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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4094

Measurement of nitrous oxide reductase activity in aquatic sediments

Denitrification in aquatic sediments was measured by an N2O reductase assay. Sediments consumed small added quantities of N2O over short periods (a few hours). In experiments with sediment slurries, N2O reductase activity was inhibited by O2, C2H2, heat treatment, and by high levels of nitrate (1 mM) or sulfide (10 mM). However, ambient levels of nitrate (<100 μM) did not influence activity, and m
Authors
L.G. Miller, Ronald S. Oremland, S. Paulsen

Chemistry of illite/smectite and end-member illite

Chemical data from three different series of diagenetic illite/smectites (I/S), analyzed statistically by two regresion techniques, indicate that the content of fixed-K per illite layer is not constant, but ranges from ∼0.55 per O10(OH)2 for illite layers in randomly interstratified I/S (R=0; > 50% smectite layers) to ∼1.0 per O10(OH)2 for illite layers formed in ordered I/S (R>0; <50% smectite la
Authors
J. Srodon, D.J. Morgan, E.V. Eslinger, D. D. Eberl, M.R. Karlinger

Concentration of trace elements in water samples by reductive precipitation

No abstract available.
Authors
R. K Skogerboe, W.A. Hanagan, Howard E. Taylor

Assessment of the instantaneous unit hydrograph derived from the theory of topologically random networks

An instantaneous unit hydrograph (iuh) based on the theory of topologically random networks (topological iuh) is evaluated in terms of sets of basin characteristics and hydraulic parameters. Hydrographs were computed using two linear routing methods for each of two drainage basins in the southeastern United States and are the basis of comparison for the topological iuh's. Elements in the sets of b
Authors
M.R. Karlinger, B.M. Troutman

Field determination of the three-dimensional hydraulic conductivity tensor of anisotropic media: 1. Theory

A field method is proposed for determining the three-dimensional hydraulic conductivity tensor and specific storage of an anisotropic porous or fractured medium. The method, known as cross-hole testing (to distinguish it from conventional single-hole packer tests), consists of injecting fluid into (or withdrawing fluid from) packed-off intervals in a number of boreholes and monitoring the transien
Authors
Paul A. Hsieh, Shlomo P. Neuman

Biogeochemistry of aquatic humic substances in Thoreau's Bog, Concord, Massachusetts

Thoreau's Bog is an ombrotrophic floating—mat Sphagnum bog developed in a glacial kettlehole and surrounded by a red maple swamp. Concentrations of dissolved organic carbon in the porewater of the bog average 36 mg/L and are greatest near the surface, especially during late summer. This distribution suggest that the upper layer of living and dead Sphagnum and moderately humified peat is the major
Authors
Diane M. McKnight, E. Michael Thurman, Robert L. Wershaw, Herold Hemond

The aqueous photolysis of ethylene glycol adsorbed on geothite

Suspensions of goethite (α-FeOOH) were photolyzed in aerated ethylene glycol-water solutions at pH 6.5, with ultraviolet light in the wavelength range300–400 nm. Under these conditions, formaldehyde and glycolaldehyde were detected as photoproducts. Quantum yields of formaldehyde production ranged from 1.9 7times; 10-5 to 2.9 × 10-4 over the ethylene glycol concentration range of 0.002-2.0 mol/ℓ,
Authors
Kirkwood M. Cunningham, Marvin C. Goldberg, E.R. Weiner

Effects of copper on production of periphyton, nitrogen fixation and processing of leaf litter in a Sierra Nevada, California, stream

1Production of periphyton, nitrogen fixation and processing of leaf litter were examined in an oligotrophic Sierra Nevada stream and the responses of these processes to copper (2.5, 5 and 10μg 1-1 CuT [total filtrable copper]; approximately 12, 25 and 50 ng 1-1 Cu2+) were determined.2Autotrophic and total production were estimated from 3-week accumulations of biomass on artificial substrates. Mean
Authors
Harry V. Leland, James L. Carter

Sorption of lead onto two gram-negative marine bacteria in seawater

Laboratory adsorption experiments performed at environmentally significant lead (Pb) and cell concentrations indicate that the marine bacteria examined have significant binding capacities for Pb. However, the behavior governing Pb sorption onto gram-negative bacteria in seawater may be quite complex. The sorption kinetics appear to involve two distinct phases, i.e., a rapid removal of Pb from solu
Authors
Ronald W. Harvey, James O. Leckie