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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Crude oil metabolites in groundwater at two spill sites

Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring
Authors
Barbara A. Bekins, Isabelle M. Cozzarelli, Melinda L. Erickson, Ross Steenson, Kevin A. Thorn

Hydrologic indicators of hot spots and hot moments of mercury methylation potential along river corridors

The biogeochemical cycling of metals and other contaminants in river-floodplain corridors is controlled by microbial activity responding to dynamic redox conditions. Riverine flooding thus has the potential to affect speciation of redox-sensitive metals such as mercury (Hg). Therefore, inundation history over a period of decades potentially holds information on past production of bioavailable Hg.
Authors
Michael B. Singer, Lee R. Harrison, Patrick M. Donovan, Joel D. Blum, Mark C. Marvin-DiPasquale

Hydrologic controls on nitrogen cycling processes and functional gene abundance in sediments of a groundwater flow-through lake

The fate and transport of inorganic nitrogen (N) is a critically important issue for human and aquatic ecosystem health because discharging N-contaminated groundwater can foul drinking water and cause algal blooms. Factors controlling N-processing were examined in sediments at three sites with contrasting hydrologic regimes at a lake on Cape Cod, MA. These factors included water chemistry, seepage
Authors
Deborah L. Stoliker, Deborah A. Repert, Richard L. Smith, Bongkeun Song, Denis R. LeBlanc, Timothy D. McCobb, Christopher Conaway, Sung Pil Hyun, Dong-Chan Koh, Hee Sun Moon, Douglas B. Kent

Quantifying fish swimming behavior in response to acute exposure of aqueous copper using computer assisted video and digital image analysis

Behavioral responses of aquatic organisms to environmental contaminants can be precursors of other effects such as survival, growth, or reproduction. However, these responses may be subtle, and measurement can be challenging. Using juvenile white sturgeon (Acipenser transmontanus) with copper exposures, this paper illustrates techniques used for quantifying behavioral responses using computer assi
Authors
Robin Calfee, Holly J. Puglis, Edward E. Little, William G. Brumbaugh, Christopher A. Mebane

Effect of wastewater treatment facility closure on endocrine disrupting chemicals in a Coastal Plain stream

Wastewater treatment facility (WWTF) closures are rare environmental remediation events; offering unique insight into contaminant persistence, long-term wastewater impacts, and ecosystem recovery processes. The U.S. Geological Survey assessed the fate of select endocrine disrupting chemicals (EDC) in surface water and streambed sediment one year before and one year after closure of a long-term WWT
Authors
Paul M. Bradley, Celeste A. Journey, Jimmy M. Clark

Establishing a pre-mining geochemical baseline at a uranium mine near Grand Canyon National Park, USA

During 2012, approximately 404,000 ha of Federal Land in northern Arizona was withdrawn from consideration of mineral extraction for a 20-year period to protect the Grand Canyon watershed from potentially adverse effects of U mineral exploration and development. The development, operation, and reclamation of the Canyon Mine during the withdrawal period provide an excellent field site to understand
Authors
David L. Naftz, Katherine Walton-Day

Mercury transformation and release differs with depth and time in a contaminated riparian soil during simulated flooding

Riparian soils are an important environment in the transport of mercury in rivers and wetlands, but the biogeochemical factors controlling mercury dynamics under transient redox conditions in these soils are not well understood. Mercury release and transformations in the Oa and underlying A horizons of a contaminated riparian soil were characterized in microcosms and an intact soil core under satu
Authors
Brett Poulin, George R. Aiken, Kathryn L. Nagy, Alain Manceau, David P. Krabbenhoft, Joseph N. Ryan

Groundwater

Introduction Groundwater represents the terrestrial subsurface component of the hydrologic cycle. As such, groundwater is generally in motion, moving from elevated areas of recharge to lower areas of discharge. Groundwater usually moves in accordance with Darcy’s law (Dalmont, Paris: Les Fontaines Publiques de la Ville de Dijon, 1856). Groundwater residence times can be under a day in small upland
Authors
David A. Stonestrom

Hydraulic and biochemical gradients limit wetland mercury supply to an Adirondack stream

Net fluxes (change between upstream and downstream margins) for water, methylmercury (MeHg), total mercury (THg), dissolved organic carbon (DOC), and chloride (Cl) were assessed twice in an Adirondack stream reach (Sixmile Brook, USA), to test the hypothesized importance of wetland-stream hydraulic and chemical gradients as fundamental controls on fluvial mercury (Hg) supply. The 500 m study reach
Authors
Paul M. Bradley, Douglas A. Burns, Judson Harvey, Celeste A. Journey, Mark E. Brigham, Karen Riva-Murray

Experimental studies and model analysis of noble gas fractionation in porous media

The noble gases, which are chemically inert under normal terrestrial conditions but vary systematically across a wide range of atomic mass and diffusivity, offer a multicomponent approach to investigating gas dynamics in unsaturated soil horizons, including transfer of gas between saturated zones, unsaturated zones, and the atmosphere. To evaluate the degree to which fractionation of noble gases i
Authors
Xin Ding, B. Mack. Kennedy, William C. Evans, David A. Stonestrom

Mercury remediation in wetland sediment using zero-valent iron and granular activated carbon

Wetlands are hotspots for production of toxic methylmercury (MeHg) that can bioaccumulate in the food web. The objective of this study was to determine whether the application of zero-valent iron (ZVI) or granular activated carbon (GAC) to wetland sediment could reduce MeHg production and bioavailability to benthic organisms. Field mesocosms were installed in a wetland fringing Hodgdon Pond (Maine
Authors
Ariel S. Lewis, Thomas G. Huntington, Mark C. Marvin-DiPasquale, Aria Amirbahman

Spatial and temporal variation in microcystins occurrence in wadeable streams in the southeastern USA

Despite historical observations of potential microcystin-producing cyanobacteria (including Leptolyngbya,Phormidium, Pseudoanabaena, and Anabaena species) in 74% of headwater streams in Alabama, Georgia, South Carolina, and North Carolina (USA) from 1993 to 2011, fluvial cyanotoxin occurrence has not been systematically assessed in the southeastern United States. To begin to address this data gap,
Authors
Keith A. Loftin, Jimmy M. Clark, Celeste A. Journey, Dana W. Kolpin, Peter C. Van Metre, Paul M. Bradley