Groundwater Quality and Age of Secondary Bedrock Aquifers, Eastern Nebraska
The Eastern Nebraska Water Resources Assessment (ENWRA) project was initiated in 2006 to assist water managers by developing a hydrogeologic framework and water budget for the glaciated portion of eastern Nebraska. Within the ENWRA area, the primary groundwater sources for municipal, domestic, and irrigation water needs are provided by withdrawals from alluvial, buried paleovalley, and the High Plains aquifer (where present). Generally, other bedrock aquifers are considered a secondary water source. However, in some areas, such as parts of Sarpy and Nemaha Counties, these secondary bedrock aquifers are the only source of water within glaciated upland areas. The U.S. Geological Survey (USGS), in cooperation with the ENWRA group, which includes the Lewis and Clark, Lower Elkhorn, Lower Platte North, Lower Platte South, Nemaha, and Papio-Missouri River Natural Resources Districts completed a study to examine the quality, age, and recharge characteristics of groundwater from selected bedrock aquifers in eastern Nebraska.
Sampling
Groundwater samples were collected from August 2016 to June 2018 from selected secondary bedrock aquifers. Of the 31 wells sampled, 22 samples were collected from the Dakota aquifer contained in the Dakota Sandstone, 3 from the Niobrara aquifer contained in the Niobrara Formation of Colorado Group, and 6 from Paleozoic aquifers contained in undifferentiated Paleozoic-age units.
Samples were analyzed for major ions, physical properties, nutrients, stable isotopes, and selected age tracers.
Summary of results
The results of this study indicate that major ion data collected from the Dakota aquifer can be used for assessing the quality, recharge source, and age of groundwater. Calcium bicarbonate dominant samples were characterized as modern or mixed, indicating that, in these areas, groundwater is unconfined and is recharged by precipitation and (or) surface water. In contrast, groundwater sampled from the Dakota aquifer, having a dominant water type other than calcium bicarbonate, generally has low dissolved oxygen and nitrate concentrations, and higher concentrations of total dissolved solids and trace elements, including iron and strontium. The geochemical characteristics of noncalcium bicarbonate samples from the Dakota aquifer indicated confining conditions and limited groundwater recharge from local precipitation. Apparent groundwater ages estimated from radiocarbon (carbon-14) sampling of noncalcium bicarbonate samples from the Dakota aquifer indicated that the time of groundwater recharge to the Dakota aquifer occurred during Pleistocene time. Depleted stable isotopes results indicate recharge during a colder climate.
For the Niobrara aquifer and Paleozoic aquifers, the dominant water type was not a diagnostic indicator of recharge source, age, and groundwater quality as with the Dakota aquifer. Samples collected from wells completed in the Niobrara aquifer and Paleozoic aquifers and characterized as calcium sulfate water type have statistically significantly higher concentrations of total dissolved solids compared to other samples from the Niobrara aquifer and Paleozoic aquifers characterized as calcium bicarbonate. Given that six of the nine of samples collected from the Niobrara and Paleozoic aquifers indicated modern recharge, these secondary bedrock aquifers are reliant on precipitation to sustain groundwater levels and may be vulnerable to a multiyear drought. Well yields of the Niobrara and Paleozoic aquifers are dependent on the presence of secondary porosity and these units offer little storage. Samples collected from wells completed in Paleozoic aquifers were the most isotopically enriched and similar to modern precipitation and had the highest concentrations of nitrate, indicating that groundwater is affected by agricultural activities.
The Eastern Nebraska Water Resources Assessment (ENWRA) project was initiated in 2006 to assist water managers by developing a hydrogeologic framework and water budget for the glaciated portion of eastern Nebraska. Within the ENWRA area, the primary groundwater sources for municipal, domestic, and irrigation water needs are provided by withdrawals from alluvial, buried paleovalley, and the High Plains aquifer (where present). Generally, other bedrock aquifers are considered a secondary water source. However, in some areas, such as parts of Sarpy and Nemaha Counties, these secondary bedrock aquifers are the only source of water within glaciated upland areas. The U.S. Geological Survey (USGS), in cooperation with the ENWRA group, which includes the Lewis and Clark, Lower Elkhorn, Lower Platte North, Lower Platte South, Nemaha, and Papio-Missouri River Natural Resources Districts completed a study to examine the quality, age, and recharge characteristics of groundwater from selected bedrock aquifers in eastern Nebraska.
Sampling
Groundwater samples were collected from August 2016 to June 2018 from selected secondary bedrock aquifers. Of the 31 wells sampled, 22 samples were collected from the Dakota aquifer contained in the Dakota Sandstone, 3 from the Niobrara aquifer contained in the Niobrara Formation of Colorado Group, and 6 from Paleozoic aquifers contained in undifferentiated Paleozoic-age units.
Samples were analyzed for major ions, physical properties, nutrients, stable isotopes, and selected age tracers.
Summary of results
The results of this study indicate that major ion data collected from the Dakota aquifer can be used for assessing the quality, recharge source, and age of groundwater. Calcium bicarbonate dominant samples were characterized as modern or mixed, indicating that, in these areas, groundwater is unconfined and is recharged by precipitation and (or) surface water. In contrast, groundwater sampled from the Dakota aquifer, having a dominant water type other than calcium bicarbonate, generally has low dissolved oxygen and nitrate concentrations, and higher concentrations of total dissolved solids and trace elements, including iron and strontium. The geochemical characteristics of noncalcium bicarbonate samples from the Dakota aquifer indicated confining conditions and limited groundwater recharge from local precipitation. Apparent groundwater ages estimated from radiocarbon (carbon-14) sampling of noncalcium bicarbonate samples from the Dakota aquifer indicated that the time of groundwater recharge to the Dakota aquifer occurred during Pleistocene time. Depleted stable isotopes results indicate recharge during a colder climate.
For the Niobrara aquifer and Paleozoic aquifers, the dominant water type was not a diagnostic indicator of recharge source, age, and groundwater quality as with the Dakota aquifer. Samples collected from wells completed in the Niobrara aquifer and Paleozoic aquifers and characterized as calcium sulfate water type have statistically significantly higher concentrations of total dissolved solids compared to other samples from the Niobrara aquifer and Paleozoic aquifers characterized as calcium bicarbonate. Given that six of the nine of samples collected from the Niobrara and Paleozoic aquifers indicated modern recharge, these secondary bedrock aquifers are reliant on precipitation to sustain groundwater levels and may be vulnerable to a multiyear drought. Well yields of the Niobrara and Paleozoic aquifers are dependent on the presence of secondary porosity and these units offer little storage. Samples collected from wells completed in Paleozoic aquifers were the most isotopically enriched and similar to modern precipitation and had the highest concentrations of nitrate, indicating that groundwater is affected by agricultural activities.