern in many areas of the United States. As a result, it has become increasingly important to identify which aquifers require monitoring and protection. In this study, we map the extent of groundwater with less than 10,000 mg/L TDS both laterally and vertically near the Elk Hills, Buena Vista and...
Authors
Janice M. Gillespie, Michael J. Stephens, Will Chang, John G. Warden
Simulation of groundwater and surface-water resources of the San Antonio Creek Valley watershed, Santa Barbara County, California
In the San Antonio Creek Valley watershed (SACVW), western Santa Barbara County, California, groundwater is the primary source of water for agricultural irrigation, the town of Los Alamos, and supplemental water to Vandenberg Space Force Base (VSFB). Groundwater pumpage has increased since the 1970s as non-irrigated agricultural land has been converted to irrigated land and as local...
Authors
Linda R. Woolfenden, John A. Engott, Joshua Larsen, Geoffrey Cromwell
Machine learning predictions of nitrate in groundwater used for drinking supply in the conterminous United States
Groundwater is an important source of drinking water supplies in the conterminous United State (CONUS), and presence of high nitrate concentrations may limit usability of groundwater in some areas because of the potential negative health effects. Prediction of locations of high nitrate groundwater is needed to focus mitigation and relief efforts. A three-dimensional extreme gradient...
Authors
Katherine Marie Ransom, Bernard T. Nolan, Paul Stackelberg, Kenneth Belitz, Miranda S. Fram
Geologic influences on the quality of groundwater used for domestic supply in the northern Sierra Nevada Foothills
Approximately 2 million California residents depend on groundwater from domestic wells for their drinking-water supply. The State of California, in collaboration with the U.S. Geological Survey, created the Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) to assess the quality of groundwater used for domestic supply throughout the state and...
Authors
Zeno F. Levy, Miranda S. Fram
Groundwater quality of aquifers overlying the Oxnard Oil Field, Ventura County, California
Groundwater samples collected from irrigation, monitoring, and municipal supply wells near the Oxnard Oil Field were analyzed for chemical and isotopic tracers to evaluate if thermogenic gas or water from hydrocarbon-bearing formations have mixed with surrounding groundwater. New and historical data show no evidence of water from hydrocarbon-bearing formations in groundwater overlying...
Authors
Celia Z. Rosecrans, Matthew K. Landon, Katherine Marie Ransom, Janice M. Gillespie, Justin T. Kulongoski, Michael J. Stephens, Andrew G. Hunt, David H. Shimabukuro, Tracy Davis
Anthropogenic and geologic causes of anomalously high uranium concentrations in groundwater used for drinking water supply in the southeastern San Joaquin Valley, CA
Concentrations of uranium (U) >30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where complex interactions of aquifer materials and anthropogenic alterations of the natural flow regime mobilize uranium. High concentrations (>30 µg/L) of U in the southeastern San Joaquin Valley, California, USA, have been detected...
Authors
Michael R. Rosen, Karen R. Burow, Miranda Fram
Groundwater salinity and the effects of produced water disposal in the Lost Hills-Belridge oilfields, Kern County, California
Increased oil and gas production in many areas has led to concerns over the effects these activities may be having on nearby groundwater quality. In this study we determine the lateral and vertical extent of groundwater with less than 10,000 milligrams per liter (mg/l) total dissolved solids (TDS) near the Lost Hills-Belridge oilfields in northwestern Kern County, California and document...
Authors
Janice M. Gillespie, Tracy Davis, Michael J. Stephens, Lyndsay B. Ball, Matthew K. Landon
A novel high-frequency groundwater quality monitoring system
High-frequency, long-term monitoring of water quality has revolutionized the study of surface waters in recent years. However, application of these techniques to groundwater has been limited by the ability to remotely pump and analyze groundwater. This paper describes a novel autonomous groundwater quality monitoring system which samples multiple wells to evaluate temporal changes and...
Authors
John Franco Saraceno, Justin T. Kulongoski, Timothy M. Mathany
Hydrogeologic controls and geochemical indicators of groundwater movement in the Niles Cone and southern East Bay Plain groundwater subbasins, Alameda County, California
Beginning in the 1970s, Alameda County Water District began infiltrating imported water through ponds in repurposed gravel quarries at the Quarry Lakes Regional Park, in the Niles Cone groundwater subbasin, to recharge groundwater and to minimize intrusion of saline, San Francisco Bay water into freshwater aquifers. Hydraulic connection between distinct aquifers underlying Quarry Lakes...
Authors
Nicholas F. Teague, John A. Izbicki, Jim Borchers, Justin T. Kulongoski, Bryant C. Jurgens
Selected techniques for monitoring water movement through unsaturated alluvium during managed aquifer recharge
Managed aquifer recharge is used to augment natural recharge to aquifers. It can be used to replenish aquifers depleted by pumping or to store water during wetter years for withdrawal during drier years. Infiltration from ponds is a commonly used, inexpensive approach for managed aquifer recharge.At some managed aquifer-recharge sites, the time when infiltrated water arrives at the water...
Authors
Joseph M. Nawikas, David R. O'Leary, John A. Izbicki, Matthew K. Burgess
Below are web tools related to groundwater quality change.
Denitrification Only Removes Minor Amounts of Nitrate in Eastern San Joaquin Valley Groundwater
Nitrate is a major concern to water-resource managers in the eastern San Joaquin Valley, and there are extensive regulatory programs in place that seek to reduce nonpoint-source loading and eventually reduce concentrations in groundwater.
Trends in Arsenic Concentrations in the San Joaquin Valley
Arsenic is known to be a problem in groundwater used for drinking water supplies in the San Joaquin Valley. About 10% of the are of groundwater resources used for public supply contain more than the USEPA MCL of 10 µg/L. Most public-supply and domestic wells currently yield groundwater with arsenic levels below 3 µg/L and do not exhibit trends in concentration.
Nothing Happens Right Away—Predicting Decreases in Nitrate Concentrations After Zero Loading is Achieved
This focuses on how we use groundwater age to predict changes in nitrate concentrations over time. Typically, deep public supply wells draw from deeper parts of the aquifer where water is decades, centuries, or even millenia old.
Irrigation Causes Naturally Occurring Uranium to Dissolve into Groundwater in the Eastern San Joaquin Valley
The USGS first identified uranium as a potential issue in California's groundwater during studies conducted in the Modesto area funded by the USGS National Water Quality Assessment Program. Subsequently, the GAMA program undertook a broader analysis of uranium concentrations across the State.