Book Chapters

This book investigates applications of selected chemical and isotopic substances that can be used to recognize and interpret age information pertaining to ‘old’ groundwater (defined as water that was recharged on a timescale from approximately 1000 to more than 1 000 000 a). However, as discussed below, only estimates of the ‘age’ of water extracted from wells can be inferred. These groundwater ag

Any estimate of ‘age’ of a groundwater sample based on environmental tracers requires some form of geochemical model to interpret the tracer chemistry (chapter 3) and is, therefore, referred to in this chapter as a tracer model age. the tracer model age of a groundwater sample can be useful for obtaining information on the residence time and replenishment rate of an aquifer system, but that type o

The radioactive isotope of carbon, radiocarbon (14C), was first produced artificially in 1940 by Martin Kamen and Sam Ruben, who bombarded graphite in a cyclotron at the Radiation Laboratory at Berkeley, CA, in an attempt to produce a radioactive isotope of carbon that could be used as a tracer in biological systems (Kamen (1963) [101]; Ruben and Kamen (1941) [102]). Carbon-14 of cosmogenic origin

Chemical and isotopic patterns in groundwater can record characteristics of water sources, flow directions, and groundwater-age information. This hydrochemical information can be useful in refining conceptualization of groundwater flow, in calibration of numerical models of groundwater flow, and in estimation of paleo and modern recharge rates. This case study shows how chemical and isotopic dat

No abstract available.

Global climate change is important in considerations of integrated coastal management in the Gulf of Mexico. This is true for a number of reasons. Climate in the Gulf spans the range from tropical to the lower part of the temperate zone. Thus, as climate warms, the tropical temperate interface, which is currently mostly offshore in the Gulf of Mexico, will increasingly move over the coastal zone o

No abstract available

Alabama is blessed with more than 77,000 miles of rivers and streams that carve through the terrestrial landscape of the state. When you think about it, every road you drive on crosses a river and many of our major cities are located on the bank of a river. In fact, Alabama's capital cities - Cahawba (Dallas County; 1820-1826), Tuscaloosa (Tuscaloosa County; 1826-1846), and Montgomery County; 18

An isotope-dilution quantification method was developed for 20 natural and synthetic steroid hormones and additional compounds in filtered and unfiltered water. Deuterium- or carbon-13-labeled isotope-dilution standards (IDSs) are added to the water sample, which is passed through an octadecylsilyl solid-phase extraction (SPE) disk. Following extract cleanup using Florisil SPE, method compounds ar

We describe the structure of the eastern Española Basin and use stratigraphic and stratal attitude data to interpret its tectonic development. This area consists of a west-dipping half graben in the northern Rio Grande rift that includes several intrabasinal grabens, faults, and folds. The Embudo–Santa Clara–Pajarito fault system, a collection of northeast- and north-striking faults in the center

No abstract available.

Arsenic (As) is a metalloid element (atomic number 33) with one naturally occurring isotope of atomic mass 75, and four oxidation states (-3, 0, +3, and +5) (Smedley and Kinniburgh, 2002). In the aqueous environment, the +3 and +5 oxidation states are most prevalent, as the oxyanions arsenite (H3AsO3 or H2AsO3- at pH ~9-11) and arsenate (H2AsO4- and HAsO42- at pH ~4-10) (Smedley and Kinniburgh, 20