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Critical behavior of dilute NaCl in H2O

January 1, 1987

The compositions of the saturated vapor and liquid phases are measured for the system NaCl-H2O at 380°C, which is close to the critical point of pure water. The shape of the phase equilibrium curve is classical, which confirms a conclusion reached earlier on the basis of less accurate data. This implies that the long-range forces introduced by the NaCl suppress the non-classical effects present in pure H2O. An empirical equation of a classical type fits these data.

Publication Year 1987
Title Critical behavior of dilute NaCl in H2O
DOI 10.1016/0009-2614(87)80014-3
Authors Kenneth S. Pitzer, James L. Bischoff, Robert J. Rosenbauer
Publication Type Article
Publication Subtype Journal Article
Series Title Chemical Physics Letters
Index ID 70015141
Record Source USGS Publications Warehouse
USGS Organization Pacific Coastal and Marine Science Center