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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4047

Terrestrial ecological risk analysis via dietary exposure at uranium mine sites in the Grand Canyon watershed (Arizona, USA)

The U.S. Department of the Interior recently included uranium (U) on a list of mineral commodities that are considered critical to economic and national security. The uses of U for commercial and residential energy production, defense applications, medical device technologies, and energy generation for space vehicles and satellites are known, but the environmental impacts of uranium extraction are
Authors
Jo Ellen Hinck, Danielle M. Cleveland, Bradley E. Sample

Retrospective analysis of estrogenic endocrine disruption and land-use influences in the Chesapeake Bay watershed

The Chesapeake Bay is the largest estuary in the United States and its watershed includes river drainages in six states and the District of Columbia. Sportfishing is of major economic interest, however, the rivers within the watershed provide numerous other ecological, recreational, cultural and economic benefits, as well as serving as a drinking water source for millions of people. Consequently,
Authors
Vicki S. Blazer, Stephanie Gordon, Daniel Jones, Luke R. Iwanowicz, Heather L. Walsh, Adam Sperry, Kelly L. Smalling

Development and testing of species-specific quantitative PCR assays for environmental DNA applications

New, non-invasive methods for detecting and monitoring species presence are being developed to aid in fisheries and wildlife conservation management. The use of environmental DNA (eDNA) samples for detecting macrobiota is one such group of methods that is rapidly becoming popular and being implemented in national management programs. Here we focus on the development of species-specific targeted as
Authors
Katy E. Klymus, Dannise Vannesa Ruiz Ramos, Nathan Thompson, Catherine A. Richter

Assessing uranium and select trace elements associated with breccia pipe uranium deposits in the Colorado River and main tributaries in Grand Canyon, USA

Assessing chemical loading from streams in remote, difficult-to-access watersheds is challenging. The Grand Canyon area in northern Arizona, an international tourist destination and sacred place for many Native Americans, is characterized by broad plateaus divided by canyons as much as two-thousand meters deep and hosts some of the highest-grade uranium deposits in the U.S. From 2015–2018 major su
Authors
Fred D. Tillman, Jessica R. Anderson, Joel A. Unema, Thomas Chapin

Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota

A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This additional remedi

Authors
Geoffrey N. Delin, William N. Herkelrath, Jared J. Trost

Transport and speciation of uranium in groundwater-surface water systems impacted by legacy milling operations

Growing worldwide concern over uranium contamination of groundwater resources has placed an emphasis on understanding uranium transport dynamics and potential toxicity in groundwater-surface water systems. In this study, we utilized novel in-situ sampling methods to establish the location and magnitude of contaminated groundwater entry into a receiving surface water environment, and to investigate
Authors
Patrick A. Byrne, Christopher C. Fuller, David L. Naftz, Robert L. Runkel, Niklas J Lehto, William L Dam

Differences in neonicotinoid and metabolite sorption to activated carbon are driven by alterations to the insecticidal pharmacophore

Widespread application of neonicotinoids has led to their proliferation in waters. Despite low neonicotinoid hydrophobicity, our prior studies implicated granular activated carbon (GAC) in neonicotinoid removal. Based on known receptor binding characteristics, we hypothesized that the insecticidal pharmacophore influences neonicotinoid sorption. Our objectives were to illuminate drivers of neonico
Authors
Danielle T. Webb, Matthew R. Nagorzanski, Megan M Powers, David M. Cwiertny, Michelle Hladik, Gregory H. LeFevre

Geochemical and geophysical indicators of oil and gas wastewater can trace potential exposure pathways following releases to surface waters

Releases of oil and gas (OG) wastewaters can have complex effects on stream-water quality and downstream organisms, due to sediment-water interactions and groundwater/surface water exchange. Previously, elevated concentrations of sodium (Na), chloride (Cl), barium (Ba), strontium (Sr), and lithium (Li), and trace hydrocarbons were determined to be key markers of OG wastewater releases when combine
Authors
Isabelle M. Cozzarelli, Douglas B. Kent, Martin A. Briggs, Mark A Engle, Adam Benthem, Katherine Skalak, Adam Mumford, Jeanne B. Jaeschke, Aida Farag, John W. Lane, Denise M. Akob

Groundwater discharges as a source of phytoestrogens and other agriculturally derived contaminants to streams

Groundwater discharge zones in streams are important habitats for aquatic organisms. The use of discharge zones for thermal refuge and spawning by fish and other biota renders them susceptible to potential focused discharge of groundwater contamination. Currently, there is a paucity of information about discharge zones as a potential exposure pathway of chemicals to stream ecosystems. Using therma
Authors
Tyler J. Thompson, Martin A. Briggs, Patrick J. Phillips, Vicki S. Blazer, Kelly L. Smalling, Dana W. Kolpin, Tyler Wagner

Effects of early life stage exposure of largemouth bass to atrazine or a model estrogen (17α-ethinylestradiol)

Endocrine disrupting contaminants are of continuing concern for potentially contributing to reproductive dysfunction in largemouth and smallmouth bass in the Chesapeake Bay watershed (CBW) and elsewhere. Exposures to atrazine (ATR) have been hypothesized to have estrogenic effects on vertebrate endocrine systems. The incidence of intersex in male smallmouth bass from some regions of CBW has been c
Authors
Jessica Kristin Leet, Catherine A. Richter, Robert S. Cornman, Jason P. Berninger, Ramji K. Bhandari, Diane K. Nicks, James L. Zajicek, Vicki S. Blazer, Donald E. Tillitt

Occurrence and spatiotemporal dynamics of pharmaceuticals in a temperate-region wastewater effluent-dominated stream: Variable inputs and differential attenuation yield evolving complex exposure mixtures

Effluent-dominated streams are becoming increasingly common in temperate regions and generate complex pharmaceutical mixture exposure conditions that may impact aquatic organisms via drug–drug interactions. Here, we quantified spatiotemporal pharmaceutical exposure concentrations and composition mixture dynamics during baseflow conditions at four sites in a temperate-region effluent-dominated stre
Authors
Hui Zhi, Dana W. Kolpin, R. D. Klaper, Luke R. Iwanowicz, Shannon M. Meppelink, Gregory H. LeFevre

Hydrocarbons to carboxyl-rich alicyclic molecules: A continuum model to describe biodegradation of petroleum-derived dissolved organic matter in contaminated groundwater plumes

Relationships between dissolved organic matter (DOM) reactivity and chemical composition in a groundwater plume containing petroleum-derived DOM (DOMHC) were examined by quantitative and qualitative measurements to determine the source and chemical composition of the compounds that persist downgradient. Samples were collected from a transect down the core of the plume in the direction of groundwat
Authors
David C. Podgorski, Phoebe Zito, Anne M. Kellerman, Barbara A. Bekins, Isabelle M. Cozzarelli, Donald F. Smith, Xiaoyan Cao, Klaus Schmidt-Rohr, Sasha Wagner, Aron Stubbins, Robert G. M. Spencer