Publications
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Effect of copper salts on hydrothermal oxidative decarboxylation: A study of phenylacetic acid
Decarboxylation of carboxylic acids is favored under hydrothermal conditions, and can be influenced by dissolved metals. Here, we use phenylacetic acid as a model compound to study its hydrothermal decarboxylation in the presence of copper(II) salts but no O2. Our results showed a strong oxidizing role of copper in facilitating oxidative decarboxylation.
Authors
Xuan Fu, Megan Jamison, Aaron M. Jubb, Yiju Liao, Alexandria Aspin, Kyle Hayes, Christopher R. Glein, Ziming Yang
Evidence of wildfires and elevated atmospheric oxygen at the Frasnian–Famennian boundary in New York (USA): Implications for the Late Devonian mass extinction
The Devonian Period experienced significant fluctuations of atmospheric oxygen (O2) levels (∼25–13%), for which the extent and timing are debated. Also characteristic of the Devonian Period, at the Frasnian–Famennian (F–F) boundary, is one of the “big five” mass extinction events of the Phanerozoic. Fossilized charcoal (inertinite) provides a record of wildfire events, which in turn can provide in
Authors
Zeyang Liu, David Selby, Paul C. Hackley, Jeffrey Over
Biomarker similarities between the saline lacustrine Eocene Green River and the Paleoproterozoic Barney Creek Formations
The Paleoproterozoic Barney Creek Formation, which is currently interpreted as a restricted, deep marine paleoenvironment, plays a disproportionate role in our understanding of Proterozoic ocean chemistry and the rise of complex life. The Barney Creek Formation hosts several unusual biomarker features, specifically its methylhopane and carotenoid signatures. Herein, we demonstrate that the saline
Authors
Katherine L. French, Justin E. Birdwell, Michael Vanden Berg
Review of studies of composition, toxicology and human health impacts of wastewater from unconventional oil and gas development from shale
Unconventional oil and gas (UOG) extractions has produced large economic benefits. However, prudent management of UOG wastes necessitates a thorough understanding of the complex composition, fate, and potential impacts of wastewater releases. UOG production results in large volumes of wastewater. Despite limited re-use of the wastewater, the majority needs to be disposed of, usually by underground
Authors
Lynn M. Crosby, William H. Orem
Direct trace element determination in oil and gas produced waters with inductively coupled plasma - Optical emission spectrometry (ICP-OES): Advantages of high salinity tolerance
Waters co-produced during petroleum extraction are the largest waste stream from oil and gas development. Reuse or disposal of these waters is difficult due to their high salinities and the sheer volumes generated. Produced waters may also contain valuable mineral commodities. While an understanding of produced water trace element composition is required for evaluating the associated resource and
Authors
Aaron M. Jubb, Mark Engle, Jessica Chenault, Madalyn Blondes, Cloelle G. Danforth, Colin Doolan, Tanya Gallegos, Dan Mueller, Jenna Shelton
Applications of correlative light and electron microscopy (CLEM) to organic matter in the North American shale petroleum systems
Scanning electron microscopy (SEM) has revolutionized our understanding of shale petroleum systems through microstructural characterization of dispersed organic matter (OM). However, due to the low atomic weight of carbon, all OM appears black in SEM (BSE image) regardless of differences in thermal maturity or OM type (kerogen types or solid bitumen). Traditional petrographic identification of OM
Authors
Brett J. Valentine, Paul C. Hackley
Natural gas hydrates: Status of potential as an energy resource
Gas hydrate is a widespread naturally-occurring combination of water and natural gases. Gas hydrate is found in shallow sediments of deepwater regions of the continental margins and in areas of continuous permafrost. Where gas supply is sufficient and migration pathways connect gas sources to favorable reservoirs, gas hydrate can accumulate to resource densities that may be attractive for gas pr
Authors
Ray Boswell, Steve Hancock, Koji Yamamoto, Timothy Collett, Mahendra Pratap, Sung-Rock Lee
Assessment of undiscovered oil and gas resources in the Central North Slope of Alaska, 2020
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean resources of 3.6 billion barrels of oil and 8.9 trillion cubic feet of natural gas (associated and nonassociated) in conventional accumulations in Mississippian through Paleogene strata in the central North Slope of Alaska.
Authors
David W. Houseknecht, Katherine J. Whidden, Christopher D. Connors, Richard O. Lease, Christopher J. Schenk, Tracey J. Mercier, William A. Rouse, Palma J. Botterell, Rebecca A. Smith, Margaret M. Sanders, William H. Craddock, Christina A. DeVera, Christopher P. Garrity, Marc L. Buursink, C. Özgen Karacan, Samuel J. Heller, Thomas E. Moore, Julie A. Dumoulin, Marilyn E. Tennyson, Katherine L. French, Cheryl A. Woodall, Ronald M. Drake, Kristen R. Marra, Thomas M. Finn, Scott A. Kinney, Chilisa M. Shorten
A chemo-mechanical snapshot of in-situ conversion of kerogen to petroleum
Organic matter (OM) from various biogenic origins converts to solid bitumen in-situ when it undergoes thermal maturation. It is well documented that during this process, the ratios of both hydrogen and oxygen to carbon will decrease, resulting in an increase in OM aromaticity and molecular chemo-mechanical homogeneity. Although there have been extensive efforts to reveal molecular alteration occur
Authors
Arash Abarghani, Mehdi Ostadhassan, Paul C. Hackley, Andrew E. Pomerantz, Siamak Nejati
Coal biomethanation potential of various ranks from Pakistan: A possible alternative energy source
The present study investigated the possibility of microbial transformations of coal to gas (biogasification) as an alternative to conventional coal mining because this approach has the potential to be less expensive, cleaner, and providinge greater access to deeper coal resources. Biogasification is often associated with low rank coal such as lignite and subbituminous coal that hasve produced enou
Authors
Aneela Y. Malik, Muhammad Ishtiaq Ali, Asif Jamal, Uzma Farooq, Nazia Khatoon, William H. Orem, Elliott P. Barnhart, John R. SanFilipo, Huan He, Zaixing Huang
Assessment of water and proppant quantities associated with petroleum production from the Eagle Ford Group, Gulf Coast, Texas, 2019
Building on a geology-based assessment of undiscovered, technically recoverable petroleum resources in the Eagle Ford Group in south Texas, the U.S. Geological Survey has estimated the required water and proppant demands and formation water production volumes associated with possible future development of these petroleum resources. The results of the water and proppant assessment are presented her
Authors
Nicholas J. Gianoutsos, Seth S. Haines, Brian A. Varela, Katherine J. Whidden, Justin E. Birdwell, Lauri A. Burke, Ronald M. Drake, Thomas M. Finn, Katherine L. French, Karen E. Jenni, Scott A. Kinney, Phuong A. Le, Heidi M. Leathers-Miller, Kristen R. Marra, Tracey J. Mercier, Stanley T. Paxton, Janet K. Pitman, Christopher J. Schenk, Brian N. Shaffer, Chilisa M. Shorten, Marilyn E. Tennyson, Cheryl A. Woodall
Sulfur isotope composition of individual compounds in immature organic-rich rocks and possible geochemical implications
We applied compound-specific sulfur isotope analysis (CSSIA) to organic matter (OM) extracted from ancient and immature organic-rich rocks from the Cretaceous Ghareb (Shefela Basin locality, Israel) and Miocene Monterey (Naples Beach locality, California, USA) Formations. Large variations in the δ34S values of different organosulfur compounds (OSCs), that reach up to 28‰ and 36‰, were observed in
Authors
Lubna Shawar, Ward Said-Ahmad, Geoffrey S. Ellis, Alon Amrani