Direct observations of hydrologic exchange occurring with less‐mobile porosity and the development of anoxic microzones in sandy lakebed sediments

Quantifying coupled mobile/less‐mobile porosity dynamics is critical to the prediction of biogeochemical storage, release, and transformation processes in the zone where groundwater and surface water exchange. The recent development of fine‐scale geoelectrical monitoring paired with pore‐water sampling in groundwater systems enables direct characterization of hydrologic exchange between more‐ and less‐mobile porosity during tracer tests. We adapt this technique to sandy interface sediments at a groundwater flow‐through kettle lake. Tracer experiments were conducted within controlled‐head permeameters over a range of specified downward flow conditions over several days. Although the bed was predominantly composed of highly permeable sands and gravels, cobble inclusions created less‐mobile flow zones at the centimeter scale. Less‐mobile porosity fractions, residence times, and rates of exchange were inferred from paired bulk and fluid electrical conductivity data, without the need for inverse model calibration. The conservative solute experiments were paired with ¹⁵NO₃⁻ and other reactive amendments, revealing anaerobic processes occurring at shallow sediment depths where pore‐water sampling indicated bulk‐oxic conditions. The average less‐mobile porosity residence times as evaluated with the geoelectrical method were on 1‐hr timescales, which appear to be biogeochemically important in the context of creating anoxic microzones within less‐mobile porosity of sandy interface sediments.