Sheila Murphy

Wildfire is a growing concern as climate shifts. The hydrologic effects of wildfire, which include elevated hazards and changes in water quantity and quality, are increasingly assessed using numerical models. Post-wildfire application of physically based distributed models provides unique insight into the underlying processes that affect water resources after wildfire. This work reviews...

Urban ammonia (NH3) emissions contribute to poor local air quality and can be transported to rural landscapes, impacting sensitive ecosystems. The Colorado Front Range urban corridor encompasses the Denver Metropolitan Area, rural farmland/rangeland and montane forest between the city and the Rocky Mountains. Reactive nitrogen emissions from the corridor are partly responsible for...

As humans increasingly dominate the nitrogen cycle, deposition of reactive nitrogen (Nr) will continue to have adverse consequences for ecosystems. In the Rocky Mountains, Nr deposition remains elevated and has become increasingly dominated by ammonium, despite efforts to reduce emissions. Currently, spatial models of Nr deposition do not fully account for urban and agricultural...

Extreme rainfall events in the humid-tropical Luquillo Mountains, Puerto Rico export the bulk of suspended sediment and particulate organic carbon. Using 25 years of river carbon and suspended sediment data, which targeted hurricanes and other large rainstorms, we estimated biogenic particulate organic carbon yields of 65 ± 16 tC km−2 yr−1 for the Icacos and 17.7 ± 5.1 tC km−2 yr−1 for...

Freshwater streams can exchange nutrients and carbon with the surrounding terrestrial environment through various mechanisms including physical erosion, flooding, leaf drop, and snowmelt. These aquatic-terrestrial interactions are crucial in carbon mobilization, transformation, ecosystem productivity, and have important implications for the role of freshwater ecosystems in the global...

The U.S. Geological Survey (USGS) Wildland Fire Science Strategic Plan defines critical, core fire science capabilities for understanding fire-related and fire-responsive earth system processes and patterns, and informing management decision making. Developed by USGS fire scientists and executive leadership, and informed by conversations with external stakeholders, the Strategic Plan is...

Ash and surface water samples collected after wildfires in four different geographical locations (California, Colorado, Kansas and Alberta) were analyzed. The ash samples were leached with deionized water, and leachates were concentrated by solid phase extraction and analyzed by liquid chromatography/time-of-flight mass spectrometry. In addition, three surface water samples and a...

Climatic shifts, disturbances, and land-use change can alter hydrologic flowpaths, water quality, and water supply to downstream communities. Prior research investigating streamflow generation processes in mountainous areas has largely focused on high-elevation alpine and subalpine catchments; less is known about these processes in lower-elevation foothills and montane catchments. In...

Despite a multitude of small catchment studies, we lack a deep understanding of how variations in critical zone architecture lead to variations in hydrologic states and fluxes. This study characterizes hydrologic dynamics of 15 catchments of the U.S. Critical Zone Observatory (CZO) network where we hypothesized that our understanding of subsurface structure would illuminate patterns of...

Sulfur (S) is widely used in agriculture, yet little is known about its fates within upland watersheds, particularly in combination with disturbances like wildfire. Our study examined the effects of land use and wildfire on the biogeochemical “fingerprints,” or the quantity and chemical composition, of S and carbon (C). We conducted our research within the Napa River Watershed...

Wildfires burning in watersheds that have been mined and since revegetated pose unique risks to downstream water supplies. A wildfire near Boulder, Colorado that burned a forested watershed recovering from mining disturbance that occurred 80-160 years ago allowed us to 1) assess arsenic and metal contamination in streams draining the burned area for a five-year period after the wildfire...

Seasonal streamflow forecast bias, changes in climate, snowpack, and land cover, and the effects of these changes on relations between basin‐wide snowpack, SNOw TELemetry (SNOTEL) station snowpack, and seasonal streamflow were evaluated in the headwaters of the Rio Grande, Colorado. Results indicate that shifts in the seasonality of precipitation and changing climatology are consistent...