Rare earth element evidence for the petrogenesis of the banded series of the Stillwater Complex, Montana, and its anorthosites

A rare earth element (REE) study was made by isotope-dilution mass spectrometry of plagioclase separates from a variety of cumulates stratigraphically spanning the Banded series of the Stillwater Complex, Montana. Evaluation of parent liquid REE patterns, calculated on the basis of published plagioclase-liquid partition coefficients, shows that the range of REE ratios is too large to be attributable to fractionation of a single magma type. At least two different parental melts were present throughout the Banded series. This finding supports hypotheses of previous workers that the Stillwater Complex formed from two different parent magma types, designated the anorthositic- or A-type liquid and the ultramafic- or U-type liquid. On the basis of our data, one melt has a REE pattern with a distinctive shallow slope and is represented by samples from the thick, massive Anorthosite zones I and II (AN I and AN II) of the Middle Banded series. Although samples from AN I and AN II are separated by as much as 1400 m stratigraphically, they have remarkably similar calculated parent liquid characteristics, with (Ce/Sm)n = 1.7–1.9, (Nd/Sm)n = 1.3–1.4 and (Ce/Yb)n = 2.9–4.6 (where n denotes chondrite-normalized). These calculated liquids are probably close to representing A-type magma. In addition, plagioclase-bronzite cumulates from Norite zones I and II (N I and N II), although thought to be U-type cumulates, contain plagioclase that has A-type REE characteristics, implying that A-type magmas were injected into the magma chamber during formation of those zones. In contrast, calculated parent liquids of cumulus augite-bearing rocks have REE patterns that display distinctly steeper slopes than the A-type REE pattern. The extreme is the calculated parent liquid of a plagioclase-bronzite-augite cumulated with (Ce/Sm)n = 2.9, (Nd/Sm)n = 1.7, and (Ce/Yb)n = 10.1.