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Isolation and structural proof of the large diamond molecule, cyclohexamantane (C26H30)

January 1, 2003

Ace of diamonds: Cyclohexamantane (C26H30), a large diamond-like molecule containing six peri-fused adamantane cages was identified in petroleum and its structure proven by X-ray crystallography (see picture), Never synthesized because of severe mechanistic difficulties, the structure of cyclohexamantane has appeared in theoretical molecular-simulation studies related to diamond; its experimentally determined properties are now discussed.

Publication Year 2003
Title Isolation and structural proof of the large diamond molecule, cyclohexamantane (C26H30)
DOI 10.1002/anie.200250794
Authors J.E.P. Dahl, J.M. Moldowan, T.M. Peakman, J.C. Clardy, E. Lobkovsky, M.M. Olmstead, P.W. May, T.J. Davis, J.W. Steeds, K. E. Peters, A. Pepper, A. Ekuan, R.M.K. Carlson
Publication Type Article
Publication Subtype Journal Article
Series Title Angewandte Chemie - International Edition
Index ID 70026107
Record Source USGS Publications Warehouse