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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4094

Microbial arsenic metabolism: New twists on an old poison

Phylogenetically diverse microorganisms metabolize arsenic despite its toxicity and are part of its robust iogeochemical cycle. Respiratory arsenate reductase is a reversible enzyme, functioning in some microbes as an arsenate reductase but in others as an arsenite oxidase. As(III) can serve as an electron donor for anoxygenic photolithoautotrophy and chemolithoautotrophy. Organoarsenicals, such a
Authors
J.F. Stolz, P. Basu, Ronald S. Oremland

Mineralogical and chemical characteristics of some natural jarosites

This paper presents a detailed study of the mineralogical, microscopic, thermal, and spectral characteristics of jarosite and natrojarosite minerals. Systematic mineralogic and chemical examination of a suite of 32 natural stoichiometric jarosite and natrojarosite samples from diverse supergene and hydrothermal environments indicates that there is only limited solid solution between Na and K at lo
Authors
George A. Desborough, Kathleen S. Smith, Heather A. Lowers, Gregg A. Swayze, Jane M. Hammarstrom, Sharon F. Diehl, Reinhard W. Leinz, Rhonda L. Driscoll

Comparison of transport and attachment behaviors of Cryptosporidium parvum oocysts and oocyst-sized microspheres being advected through three minerologically different granular porous media

In order to gain more information about the fate of Cryptosporidium parvum oocysts in tropical volcanic soils, the transport and attachment behaviors of oocysts and oocyst-sized polystyrene microspheres were studied in the presence of two soils. These soils were chosen because of their differing chemical and physical properties, i.e., an organic-rich (43–46% by mass) volcanic ash-derived soil from
Authors
Arvind Mohanram, Chittaranjan Ray, Ronald W. Harvey, David W. Metge, Joseph N. Ryan, Jon Chorover, D. D. Eberl

Linking process to pattern: estimating spatiotemporal dynamics of a wildlife epidemic from cross‐sectional data

Underlying dynamic event processes unfolding in continuous time give rise to spatiotemporal patterns that are sometimes observable at only a few discrete times. Such event processes may be modulated simultaneously over several spatial (e.g., latitude and longitude) and temporal (e.g., age, calendar time, and cohort) dimensions. The ecological challenge is to understand the dynamic latent processes
Authors
Dennis M. Heisey, Erik E. Osnas, Paul C. Cross, Damien O. Joly, Julia A. Langenberg, Michael W. Miller

Marine electrical resistivity imaging of submarine groundwater discharge: Sensitivity analysis and application in Waquoit Bay, Massachusetts, USA

Electrical resistivity imaging has been used in coastal settings to characterize fresh submarine groundwater discharge and the position of the freshwater/salt-water interface because of the relation of bulk electrical conductivity to pore-fluid conductivity, which in turn is a function of salinity. Interpretation of tomograms for hydrologic processes is complicated by inversion artifacts, uncertai
Authors
Rory Henderson, Frederick D. Day-Lewis, Elena Abarca, Charles F. Harvey, Hanan N. Karam, Lanbo Liu, John W. Lane

Improved hydrogeophysical characterization and monitoring through parallel modeling and inversion of time-domain resistivity andinduced-polarization data

Electrical geophysical methods have found wide use in the growing discipline of hydrogeophysics for characterizing the electrical properties of the subsurface and for monitoring subsurface processes in terms of the spatiotemporal changes in subsurface conductivity, chargeability, and source currents they govern. Presently, multichannel and multielectrode data collections systems can collect large
Authors
Timothy C. Johnson, Roelof J. Versteeg, Andy Ward, Frederick D. Day-Lewis, André Revil

Use of induced polarization to characterize the hydrogeologic framework of the zone of surface‐water/groundwater exchange at the Hanford 300 Area, WA

An extensive continuous waterborne electrical imaging (CWEI) survey was conducted along the Columbia River corridor adjacent to the U.S. Department of Energy (DOE) Hanford 300 Area, WA, in order to improve the conceptual model for exchange between surface water and U‐contaminated groundwater. The primary objective was to determine spatial variability in the depth to the Hanford‐Ringold (H‐R) conta
Authors
Lee Slater, Dimitrios Ntarlagiannis, Frederick D. Day-Lewis, Kisa Mwakanyamale, John W. Lane, Andy Ward, Roelof J. Versteeg

Brine delineation and monitoring with electrical resistivity tomography and electromagnetic borehole logging at the Fort Knox well field near West Point, Kentucky

The potable water system at Fort Knox is threatened by brine contamination from improperly abandoned natural gas exploration wells. The Fort Knox well field is located near the town of West Point, Kentucky, in the flood plain of the Ohio River. At the site, unconsolidated sediments approximately 30 – 40 m thick, overlie shale and porous limestone. Brine is believed to flow vertically from the unde
Authors
Rory Henderson, Michael D. Unthank, Douglas D. Zettwoch, John W. Lane

Isotopic composition and origin of indigenous natural perchlorate and co-occurring nitrate in the southwestern United States

Perchlorate (ClO4−) has been detected widely in groundwater and soils of the southwestern United States. Much of this ClO4− appears to be natural, and it may have accumulated largely through wet and dry atmospheric deposition. This study evaluates the isotopic composition of natural ClO4− indigenous to the southwestern U.S. Stable isotope ratios were measured in ClO4− (δ18O, Δ17O, δ37Cl) and assoc
Authors
W. Andrew Jackson, John K. Böhlke, Baohua Gu, Paul B. Hatzinger, Neil C. Sturchio

Groundwater hydrology--coastal flow

How groundwater flow varies when long-term external conditions change is little documented. Geochemical evidence shows that sea-level rise at the end of the last glacial period led to a shift in the flow patterns of coastal groundwater beneath Florida.
Authors
Ward E. Sanford

Current challenges using models to forecast seawater intrusion: lessons from the Eastern Shore of Virginia, USA

A three-dimensional model of the aquifer system of the Eastern Shore of Virginia, USA was calibrated to reproduce historical water levels and forecast the potential for saltwater intrusion. Future scenarios were simulated with two pumping schemes to predict potential areas of saltwater intrusion. Simulations suggest that only a few wells would be threatened with detectable salinity increases befor
Authors
Ward E. Sanford, Jason P. Pope