Skip to main content
U.S. flag

An official website of the United States government

Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Using water-quality profiles to characterize seasonal water quality and loading in the upper Animas River basin, southwestern Colorado

One of the important types of information needed to characterize water quality in streams affected by historical mining is the seasonal pattern of toxic trace-metal concentrations and loads. Seasonal patterns in water quality are estimated in this report using a technique called water-quality profiling. Water-quality profiling allows land managers and scientists to assess priority areas to be targ
Authors
Kenneth J. Leib, Alisa Mast, Winfield G. Wright

Microbial cycling of mercury in contaminated pelagic and wetland sediments of San Pablo Bay, California

San Pablo Bay is an estuary, within northern San Francisco Bay, containing elevated sediment mercury (Hg) levels because of historic loading of hydraulic mining debris during the California gold-rush of the late 1800s. A preliminary investigation of benthic microbial Hg cycling was conducted in surface sediment (0–4 cm) collected from one salt-marsh and three open-water sites. A deeper profile (0–
Authors
M. C. Marvin-DiPasquale, J.L. Agee, R. M. Bouse, B. E. Jaffe

Applicability of tetrazolium salts for the measurement of respiratory activity and viability of groundwater bacteria

A study was undertaken to measure aerobic respiration by indigenous bacteria in a sand and gravel aquifer on western Cape Cod, MA using tetrazolium salts and by direct oxygen consumption using gas chromatography (GC). In groundwater and aquifer slurries, the rate of aerobic respiration calculated from the direct GC assay was more than 600 times greater than that using the tetrazolium salt 2-(4-iod
Authors
P.B. Hatzinger, P. Palmer, R. L. Smith, C.T. Penarrieta, T. Yoshinari

Effects of crustal stresses on fluid transport in fractured rock: Case studies from northeastern and southwestern USA

The link between stress and hydrologic properties was examined at two sites that are distinguished by different rock types and different stress states. This investigation is based upon the analysis and interpretation of geophysical logs obtained in water wells at the two locations. At the northeast site (Newark Basin), the hydrologic characteristics of sedimentary rocks are dependent upon the rela
Authors
R. H. Morin, W. Z. Savage

Terpenoids as major precursors of dissolved organic matter in landfill leachates, surface water, and groundwater

13C NMR analyses of hydrophobic dissolved organic matter (DOM) fractions isolated from a landfill leachate contaminated groundwater near Norman, OK; the Colorado River aqueduct near Los Angeles, CA; Anaheim Lake, an infiltration basin for the Santa Ana River in Orange County, CA; and groundwater from the Tomago Sand Beds, near Sydney, Australia, found branched methyl groups and quaternary aliphati
Authors
J. A. Leenheer, M.A. Nanny, C. McIntyre

Characterizing aquatic health using salmonid mortality, physiology, and biomass estimates in streams with elevated concentrations of arsenic, cadmium, copper, lead, and zinc in the Boulder River Watershed, Montana

Abandoned tailings and mine adits are located throughout the Boulder River watershed in Montana. In this watershed, all species of fish are absent from some tributary reaches near mine sources; however, populations of brook trout Salvelinus fontitalis, rainbow trout Oncorhynchus mykiss, and cut-throat trout O. clarki are found further downstream. Multiple methods must be used to investigate the ef
Authors
Aïda M. Farag, Don Skaar, David A. Nimick, Elizabeth MacConnell, Christer Hogstrand

Mercury in soil near a long-term air emission source in southeastern Idaho

At the Idaho National Engineering and Environmental Laboratory in southeastern Idaho, a 500 °C fluidized bed calciner was intermittently operated for 37 years, with measured Hg emission rates of 9–11 g/h. Surface soil was sampled at 57 locations around the facility to determine the spatial distribution of Hg fallout and surface Hg variability, and to predict the total residual Hg mass in the soil
Authors
M.L. Abbott, D. D. Susong, M. Olson, D. P. Krabbenhoft

Characterization and copper binding of humic and nonhumic organic matter isolated from the South Platte River: Evidence for the presence of nitrogenous binding site

Humic substances typically constitute 40−60% of the dissolved organic matter (DOM) in surface waters. However, little information is available regarding the metal binding properties of the nonhumic hydrophilic portion of the DOM. In this study, humic and nonhumic DOM samples were isolated from the South Platte River (Colorado, DOC = 2.6 mg·L-1, SUVA254 = 2.4 L/mg·m) using a two-column array of XAD
Authors
J.-P. Croue, M.F. Benedetti, D. Violleau, J. A. Leenheer

Abundance and characteristics of the recreational water quality indicator bacteria Escherichia coli and enterococci in gull faeces

Aims: To evaluate the numbers and selected phenotypic and genotypic characteristics of the faecal indicator bacteria Escherichia coli and enterococci in gull faeces at representative Great Lakes swimming beaches in the United States.Methods and Results: E. coli and enterococci were enumerated in gull faeces by membrane filtration. E. coli genotypes (rep‐PCR genomic profiles) and E. coli (Vitek® GN
Authors
L.R. Fogarty, S.K. Haack, M. J. Wolcott, R.L. Whitman

Sources of sulfate supporting anaerobic metabolism in a contaminated aquifer

Field and laboratory techniques were used to identify the biogeochemical factors affecting sulfate reduction in a shallow, unconsolidated alluvial aquifer contaminated with landfill leachate. Depth profiles of 35S-sulfate reduction rates in aquifer sediments were positively correlated with the concentration of dissolved sulfate. Manipulation of the sulfate concentration in samples revealed a Micha
Authors
G.A. Ulrich, G. N. Breit, I.M. Cozzarelli, J.M. Suflita

Characterization and diagenesis of strong-acid carboxyl groups in humic substances

A small fraction of carboxylic acid functional groups in humic substances are exceptionally acidic with pKa values as low as 0.5. A review of acid-group theory eliminated most models and explanations for these exceptionally acidic carboxyl groups. These acidic carboxyl groups in Suwannee River fulvic acid were enriched by a 2-stage fractionation process and the fractions were characterized by elem
Authors
J. A. Leenheer, R. L. Wershaw, G.K. Brown, M.M. Reddy