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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3787

Identification of hydraulic conductivity structure in sand and gravel aquifers: Cape Cod data set

This study evaluates commonly used geostatistical methods to assess reproduction of hydraulic conductivity (K) structure and sensitivity under limiting amounts of data. Extensive conductivity measurements from the Cape Cod sand and gravel aquifer are used to evaluate two geostatistical estimation methods, conditional mean as an estimate and ordinary kriging, and two stochastic simulation methods,
Authors
J.R. Eggleston, S.A. Rojstaczer, J.J. Peirce

Overview of a simple model describing variation of dissolved organic carbon in an upland catchment

Hydrological mechanisms controlling the variation of dissolved organic carbon (DOC) were investigated in the Deer Creek catchment located near Montezuma, CO. Patterns of DOC in streamflow suggested that increased flows through the upper soil horizon during snowmelt are responsible for flushing this DOC-enriched interstitial water to the streams. We examined possible hydrological mechanisms to expl
Authors
Elizabeth W. Boyer, George M. Hornberger, Kenneth E. Bencala, Diane M. McKnight

Glutathione conjugation and contaminant transformation

The recent identification of a novel sulfonated metabolite of alachlor in groundwater and metolachlor in soil is likely the result of glutathione conjugation. Glutathione conjugation is an important biochemical reaction that leads, in the case of alachlor, to the formation of a rather difficult to detect, water-soluble, and therefore highly mobile, sulfonated metabolite. Research from weed science
Authors
Jennifer A. Field, E.M. Thurman

Dimethylsulfoniopropionate as a potential methanogenic substrate in Mono Lake sediments

A high concentration of dimethylsulfoniopropionate (DMSP) was found in the water column (0.1–1.8 µM particulate plus dissolved) of Mono Lake, CA, an alkaline, hypersaline waterbody. The dense Artemia monica population contained high levels of DMSP (1.7–2.5 mmol.g-1 wet weight), presumably as an osmolyte. Death of these brine shrimp caused accumulation of DMSP along the shoreline of the lake, where
Authors
P.T. Visscher, J.R. Guidetti, Charles W. Culbertson, Ronald S. Oremland

Microbial cycling of methyl bromide

Environmental concern about brominated halocarbons like methyl bromide (MeBr) is focused on their potential to destroy stratospheric ozone. Photocatalysis of MeBr and other halocarbons in the stratosphere results in the liberation of reactive CI and Br atoms. Because Br atoms are perhaps as much as 100-fold more efficient at attacking ozone than are CI atoms, bromine’s lower abundance is partly co
Authors
Ronald S. Oremland

Investigation of methane production and consumption by use of stable isotopes

No abstract available. 
Authors
Kinga M. Revesz, Tyler B. Coplen, Mary Jo Baedecker, P. D. Glynn, M. F. Hult

Method for the determination of dissolved chloride, nitrate, and sulfate in natural water using ion chromatography

Ion chromatography was used for the determination of dissolved chloride, nitrate and sulfate in natural water where concentrations ranged from a detection limit of 0.02 milligrams per liter to 80 milligrams per liter for chloride, to 18 milligrams per liter for nitrate, and to 280 milligrams per liter for sulfate. Specific conductance was the mode of detection used. Three analytical sample size lo
Authors
Terry I. Brinton, Ronald C. Antweiler, Howard E. Taylor

Using geochemical and statistical tools to identify irrigated areas that might contain high selenium concentrations in surface water

Irrigated agriculture has a long history in the Western United States, beginning with Native American Indians. After passage of the Reclamation Act of 1902, the United States Government began building and subsidizing irrigation projects to foster settlement and development of the arid and semi-arid areas of the Western United States (National Research Council, 1989). Precipitation in the mountaino
Authors
David L. Naftz

Inductively coupled plasma-mass spectrometric method for the determination of dissolved trace elements in natural water

An inductively coupled plasma-mass spectrometry method was developed for the determination of dissolved Al, As, B, Ba, Be, Cd, Co, Cr, Cu, Li, Mn, Mo, Ni, Pb, Sr, Tl, U, V, and Zn in natural waters. Detection limits are generally in the 50-100 picogram per milliliter (pg/mL) range, with the exception of As which is in the 1 microgram per liter (ug/L) range. Interferences associated with spectral o
Authors
J.R. Garbarino, Howard E. Taylor