Publications

A survey of the natural and anthropogenic sources of lead contributing to secondary minerals in sulphidic schists associated with arsenic-enriched groundwater in Coastal Maine shows that the most likely source is natural Pb, particularly from coexisting sulphide minerals. The secondary minerals also reflect notable contributions from anthropogenic Pb. The Pb isotopes establish pathways by which Pb

Episodic acidification resulting in increased acidity and inorganic aluminum (Ali) is known to impact anadromous salmonids and has been identified as a possible cause of Atlantic salmon population decline. Sensitive life-stages such as smolts may be particularly vulnerable to impacts of short-term (days–week) acid/Al exposure, however the extent and mechanism(s) of this remain unknown. To determin

To investigate the role of the seepage zone in transport, chemical speciation, and attenuation of nitrogen loads carried by submarine groundwater discharge, we collected nearshore groundwater samples (n = 328) and examined the distribution and isotopic signature (δ15N) of nitrate and ammonium. In addition, we estimated nutrient fluxes from terrestrial and marine groundwater sources. We discuss our

Pesticide transport through the unsaturated zone is a function of chemical and soil characteristics, application, and water recharge rate. The fate and transport of 82 pesticides and degradates were investigated at five different agricultural sites. Atrazine and metolachlor, as well as several of the degradates of atrazine, metolachlor, acetochlor, and alachlor, were frequently detected in soil wa

This paper presents a new, non-invasive means of quantifying groundwater discharge into marine waters using an eddy correlation approach. The method takes advantage of the fact that, in virtually all aquatic environments, the dominant mode of vertical transport near the sediment–water interface is turbulent mixing. The technique thus relies on measuring simultaneously the fluctuating vertical velo

The Keathley Canyon sites drilled in 2005 by the Chevron Joint Industry Project are located along the southeastern edge of an intraslope minibasin (Casey basin) in the northern Gulf of Mexico at 1335 m water depth. Around the drill sites, a grid of 2D high-resolution multichannel seismic data designed to image depths down to at least 1000 m sub-bottom reveals 7 unconformities and disconformities t

There has been a resurgence of interest in marine heat flow in the past 10–15 years, coinciding with fundamental achievements in understanding the Earth's thermal state and quantifying the dynamics and impacts of material and energy fluxes within and between the lithosphere and hydrosphere. At the same time, technical capabilities have dwindled to the point that no U.S. academic institution curren

The shoaling of the nonlinear internal tide in Massachusetts Bay is studied with a fully nonlinear and nonhydrostatic model. The results are compared with current and temperature observations obtained during the August 1998 Massachusetts Bay Internal Wave Experiment and observations from a shorter experiment which took place in September 2001. The model shows how the approaching nonlinear undular

Six Mile Reef, a sandy, 22-m-high shoal trending east-west and located about 7.8 km off the Connecticut coast, has a core of postglacial marine deltaic deposits mantled by tidally reworked modern sediments. Sedimentary environments off the eastern end of the shoal are characterized by processes associated with long-term erosion or nondeposition, a mobile-sediment-limited seafloor armored by gravel

One of the many challenges in studying methane hydrate is that it is unstable at typical surface pressure and temperature conditions. To enable methane hydrates and hydrate-bearing sediments to be formed, analyzed, and experimented with, the National Energy Technology Laboratory (NETL), and the U.S. Geological Survey (USGS) in Woods Hole, MA collaborated in the development of the Gas Hydrate And S

Pore waters extracted from 18 piston cores obtained on and near a salt-cored bathymetric high in Keathley Canyon lease block 151 in the northern Gulf of Mexico contain elevated concentrations of chloride (up to 838 mM) and have pore water chemical concentration profiles that exhibit extensive departures (concavity) from steady-state (linear) diffusive equilibrium with depth. Minimum ??13C dissolve

Using an oedometer cell instrumented to measure the evolution of electromagnetic properties, small strain stiffness, and temperature, we conducted consolidation tests on sediments recovered during drilling in the northern Gulf of Mexico at the Atwater Valley and Keathley Canyon sites as part of the 2005 Chevron Joint Industry Project on Methane Hydrates. The tested specimens include both unremolde