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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4047

Coupling of hydrologic transport and chemical reactions in a stream affected by acid mine drainage

Experiments in St. Kevin Gulch, an acid mine drainage stream, examined the coupling of hydrologic transport to chemical reactions affecting metal concentrations. Injection of LiCl as a conservative tracer was used to determine discharge and residence time along a 1497-m reach. Transport of metals downstream from inflows of acidic, metal-rich water was evaluated based on synoptic samples of metal c
Authors
B. A. Kimball, R. E. Broshears, K.E. Bencala, Diane M. McKnight

Reduction of nonpoint source contamination of surface water and groundwater by starch encapsulation of herbicides

The loss of the preemergent herbicide atrazine in surface runoff from experimental field plots growing corn (Zea mays L.) was significantly reduced using a starchencapsulated formulation versus a conventional powdered formulation. Field edge losses of starch-encapsulated atrazine were described as following a Rayleigh distribution totaling 1.8% of applied herbicide compared to exponential powdered
Authors
M. S. Mills, E. M. Thurman

Testing and comparison of four ionic tracers to measure stream flow loss by multiple tracer injection

The ionic tracers lithium, sodium, chloride and bromide were used to measure flow loss in a small stream (≈︁ 10 ls−1). An injectate containing all four tracers was added continuously at five sites along a 507 m study reach of St Kevin Gulch, Lake County, Colorado to determine which sections of the stream were losing water to the stream bed and to ascertain how well the four tracers performed. The
Authors
G. W. Zellweger

Formation and transport of deethylatrazine and deisopropylatrazine in surface water

No abstract available. 
Authors
E. M. Thurman, M. T. Meyer, M. S. Mills, L.R. Zimmerman, C. A. Perry, D. A. Goolsby

Herbicide interchange between a stream and the adjacent alluvial aquifer

Herbicide interchange between a stream and the adjacent alluvial aquifer and quantification of herbicide bank storage during high streamflow were investigated at a research site on the Cedar River flood plain, 10 km southeast of Cedar Rapids, Iowa. During high streamflow in March 1990, alachlor, atrazine, and metolachlor were detected at concentrations above background in water from wells as dista
Authors
Wuncheng Wang, P. Squillace

Degradation of methyl bromide in anaerobic sediments

No abstract available.
Authors
R.S. Oremland, L.G. Miller, F.E. Strohmaler

Preferential dealkylation reactions of s-triazine herbicides in the unsaturated zone

The preferential dealkylation pathways of the s-triazine herbicides, atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine), propazine [2-chloro-4,6-bis(isopropylamino)-s-triazine], and simazine [2-chloro-4,6-bis(ethylamino)-s-triazine], and two monodealkylated triazine metabolites, deisopropylatrazine (DIA: 2-amino-4-chloro-6-ethylamino-s-triazine) and deethylatrazine (DEA: 2-amino-4-chloro
Authors
M. S. Mills, Thurman E. Michael

Behavior of pollutant-degrading microorganisms in aquifers: Predictions for genetically engineered organisms

Bioremediation via environmental introductions of degradative microorganisms requires that the microbes survive in substantial numbers and effect an increase in the rate and extent of pollutant removal. Combined field and microcosm studies were used to assess these abilities for laboratory-grown bacteria. Following introduction into a contaminated aquifer, viable cells of Pseudomonas sp. B13 were
Authors
M.L. Krumme, R. L. Smith, J. Egestorff, S.M. Thiem, J.M. Tiedje, K.N. Timmis, D.F. Dwyer

Effects of polar and nonpolar groups on the solubility of organic compounds in soil organic matter

Vapor sorption capacities on a high-organic-content peat, a model for soil organic matter (SOM), were determined at room temperature for the following liquids: n-hexane, 1,4-dioxane, nitroethane, acetone, acetonitrile, 1-propanol, ethanol, and methanol. The linear organic vapor sorption is in keeping with the dominance of vapor partition in peat SOM. These data and similar results of carbon tetrac
Authors
C. T. Chiou, D. E. Kile

Model for dolomite formation in northwest Florida

Petrographic methods are used to examine the nature of the Floridan post-Oligocene unconformity and diagenetic responses in the associated carbonate units. The study addresses the depositional environment and the character of sediments associated with the unconformity, types and timing of diagenetic changes, and mode of dolomitization for the Suwannee Limestone dolomites and basal Hawthorn Group d
Authors
C.R. Cooper, J.A. Tindall

'The Kesterson effect'

Hypothesized to be derived from Cretaceous marine sedimentary rocks, selenium contamination of the Kesterson National Wildlife Refuge is traced through irrigation drainage to the source bedrock of the California Coast Ranges. This biogeochemical pathway of selenium is defined here as the 'Kesterson effect.' At the refuge ponds, this effect culminated in 1983 in a 64% rate of deformity and death of
Authors
T. S. Presser

Autotrophic, hydrogen-oxidizing, denitrifying bacteria in groundwater, potential agents for bioremediation of nitrate contamination

Addition of hydrogen or formate significantly enhanced the rate of consumption of nitrate in slurried core samples obtained from an active zone of denitrification in a nitrate-contaminated sand and gravel aquifer (Cape Cod, Mass.). Hydrogen uptake by the core material was immediate and rapid, with an apparent Km of 0.45 to 0.60 μM and a Vmax of 18.7 nmol cm-3 h-1 at 30°C. Nine strains of hydrogen-
Authors
Richard L. Smith, M.L. Ceazan, Myron H. Brooks