The Mitu Group consists of generally coarse clastic strata and volcanic rock of Permian and (or) Triassic age filling elongate basins that parallel the general structural trend of the Peruvian Andes. Volcanic rocks of the Mitu Group include peralkaline and nonperalkaline rhyolite and subalkaline basalt. To our knowledge, the peralkaline rhyolites are the first of this rock type reported from South America. The presence of appreciable volumes of peralkaline rhyolite and basalt, supports the interpretation that the Mitu Group was deposited in major graben structures that resulted from lithospheric extension produced by rifting or possible backarc extension.