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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4047

Automated solid-phase extraction of herbicides from water for gas chromatographic-mass spectrometric analysis

An automated solid-phase extraction (SPE) method was developed for the pre-concentration of chloroacetanilide and triazine herbicides, and two triazine metabolites from 100-ml water samples. Breakthrough experiments for the C18 SPE cartridge show that the two triazine metabolites are not fully retained and that increasing flow-rate decreases their retention. Standard curve r2 values of 0.998–1.000
Authors
M. T. Meyer, M. S. Mills, E. M. Thurman

Effects of climatic variations over 11 years on nitrate-nitrogen concentrations in the Raccoon River, Iowa

Nitrate-nitrogen (NO3-N) concentrations at public water supply intakes on the Des Moines and Raccoon Rivers in Iowa exceeded the maximum contaminant level (MCL) of 10 mg L-1 for public water supplies established by the USEPA for extended periods of time from March through early August 1990. The excessive NO3-N levels followed 2 yr of less-than normal precipitation in 1988 and 1989. The largest dai
Authors
K.J. Lucey, D. A. Goolsby

Assessing the effect of pesticides in agricultural runoff on aquatic life in the Sangamon River near Monticello, Illinois

Stream-water samples collected from a midwest stream, following a thunderstorm during May 1991 were toxic to water fleas (Ceriodaphnia dubia), but not fathead minnows (Pimephales promelas), or a bacterium (Photobacterium phosphoreum) or green alga (Selenastrum capricornutum). It was unlikely that the toxicity to the water fleas was caused by herbicides, but it may have been caused by insecticides.
Authors
R.H. Coupe, M.S. Henebry, M.R. Branham

Crude oil in a shallow sand and gravel aquifer—I. Hydrogeology and inorganic geochemistry

Changes in the distribution of inorganic solutes in a shallow ground water contaminated by crude oil document a series of geochemical reactions initiated by biodegradation of the oil. Upgradient of an oil body floating on the water table, oxidation of oil to carbonic acid dissolves carbonate minerals in the aquifer matrix. In this oxidized zone pH is depressed ∼1 pH unit, and the concentrations of
Authors
P.C. Bennett, D.E. Siegel, M.J. Baedecker, M. F. Hult

Using borehole geophysics and cross-borehole flow testing to define hydraulic connections between fracture zones in bedrock aquifers

Nearly a decade of intensive geophysical logging at fractured rock hydrology research sites indicates that geophysical logs can be used to identify and characterize fractures intersecting boreholes. However, borehole-to-borehole flow tests indicate that only a few of the apparently open fractures found to intersect boreholes conduct flow under test conditions. This paper presents a systematic appr
Authors
Frederick L. Paillet

A brief history of the American radium industry and its ties to the scientific community of its early twentieth century

Federally funded remedial action projects are presently underway in New Jersey and Colorado at sites containing 226Ra and other radionuclides from radium-uranium ore extraction plants that operated during the early twentieth century. They are but the latest chapter in the story of an American industry that emerged and perished in the span of three decades. Major extraction plants were established
Authors
E. R. Landa

Crude oil in a shallow sand and gravel aquifer-II. Organic geochemistry

Crude oil spilled from a pipeline break in a remote area of north-central Minnesota has contaminated a shallow glacial outwash aquifer. Part of the oil was sprayed over a large area to the west of the pipeline and part of it accumulated in an oil body that floats at the water table to the east of the point of discharge. Total dissolved organic carbon (TDOC) concentrations in shallow groundwater co
Authors
R.P. Eganhouse, M.J. Baedecker, I.M. Cozzarelli, G. R. Aiken, K. A. Thorn, T.F. Dorsey

Analysis of flow in an observation well intersecting a single fracture

A semi-analytical model is developed to determine transmissivity and storativity from the interpretation of transient flow in an observation well due to pumping in a source well where the two wells are connected by a single fracture. Flow rate can be determined using a heat-pulse flowmeter located above the intersection of the fracture in the observation well. The results of a field experiment wer
Authors
P.A. Lapcevic, K.S. Novakowski, Frederick L. Paillet

Dissolved sulfides in the oxic water column of San Francisco Bay, California

Trace contaminants enter major estuaries such as San Francisco Bay from a variety of point and nonpoint sources and may then be repartitioned between solid and aqueous phases or altered in chemical speciation. Chemical speciation affects the bioavailability of metals as well as organic ligands to planktonic and benthic organisms, and the partitioning of these solutes between phases. Our previous,
Authors
J.S. Kuwabara, G.W. Luther