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How reservoirs alter drinking water quality: Organic matter sources, sinks, and transformations

Within reservoirs, production, transformation, and loss of dissolved organic matter (DOM) occur simultaneously. While the balance between production and loss determines whether a reservoir is a net sink or source of DOM, changes in chemical composition are also important because they affect DOM reactivity with respect to disinfection by-product (DBP) formation. The composition of the DOM pool also
Authors
Tamara E.C. Kraus, Brian A. Bergamaschi, Peter J. Hernes, Daniel H. Doctor, Carol Kendall, Bryan D. Downing, Richard F. Losee

Removal of inorganic mercury and methylmercury from surface waters following coagulation of dissolved organic matter with metal-based salts

The presence of inorganic mercury (IHg) and methylmercury (MeHg) in surface waters is a health concern worldwide. This study assessed the removal potential use of metal-based coagulants as a means to remove both dissolved IHg and MeHg from natural waters and provides information regarding the importance of Hg associations with the dissolved organic matter (DOM) fraction and metal hydroxides. Previ
Authors
Y.K. Henneberry, T.E.C. Kraus, J.A. Fleck, David P. Krabbenhoft, P.M. Bachand, W.R. Horwath

Determining sources of dissolved organic carbon and disinfection byproduct precursors to the McKenzie River, Oregon

This study was conducted to determine the main sources of dissolved organic carbon (DOC) and disinfection byproduct (DBP) precursors to the McKenzie River, Oregon (USA). Water samples collected from the mainstem, tributaries, and reservoir outflows were analyzed for DOC concentration and DBP formation potentials (trihalomethanes [THMFPs] and haloacetic acids [HAAFPs]). In addition, optical propert
Authors
Tamara E.C. Kraus, Chauncey W. Anderson, Karl Morgenstern, Bryan D. Downing, Brian A. Pellerin, Brian A. Bergamaschi

Microbial degradation of plant leachate alters lignin phenols and trihalomethane precursors

Although the importance of vascular plant-derived dissolved organic carbon (DOC) in freshwater systems has been studied, the role of leached DOC as precursors of disinfection byproducts (DBPs) during drinking water treatment is not well known. Here we measured the propensity of leachates from four crops and four aquatic macrophytes to form trihalomethanes (THMs)—a regulated class of DBPs—before an
Authors
Brian A. Pellerin, Peter J. Hernes, John Franco Saraceno, Robert G.M. Spencer, Brian A. Bergamaschi

Quantifying fluxes and characterizing compositional changes of dissolved organic matter in aquatic systems in situ using combined acoustic and optical measurements

Studying the dynamics and geochemical behavior of dissolved and particulate organic material is difficult because concentration and composition may rapidly change in response to aperiodic as well as periodic physical and biological forcing. Here we describe a method useful for quantifying fluxes and analyzing dissolved organic matter (DOM) dynamics. The method uses coupled optical and acoustic mea
Authors
B.D. Downing, E. Boss, B.A. Bergamaschi, J.A. Fleck, M. A. Lionberger, N. K. Ganju, D. H. Schoellhamer, R. Fujii

Fluorescence-based proxies for lignin in freshwater dissolved organic matter

Lignin phenols have proven to be powerful biomarkers in environmental studies; however, the complexity of lignin analysis limits the number of samples and thus spatial and temporal resolution in any given study. In contrast, spectrophotometric characterization of dissolved organic matter (DOM) is rapid, noninvasive, relatively inexpensive, requires small sample volumes, and can even be measured in
Authors
Peter J. Hernes, Brian A. Bergamaschi, Robert S. Eckard, Robert G.M. Spencer

High-frequency in situ optical measurements during a storm event: Assessing relationships between dissolved organic matter, sediment concentrations, and hydrologic processes

Dissolved organic matter (DOM) dynamics during storm events has received considerable attention in forested watersheds, but the extent to which storms impart rapid changes in DOM concentration and composition in highly disturbed agricultural watersheds remains poorly understood. In this study, we used identical in situ optical sensors for DOM fluorescence (FDOM) with and without filtration to cont
Authors
John Franco Saraceno, Brian A. Pellerin, Bryan D. Downing, Emmanuel Boss, Philip A. M. Bachand, Brian A. Bergamaschi

The role of hydrologic regimes on dissolved organic carbon composition in an agricultural watershed

Willow Slough, a seasonally irrigated agricultural watershed in the Sacramento River valley, California, was sampled weekly in 2006 in order to investigate seasonal concentrations and compositions of dissolved organic carbon (DOC). Average DOC concentrations nearly doubled from winter baseflow (2.75 mg L-1) to summer irrigation (5.14 mg L-1), while a concomitant increase in carbon-normalized vanil
Authors
P.J. Hernes, R.G.M. Spencer, R.Y. Dyda, B.A. Pellerin, P.A.M. Bachand, B.A. Bergamaschi

Assessing contribution of DOC from sediments to a drinking-water reservoir using optical profiling

Understanding the sources of dissolved organic carbon (DOC) in drinking-water reservoirs is an important management issue because DOC may form disinfection by-products, interfere with disinfection, or increase treatment costs. DOC may be derived from a host of sources-algal production of DOC in the reservoir, marginal production of DOC from mucks and vascular plants at the margins, and sediments i
Authors
Bryan D. Downing, Brian A. Bergamaschi, David G. Evans, Emmanuel Boss

Assessing the contribution of wetlands and subsided islands to dissolved organic matter and disinfection byproduct precursors in the Sacramento-San Joaquin River Delta: A geochemical approach

This study assesses how rivers, wetlands, island drains and open water habitats within the Sacramento-San Joaquin River Delta affect dissolved organic matter (DOM) content and composition, and disinfection byproduct (DBP) formation. Eleven sites representative of these habitats were sampled on six dates to encompass seasonal variability. Using a suite of qualitative analyses, including specific DB
Authors
T.E.C. Kraus, B.A. Bergamaschi, P.J. Hernes, R.G.M. Spencer, R. Stepanauskas, C. Kendall, R.F. Losee, R. Fujii

Diurnal variability in riverine dissolved organic matter composition determined by in situ optical measurement in the San Joaquin River (California, USA)

Dissolved organic matter (DOM) concentration and composition in riverine and stream systems are known to vary with hydrological and productivity cycles over the annual and interannual time scales. Rivers are commonly perceived as homogeneous with respect to DOM concentration and composition, particularly under steady flow conditions over short time periods. However, few studies have evaluated the
Authors
R.G.M. Spencer, B.A. Pellerin, B.A. Bergamaschi, B.D. Downing, T.E.C. Kraus, D.R. Smart, R.A. Dahlgren, P.J. Hernes

Alteration of soil microbial communities and water quality in restored wetlands

Land usage is a strong determinant of soil microbial community composition and activity, which in turn determine organic matter decomposition rates and decomposition products in soils. Microbial communities in permanently flooded wetlands, such as those created by wetland restoration on Sacramento-San Joaquin Delta islands in California, function under restricted aeration conditions that result in
Authors
D.A. Bossio, J.A. Fleck, K.M. Scow, R. Fujii