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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3787

Similar rates of decrease of persistent, hydrophobic and particle-reactive contaminants in riverine systems

Although it is well-known that concentrations of anthropogenic radionuclides and organochlorine compounds in aquatic systems have decreased since their widespread release has stopped in the United States, the magnitude and variability of rates of decrease are not well-known. Paleolimnological studies of reservoirs provide a tool for evaluating these long-term trends in riverine systems. Rates of d
Authors
Peter C. Van Metre, Jennifer T. Wilson, Edward Callender, Christopher C. Fuller

Determination of a wide range of volatile organic compounds in ambient air using multisorbent adsorption/thermal desorption and gas chromatography/mass spectrometry

Adsorption/thermal desorption with multisorbent air-sampling cartridges was developed for the determination of 87 method analytes including halogenated alkanes, halogenated alkenes, ethers, alcohols, nitriles, esters, ketones, aromatics, a disulfide, and a furan. The volatilities of the compounds ranged from that of dichlorofluoromethane (CFC12) to that of 1,2,3- trichlorobenzene. The eight most v
Authors
J. F. Pankow, W. Luo, L.M. Isabelle, D.A. Bender, R.J. Baker

Field study and simulation of diurnal temperature effects on infiltration and variably saturated flow beneath an ephemeral stream

Two experiments were performed to investigate flow beneath an ephemeral stream and to estimate streambed infiltration rates. Discharge and stream-area measurements were used to determine infiltration rates. Stream and subsurface temperatures were used to interpret subsurface flow through variably saturated sediments beneath the stream. Spatial variations in subsurface temperatures suggest that flo
Authors
Anne Dudek Ronan, David E. Prudic, Carl E. Thodal, Jim Constantz

Modeling tidal hydrodynamics of San Diego Bay, California

In 1983, current data were collected by the National Oceanic and Atmospheric Administration using mechanical current meters. During 1992 through 1996, acoustic Doppler current profilers as well as mechanical current meters and tide gauges were used. These measurements not only document tides and tidal currents in San Diego Bay, but also provide independent data sets for model calibration and verif
Authors
P.-F. Wang, R. T. Cheng, K. Richter, E.S. Gross, D. Sutton, J. W. Gartner

Biodegradation of the surfactant linear alkylbenzenesulfonate in sewage-contaminated groundwater: A comparison of column experiments and field tracer tests

Transport and biodegradation of linear alkylbenzenesulfonate (LAS) in sewage-contaminated groundwater were investigated for a range of dissolved oxygen concentrations. Both laboratory column and an 80-day continuous injection tracer test field experiments were conducted. The rates of LAS biodegradation increased with increasing dissolved oxygen concentrations and indicated the preferential biodegr
Authors
C.J. Krueger, K.M. Radakovich, T.E. Sawyer, L. B. Barber, R. L. Smith, J.A. Field

Bacterial methylmercury degradation in Florida Everglades peat sediment

Methylmercury (MeHg) degradation was investigated along an eutrophication gradient in the Florida Everglades by quantifying 14CH4 and 14CO2 production after incubation of anaerobic sediments with [14C]MeHg. Degradation rate constants (k) were consistently ≤0.1 d-1 and decreased with sediment depth. Higher k values were observed when shorter incubation times and lower MeHg amendment levels were use
Authors
M. C. Marvin-DiPasquale, R.S. Oremland

Microbial diversity in a hydrocarbon- and chlorinated-solvent- contaminated aquifer undergoing intrinsic bioremediation

A culture-independent molecular phylogenetic approach was used to survey constituents of microbial communities associated with an aquifer contaminated with hydrocarbons (mainly jet fuel) and chlorinated solvents undergoing intrinsic bioremediation. Samples were obtained from three redox zones: methanogenic, methanogenic-sulfate reducing, and iron or sulfate reducing. Small-subunit rRNA genes were
Authors
M.A. Dojka, P. Hugenholtz, S.K. Haack, N.R. Pace

Sulfur geochemistry of hydrothermal waters in Yellowstone National Park: I. The origin of thiosulfate in hot spring waters

Thiosulfate (S2O32−), polythionate (SxO62−), dissolved sulfide (H2S), and sulfate (SO42−) concentrations in thirty-nine alkaline and acidic springs in Yellowstone National Park (YNP) were determined. The analyses were conducted on site, using ion chromatography for thiosulfate, polythionate, and sulfate, and using colorimetry for dissolved sulfide. Thiosulfate was detected at concentrations typica
Authors
Y. Xu, M.A.A. Schoonen, D. Kirk Nordstrom, K.M. Cunningham, J. W. Ball

Influence of microalgal biomass on absorption efficiency of Cd, Cr, and Zn by two bivalves from San Francisco Bay

The bioavailability to clams (Potamocorbula amurensis and Macoma balthica) of Cd, Cr, and Zn from suspended particulate material (SPM) collected during a phytoplankton bloom was compared to bioavailability from SPM dominated by resuspended sediments. Bioavailability was also compared among mudflat sediments amended with different levels of living benthic microalgae. Bioavailability was defined by
Authors
B.-G. Lee, S. N. Luoma

Flow of river water into a Karstic limestone aquifer. 1. Tracing the young fraction in groundwater mixtures in the Upper Floridan Aquifer near Valdosta, Georgia

The quality of water in the Upper Floridan aquifer near Valdosta, Georgia is affected locally by discharge of Withlacoochee River water through sinkholes in the river bed. Data on transient tracers and other dissolved substances, including Cl−, 3H, tritiogenic helium-3 (3He), chlorofluorocarbons (CFC-11, CFC-12, CFC-113), organic C (DOC), O2 (DO), H2S, CH4, δ18O, δD, and 14C were investigated as t
Authors
Niel Plummer, E. Busenberg, J. B. McConnell, S. Drenkard, P. Schlosser, R. L. Michel

Effect of enhanced manganese oxidation in the hyporheic zone on basin-scale geochemical mass balance

We determined the role of the hyporheic zone (the subsurface zone where stream water and shallow groundwater mix) in enhancing microbially mediated oxidation of dissolved manganese (to form manganese precipitates) in a drainage basin contaminated by copper mining. The fate of manganese is of overall importance to water quality in Pinal Creek Basin, Arizona, because manganese reactions affect the t
Authors
Judson W. Harvey, Christopher C. Fuller