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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4094

Efficacy and residual toxicity of a sodium hydroxide based ballast water treatment system for freshwater bulk freighters

The efficacy and residual toxicity of a sodium hydroxide (NaOH) based ballast water treatment system (BWTS) were tested aboard the Great Lakes carrier M/V American Spiritin 1000 L mesocosms containing water from the ship's ballast tanks. NaOH was added to elevate the pH to 11.5 or 11.7 for 48 h, after which pH was reduced to < 9 before discharge by sparging with carbon dioxide to form sodium bicar
Authors
Adria Elskus, Carys L. Mitchelmore, David Wright, Jeffrey W. Henquinet, Nicholas Welschmeyer, Colin Flynn, Barnaby J. Watten

Future research needs involving pathogens in groundwater

Contamination of groundwater by enteric pathogens has commonly been associated with disease outbreaks. Proper management and treatment of pathogen sources are important prerequisites for preventing groundwater contamination. However, non-point sources of pathogen contamination are frequently difficult to identify, and existing approaches for pathogen detection are costly and only provide semi-quan
Authors
Scott A. Bradford, Ronald W. Harvey

Geochemical characterization of groundwater discharging from springs north of the Grand Canyon, Arizona, 2009–2016

A geochemical study was conducted on 37 springs discharging from the Toroweap Formation, Coconino Sandstone, Hermit Formation, Supai Group, and Redwall Limestone north of the Grand Canyon near areas of breccia-pipe uranium mining. Baseline concentrations were established for the elements As, B, Li, Se, SiO2, Sr, Tl, U, and V. Three springs exceeded U.S. Environmental Protection Agency drinking wat
Authors
Kimberly R. Beisner, Fred D. Tillman, Jessica R. Anderson, Ronald C. Antweiler, Donald J. Bills

Selenium: Mercury molar ratios in freshwater fish in the Columbia River Basin: Potential applications for specific fish consumption advisories

Fish provide a valuable source of beneficial nutrients and are an excellent source of low fat protein. However, fish are also the primary source of methylmercury exposure in humans. Selenium often co-occurs with mercury and there is some evidence that selenium can protect against mercury toxicity yet States issue fish consumption advisories based solely on the risks that methylmercury pose to huma
Authors
Leanne K. Cusack, Collin A. Eagles-Smith, Anna K. Harding, Molly Kile, Dave Stone

Density-driven free-convection model for isotopically fractionated geogenic nitrate in sabkha brine

Subsurface brines with high nitrate (NO3−) concentration are common in desert environments as atmospheric nitrogen is concentrated by the evaporation of precipitation and little nitrogen uptake. However, in addition to having an elevated mean concentration of ∼525 mg/L (as N), NO3− in the coastal sabkhas of Abu Dhabi is enriched in 15N (mean δ15N ∼17‰), which is an enigma. A NO3− solute mass balan
Authors
Warren W. Wood, John K. Böhlke

Occurrence of neonicotinoid insecticides in finished drinking water and fate during drinking water treatment

Neonicotinoid insecticides are widespread in surface waters across the agriculturally-intensive Midwestern US. We report for the first time the presence of three neonicotinoids in finished drinking water and demonstrate their general persistence during conventional water treatment. Periodic tap water grab samples were collected at the University of Iowa over seven weeks in 2016 (May-July) after ma
Authors
Kathryn L. Klarich, Nicholas C. Pflug, Eden M. DeWald, Michelle L. Hladik, Dana W. Kolpin, David M. Cwiertny, Gergory H. LeFevre

Field-scale observations of a transient geobattery resulting from natural attenuation of a crude oil spill

We present evidence of a geobattery associated with microbial degradation of a mature crude oil spill. Self-potential measurements were collected using a vertical array of nonpolarizing electrodes, starting at the land surface and passing through the smear zone where seasonal water table fluctuations have resulted in the coating of hydrocarbons on the aquifer solids. These passive electrical poten
Authors
Jeffrey Heenan, Dimitris Ntarlagiannis, Lee Slater, Carol Beaver, S. Rossbach, A. Revil, E.A. Atekwana, Barbara A. Bekins

Acute sensitivity of a broad range of freshwater mussels to chemicals with different modes of toxic action

Freshwater mussels, one of the most imperiled groups of animals in the world, are generally underrepresented in toxicity databases used for the development of ambient water quality criteria and other environmental guidance values. Acute 96-h toxicity tests were conducted to evaluate the sensitivity of 5 species of juvenile mussels from 2 families and 4 tribes to 10 chemicals (ammonia, metals, majo
Authors
Ning Wang, Chris D. Ivey, Christopher G. Ingersoll, William G. Brumbaugh, David Alvarez, Edward J. Hammer, Candice R. Bauer, Tom Augspurger, Sandy Raimondo, M.Christopher Barnhart

Importance of the 2014 Colorado River Delta pulse flow for migratory songbirds: Insights from foraging behavior

The Lower Colorado River provides critical riparian areas in an otherwise arid region and is an important stopover site for migrating landbirds. In order to reverse ongoing habitat degradation due to drought and human-altered hydrology, a pulse flow was released from Morelos Dam in spring of 2014, which brought surface flow to dry stretches of the Colorado River in Mexico. To assess the potential
Authors
Abigail J. Darrah, Harold F. Greeney, Charles van Riper

An evaluation of inorganic toxicity reference values for use in assessing hazards to American robins (Turdus migratorius)

When performing screening-level and baseline risk assessments, assessors usually compare estimated exposures of wildlife receptor species with toxicity reference values (TRVs). We modeled the exposure of American robins (Turdus migratorius) to 10 elements (As, Cd, Cr, Cu, Hg, Mn, Pb, Se, Zn, and V) in spring and early summer, a time when earthworms are the preferred prey. We calculated soil benchm
Authors
W. Nelson Beyer, Bradley E. Sample

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine, Arizona (USA)

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area
Authors
Kimberly R. Beisner, Nicholas V. Paretti, Fred D. Tillman, David L. Naftz, Donald J. Bills, Katherine Walton-Day, Tanya J. Gallegos

Shifts in microbial community structure and function in surface waters impacted by unconventional oil and gas wastewater revealed by metagenomics

Unconventional oil and gas (UOG) production produces large quantities of wastewater with complex geochemistry and largely uncharacterized impacts on surface waters. In this study, we assessed shifts in microbial community structure and function in sediments and waters upstream and downstream from a UOG wastewater disposal facility. To do this, quantitative PCR for 16S rRNA and antibiotic resistanc
Authors
N.L. Fahrenfeld, Hannah Delos Reyes, Alessia Eramo, Denise M. Akob, Adam Mumford, Isabelle M. Cozzarelli