Robert Gale, PhD (Former Employee)
Science and Products
Filter Total Items: 41
Evaluation of persistent hydrophobic organic compounds in the Columbia River Basin using semipermeable-membrane devices
Persistent hydrophobic organic compounds are of concern in the Columbia River because they have been correlated with adverse effects on wildlife. We analysed samples from nine main-stem and six tributary sites throughout the Columbia River Basin (Washington and Oregon) for polychlorinated dibenzo-p-dioxins, dibenzofurans, polychlorinated biphenyls, organochlorine pesticides, and priority-pollutant
Authors
K. A. McCarthy, R.W. Gale
Evaluation of planar halogenated and polycyclic aromatic hydrocarbons in estuarine sediments using ethoxyresorufin-O-deethylase induction of H4IIE cells
Polycyclic aromatic hydrocarbons (PAHs) and planar halogenated hydrocarbons (PHHs), including polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), and biphenyls (PCBs) were determined in fractionated sediment extracts from the Hudson-Raritan estuary and Newark Bay, New Jersey, USA, as part of a comprehensive risk assessment. Contributions of PCDDs/PCDFs, PCBs, and PAHs to the total to
Authors
R.W. Gale, E.R. Long, T.R. Schwartz, D. E. Tillitt
Comparing polychlorinated biphenyl concentrations and patterns in the Saginaw River using sediment, caged fish, and semipermeable membrane devices
Three techniques of assessing bioavailable polychlorinated biphenyls (PCBs) in the Saginaw River, MI, were compared: sediments, caged fish, and semipermeable membrane devices (SPMDs). SPMDs and caged fish were placed in the river for 28 days at five sites where sediments were also sampled. The samples were analyzed for PCB congeners to determine concentrations and patterns. Total PCB concentration
Authors
K. R. Echols, R.W. Gale, T.R. Schwartz, J.N. Huckins, L.L. Williams, J.C. Meadows, D. Morse, J. D. Petty, C.E. Orazio, D. E. Tillitt
Considerations involved with the use of semipermeable membrane devices for monitoring environmental contaminants
Semipermeable membrane devices (SPMDs) are used with increasing frequency, and throughout the world as samplers of organic contaminants. The devices can be used to detect a variety of lipophilic chemicals in water, sediment/soil, and air. SPMDs are designed to sample nonpolar, hydrophobic chemicals. The maximum concentration factor achievable for a particular chemical is proportional to its octano
Authors
J. D. Petty, C.E. Orazio, J.N. Huckins, R.W. Gale, J.A. Lebo, J.C. Meadows, K. R. Echols, W.L. Cranor
Polychlorinated biphenyls and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents in tree swallows from the upper Hudson River, New York State, USA
The upper Hudson River of New York State, USA, is contaminated with polychlorinated biphenyls (PCBs) as a result of industrial discharges throughout the latter half of this century. In 1994 and 1995, we monitored the transfer of PCBs from aquatic sediments to a terrestrial wildlife community using the tree swallow (Tachycineta bicolor) as a model organism. Tree swallow eggs and nestlings were coll
Authors
Anne L. Secord, John P. McCarty, Kathy R. Echols, John C. Meadows, Robert W. Gale, Donald E. Tillitt
Investigation of the distribution of organochlorine and polycyclic aromatic hydrocarbon compounds in the Lower Columbia River using semipermeable-membrane devices
Organochlorine and polycyclic aromatic hydrocarbon compounds are of concern in the Columbia River Basin because of their adverse effects on fish and wildlife. Because these compounds can have important biological consequences at concentrations well below the detection limits associated with conventional water-sampling techniques, we used semipermeable membrane devices (SPMDs) to sample water, and
Authors
Kathleen A. McCarthy, Robert W. Gale
Loading capacity and chromatographic behavior of a porous graphitic carbon column for polychlorinated biphenyls
A porous graphitic carbon column (Hypercarb) was used for the fractionation of polychlorinated biphenyls (PCBs) into classes of 2-4 ortho chlorines, 1 ortho chlorine and 0 ortho chlorine congeners. A method was developed that combined the fractionation of PCBs, polychlorinated dibenzo-p-dioxins and dibenzofurans in a variety of biotic environmental samples. Many of these samples have high concentr
Authors
K. R. Echols, R.W. Gale, K. Feltz, J. O'Laughlin, D. E. Tillitt, T.R. Schwartz
Three-compartment model for contaminant accumulation by semipermeable membrane devices
Passive sampling of dissolved hydrophobic contaminants with lipid (triolein)-containing semipermeable membrane devices (SPMDs) has been gaining acceptance for environmental monitoring. Understanding of the accumulation process has employed a simple polymer film-control model of uptake by the polymer-enclosed lipid, while aqueous film control has been only briefly discussed. A more complete three-c
Authors
Robert W. Gale
Polychlorinated dibenzo-p-dioxins, dibenzofurans, biphenyls and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents in fishes from Saginaw Bay, Michigan
Concentrations of polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated naphthalenes (PCNs), polychlorinated dibenzothiophenes (PCDTs), and 2,3,7,8-tetrachlo-rodibenzo-p-dioxin (2,3,7,8-TCDD) equivalents were measured in composite samples of forage fishes and several sizes of walleyes (Stizostedion vitreum) and common ca
Authors
John P. Giesy, David J. Jude, Donald E. Tillitt, Robert W. Gale, John C. Meadows, James L. Zajieck, Paul H. Peterman, David A. Verbrugge, J. Thomas Sanderson, Ted R. Schwartz, Marc L. Tuchman
An automated HPLC method for the fractionation of polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, and polychlorinated dibenzofurans in fish tissue on a porous graphitic carbon column
The Ah (aryl-hydrocarbon) hydroxylase-receptor active polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were fractionated by an automated high-performance liquid chromatography (HPLC) system using the Hypercarb™ porous graphitic carbon (PGC) column. This commercially available column was used to fractionate the di-, mono-, and non
Authors
Kathy R. Echols, Robert W. Gale, Donald E. Tillitt, Ted R. Schwartz, Jerome O'Laughlin
Organochlorine contaminants in double-crested cormorants from Green Bay, WI: I. Large-scale extraction and isolation from eggs using semi-permeable membrane dialysis
A 41.3-kg sample of double-crested cormorant (Phalacrocorax auritus) egg contents was extracted, yielding over 2 L of egg lipid. The double-crested cormorant (DCC) egg extract, after clean-up and concentration, was intended for use in egg injection studies to determine the embryotoxicity of the organic contaminants found within the eggs. Large-scale dialysis was used as a preliminary treatment to
Authors
J.C. Meadows, D. E. Tillitt, T.R. Schwartz, D.J. Schroeder, K. R. Echols, R.W. Gale, D.C. Powell, S.J. Bursian
Comparison of the uptake of dioxin-like compounds by caged channel catfish and semipermeable membrane devices in the Saginaw River, Michigan
Elevated concentrations of planar, halogenated hydrocarbons have been linked to reproductive problems in a variety of fish-eating birds and mammals in the Great Lakes and in particular Saginaw Bay. Currently, there are no accurate procedures to assess bioavailability of these contaminants. Polychlorinated dibenzo-p-dioxins and dibenzofurans and mono- and non-ortho-chloro-substituted biphenyls in w
Authors
Robert W. Gale, James N. Huckins, Jimmie D. Petty, Paul H. Peterman, Lisa L. Williams, Douglas Morse, Ted R. Schwartz, Donald E. Tillitt
Science and Products
Filter Total Items: 41
Evaluation of persistent hydrophobic organic compounds in the Columbia River Basin using semipermeable-membrane devices
Persistent hydrophobic organic compounds are of concern in the Columbia River because they have been correlated with adverse effects on wildlife. We analysed samples from nine main-stem and six tributary sites throughout the Columbia River Basin (Washington and Oregon) for polychlorinated dibenzo-p-dioxins, dibenzofurans, polychlorinated biphenyls, organochlorine pesticides, and priority-pollutant
Authors
K. A. McCarthy, R.W. Gale
Evaluation of planar halogenated and polycyclic aromatic hydrocarbons in estuarine sediments using ethoxyresorufin-O-deethylase induction of H4IIE cells
Polycyclic aromatic hydrocarbons (PAHs) and planar halogenated hydrocarbons (PHHs), including polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), and biphenyls (PCBs) were determined in fractionated sediment extracts from the Hudson-Raritan estuary and Newark Bay, New Jersey, USA, as part of a comprehensive risk assessment. Contributions of PCDDs/PCDFs, PCBs, and PAHs to the total to
Authors
R.W. Gale, E.R. Long, T.R. Schwartz, D. E. Tillitt
Comparing polychlorinated biphenyl concentrations and patterns in the Saginaw River using sediment, caged fish, and semipermeable membrane devices
Three techniques of assessing bioavailable polychlorinated biphenyls (PCBs) in the Saginaw River, MI, were compared: sediments, caged fish, and semipermeable membrane devices (SPMDs). SPMDs and caged fish were placed in the river for 28 days at five sites where sediments were also sampled. The samples were analyzed for PCB congeners to determine concentrations and patterns. Total PCB concentration
Authors
K. R. Echols, R.W. Gale, T.R. Schwartz, J.N. Huckins, L.L. Williams, J.C. Meadows, D. Morse, J. D. Petty, C.E. Orazio, D. E. Tillitt
Considerations involved with the use of semipermeable membrane devices for monitoring environmental contaminants
Semipermeable membrane devices (SPMDs) are used with increasing frequency, and throughout the world as samplers of organic contaminants. The devices can be used to detect a variety of lipophilic chemicals in water, sediment/soil, and air. SPMDs are designed to sample nonpolar, hydrophobic chemicals. The maximum concentration factor achievable for a particular chemical is proportional to its octano
Authors
J. D. Petty, C.E. Orazio, J.N. Huckins, R.W. Gale, J.A. Lebo, J.C. Meadows, K. R. Echols, W.L. Cranor
Polychlorinated biphenyls and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents in tree swallows from the upper Hudson River, New York State, USA
The upper Hudson River of New York State, USA, is contaminated with polychlorinated biphenyls (PCBs) as a result of industrial discharges throughout the latter half of this century. In 1994 and 1995, we monitored the transfer of PCBs from aquatic sediments to a terrestrial wildlife community using the tree swallow (Tachycineta bicolor) as a model organism. Tree swallow eggs and nestlings were coll
Authors
Anne L. Secord, John P. McCarty, Kathy R. Echols, John C. Meadows, Robert W. Gale, Donald E. Tillitt
Investigation of the distribution of organochlorine and polycyclic aromatic hydrocarbon compounds in the Lower Columbia River using semipermeable-membrane devices
Organochlorine and polycyclic aromatic hydrocarbon compounds are of concern in the Columbia River Basin because of their adverse effects on fish and wildlife. Because these compounds can have important biological consequences at concentrations well below the detection limits associated with conventional water-sampling techniques, we used semipermeable membrane devices (SPMDs) to sample water, and
Authors
Kathleen A. McCarthy, Robert W. Gale
Loading capacity and chromatographic behavior of a porous graphitic carbon column for polychlorinated biphenyls
A porous graphitic carbon column (Hypercarb) was used for the fractionation of polychlorinated biphenyls (PCBs) into classes of 2-4 ortho chlorines, 1 ortho chlorine and 0 ortho chlorine congeners. A method was developed that combined the fractionation of PCBs, polychlorinated dibenzo-p-dioxins and dibenzofurans in a variety of biotic environmental samples. Many of these samples have high concentr
Authors
K. R. Echols, R.W. Gale, K. Feltz, J. O'Laughlin, D. E. Tillitt, T.R. Schwartz
Three-compartment model for contaminant accumulation by semipermeable membrane devices
Passive sampling of dissolved hydrophobic contaminants with lipid (triolein)-containing semipermeable membrane devices (SPMDs) has been gaining acceptance for environmental monitoring. Understanding of the accumulation process has employed a simple polymer film-control model of uptake by the polymer-enclosed lipid, while aqueous film control has been only briefly discussed. A more complete three-c
Authors
Robert W. Gale
Polychlorinated dibenzo-p-dioxins, dibenzofurans, biphenyls and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents in fishes from Saginaw Bay, Michigan
Concentrations of polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated naphthalenes (PCNs), polychlorinated dibenzothiophenes (PCDTs), and 2,3,7,8-tetrachlo-rodibenzo-p-dioxin (2,3,7,8-TCDD) equivalents were measured in composite samples of forage fishes and several sizes of walleyes (Stizostedion vitreum) and common ca
Authors
John P. Giesy, David J. Jude, Donald E. Tillitt, Robert W. Gale, John C. Meadows, James L. Zajieck, Paul H. Peterman, David A. Verbrugge, J. Thomas Sanderson, Ted R. Schwartz, Marc L. Tuchman
An automated HPLC method for the fractionation of polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, and polychlorinated dibenzofurans in fish tissue on a porous graphitic carbon column
The Ah (aryl-hydrocarbon) hydroxylase-receptor active polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were fractionated by an automated high-performance liquid chromatography (HPLC) system using the Hypercarb™ porous graphitic carbon (PGC) column. This commercially available column was used to fractionate the di-, mono-, and non
Authors
Kathy R. Echols, Robert W. Gale, Donald E. Tillitt, Ted R. Schwartz, Jerome O'Laughlin
Organochlorine contaminants in double-crested cormorants from Green Bay, WI: I. Large-scale extraction and isolation from eggs using semi-permeable membrane dialysis
A 41.3-kg sample of double-crested cormorant (Phalacrocorax auritus) egg contents was extracted, yielding over 2 L of egg lipid. The double-crested cormorant (DCC) egg extract, after clean-up and concentration, was intended for use in egg injection studies to determine the embryotoxicity of the organic contaminants found within the eggs. Large-scale dialysis was used as a preliminary treatment to
Authors
J.C. Meadows, D. E. Tillitt, T.R. Schwartz, D.J. Schroeder, K. R. Echols, R.W. Gale, D.C. Powell, S.J. Bursian
Comparison of the uptake of dioxin-like compounds by caged channel catfish and semipermeable membrane devices in the Saginaw River, Michigan
Elevated concentrations of planar, halogenated hydrocarbons have been linked to reproductive problems in a variety of fish-eating birds and mammals in the Great Lakes and in particular Saginaw Bay. Currently, there are no accurate procedures to assess bioavailability of these contaminants. Polychlorinated dibenzo-p-dioxins and dibenzofurans and mono- and non-ortho-chloro-substituted biphenyls in w
Authors
Robert W. Gale, James N. Huckins, Jimmie D. Petty, Paul H. Peterman, Lisa L. Williams, Douglas Morse, Ted R. Schwartz, Donald E. Tillitt