Vacuum-jacketed hydrofluoric acid solution calorimeter
January 1, 1965
A vacuum‐jacketed metal calorimeter for determining heats of solution in aqueous HF was constructed. The reaction vessel was made of copper and was heavily gold plated. The calorimeter has a cooling constant of 0.6 cal‐deg−1‐min−1, approximately ¼ that of the air‐jacketed calorimeters most commonly used with HF. It reaches equilibrium within 10 min after turning off the heater current. Measurements of the heat of solution of reagent grade KCl(−100 mesh dried 2 h at 200°C) at a mole ratio of 1 KCl to 200 H2O gave ΔH = 4198±11 cal at 25°C.
Citation Information
Publication Year | 1965 |
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Title | Vacuum-jacketed hydrofluoric acid solution calorimeter |
DOI | 10.1063/1.1719605 |
Authors | R. A. Robie |
Publication Type | Article |
Publication Subtype | Journal Article |
Series Title | Review of Scientific Instruments |
Index ID | 70010523 |
Record Source | USGS Publications Warehouse |