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Adjustment of pesticide concentrations for temporal changes in analytical recovery, 1992-2006

Recovery is the proportion of a target analyte that is quantified by an analytical method and is a primary indicator of the analytical bias of a measurement. Recovery is measured by analysis of quality-control (QC) water samples that have known amounts of target analytes added ('spiked' QC samples). For pesticides, recovery is the measured amount of pesticide in the spiked QC sample expressed as p
Authors
Jeffrey D. Martin, Wesley W. Stone, Duane S. Wydoski, Mark W. Sandstrom

Identification of methyl triclosan and halogenated analogues in male common carp (Cyprinus carpio) from Las Vegas Bay and semipermeable membrane devices from Las Vegas Wash, Nevada

Methyl triclosan and four halogenated analogues have been identified in extracts of individual whole-body male carp (Cyprinus carpio) tissue that were collected from Las Vegas Bay, Nevada, and Semipermeable Membrane Devices (SPMD) that were deployed in Las Vegas Wash, Nevada. Methyl triclosan is believed to be the microbially methylated product of the antibacterial agent triclosan (2, 4, 4'-trichl
Authors
T.J. Leiker, S.R. Abney, S. L. Goodbred, Michael R. Rosen

Biodegradation of 17β-estradiol, estrone and testosterone in stream sediments

Biodegradation of 17β-estradiol (E2), estrone (E1), and testosterone (T) was investigated in three wastewater treatment plant (WWTP) affected streams in the United States. Relative differences in the mineralization of [4-14C] substrates were assessed in oxic microcosms containing saturated sediment or water-only from locations upstream and downstream of the WWTP outfall in each system. Upstream se
Authors
Paul M. Bradley, Larry B. Barber, Francis H. Chapelle, James L. Gray, Dana W. Kolpin, Peter B. McMahon

Waste-indicator and pharmaceutical compounds in landfill-leachate-affected ground water near Elkhart, Indiana, 2000-2002

Four wells downgradient from a landfill near Elkhart, Indiana were sampled during 2000–2002 to evaluate the presence of waste-indicator and pharmaceutical compounds in landfill-leachate-affected ground water. Compounds detected in leachate-affected ground water included detergent metabolites (p-nonylphenol, nonylphenol monoethoxylate, nonylphenol diethoxylate, and octylphenol monoethoxylate), plas
Authors
P.M. Buszka, D. J. Yeskis, D.W. Kolpin, E. T. Furlong, S.D. Zaugg, M. T. Meyer

Comparing wastewater chemicals, indicator bacteria concentrations, and bacterial pathogen genes as fecal pollution indicators

The objective of this study was to compare fecal indicator bacteria (FIB) (fecal coliforms, Escherichia coli [EC], and enterococci [ENT]) concentrations with a wide array of typical organic wastewater chemicals and selected bacterial genes as indicators of fecal pollution in water samples collected at or near 18 surface water drinking water intakes. Genes tested included esp (indicating human-path
Authors
S.K. Haack, J.W. Duris, L.R. Fogarty, D.W. Kolpin, M. J. Focazio, E. T. Furlong, M. T. Meyer

Interpreting and Reporting Radiological Water-Quality Data

This document provides information to U.S. Geological Survey (USGS) Water Science Centers on interpreting and reporting radiological results for samples of environmental matrices, most notably water. The information provided is intended to be broadly useful throughout the United States, but it is recommended that scientists who work at sites containing radioactive hazardous wastes need to consult
Authors
David E. McCurdy, John R. Garbarino, Ann H. Mullin

Study design and percent recoveries of anthropogenic organic compounds with and without the addition of ascorbic acid to preserve water samples containing free chlorine, 2004-06

The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS) began implementing Source Water-Quality Assessments (SWQAs) in 2002 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems in the United States. As used for SWQA studies, source water is the raw (ambient) wat
Authors
Joshua F. Valder, Gregory C. Delzer, Curtis V. Price, Mark W. Sandstrom

Determination of human-health pharmaceuticals in filtered water by chemically modified styrene-divinylbenzene resin-based solid-phase extraction and high-performance liquid chromatography/Mass Spectrometry

In 1999, the Methods Research and Development Program of the U.S. Geological Survey National Water Quality Laboratory began the process of developing a method designed to identify and quantify human-health pharmaceuticals in four filtered water-sample types: reagent water, ground water, surface water minimally affected by human contributions, and surface water that contains a substantial fraction
Authors
Edward T. Furlong, Stephen L. Werner, Bruce D. Anderson, Jeffery D. Cahill

Using the U.S. Geological Survey National Water Quality Laboratory LT-MDL to Evaluate and Analyze Data

A long-term method detection level (LT-MDL) and laboratory reporting level (LRL) are used by the U.S. Geological Survey?s National Water Quality Laboratory (NWQL) when reporting results from most chemical analyses of water samples. Changing to this method provided data users with additional information about their data and often resulted in more reported values in the low concentration range. Befo
Authors
Bernadine A. Bonn

Reproductive disruption in fish downstream from an estrogenic wastewater effluent

To assess the impact of an estrogenic wastewater treatment plant (WWTP) effluent on fish reproduction, white suckers (Catostomus commersoni) were collected from immediately upstream and downstream (effluent site) of the city of Boulder, CO, WWTP outfall. Gonadal intersex, altered sex ratios, reduced gonad size, disrupted ovarian and testicular histopathology, and vitellogenin induction consistent
Authors
A.M. Vajda, Larry B. Barber, James L. Gray, E.M. Lopez, John D. Woodling, David O. Norris

Pesticide fate and transport throughout unsaturated zones in five agricultural settings, USA

Pesticide transport through the unsaturated zone is a function of chemical and soil characteristics, application, and water recharge rate. The fate and transport of 82 pesticides and degradates were investigated at five different agricultural sites. Atrazine and metolachlor, as well as several of the degradates of atrazine, metolachlor, acetochlor, and alachlor, were frequently detected in soil wa
Authors
T.C. Hancock, Mark W. Sandstrom, J. R. Vogel, R.M.T. Webb, E.R. Bayless, J.E. Barbash

Comparative study of transport processes of nitrogen, phosphorus, and herbicides to streams in five agricultural basins, USA

Agricultural chemical transport to surface water and the linkage to other hydrological compartments, principally ground water, was investigated at five watersheds in semiarid to humid climatic settings. Chemical transport was affected by storm water runoff, soil drainage, irrigation, and how streams were linked to shallow ground water systems. Irrigation practices and timing of chemical use greatl
Authors
Joseph L. Domagalski, S. Ator, R. Coupe, K. McCarthy, D. Lampe, Mark W. Sandstrom, N. Baker