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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Timescales for nitrate contamination of spring waters, northern Florida, USA

Residence times of groundwater, discharging from springs in the middle Suwannee River Basin, were estimated using chlorofluorocarbons (CFCs), tritium (3H), and tritium/helium-3 (3H/3He) age-dating methods to assess the chronology of nitrate contamination of spring waters in northern Florida. During base-flow conditions for the Suwannee River in 1997–1999, 17 water samples were collected from 12 fi
Authors
B. G. Katz, J.K. Böhlke, H.D. Hornsby

Sulfate-reducing bacteria release barium and radium from naturally occurring radioactive material in oil-field barite

Scale and sludge deposits formed during oil production can contain elevated levels of Ra, often coprecipitated with barium sulfate (barite). The potential for sulfate-reducing bacteria to release 226 Ra and Ba (a Ra analog) from oil-field barite was evaluated. The concentration of dissolved Ba increased when samples containing pipe scale, tank sludge, or oil-field brine pond sediment were incubate
Authors
E. J. P. Phillips, E. R. Landa, T. Kraemer, R. Zielinski

Influence of reactive sulfide (AVS) and supplementary food on Ag, Cd and Zn bioaccumulation in the marine polychaete Neanthes arenaceodentata

A laboratory bioassay determined the relative contribution of various pathways of Ag, Cd and Zn bioaccumulation in the marine polychaete Neanthes arenaceodentata exposed to moderately contaminated sediments. Juvenile worms were exposed for 25 d to experimental sediments containing 5 different reactive sulfide (acid volatile sulfides, AVS) concentrations (1 to 30 ??mol g-1), but with constant Ag, C
Authors
J.-S. Lee, B.-G. Lee, H. Yoo, C.-H. Koh, S. N. Luoma

Possible environmental factors underlying amphibian decline in eastern Puerto Rico: Analysis of U.S. government data archives

The past three decades have seen major declines in populations of several species of amphibians at high elevations in eastern Puerto Rico, a region unique in the humid tropics because of the degree of environmental monitoring that has taken place through the efforts of U.S. government agencies. I examined changes in environmental conditions by examining time-series data sets that extend back at le
Authors
R.F. Stallard

Long-term changes in consentrations and flux fo nitrogen in the Mississippi River Basin, USA

Current and historical data show that nitrogen concentrations and flux in the Mississippi River Basin have increased significantly during the past 100 years. Most of the increase observed in the lower Mississippi River has occurred since the early 1970s and is due almost entirely to an increase in nitrate. The current (1980-99) average annual nitrogen (N) flux from the Mississippi Basin to the Gul
Authors
D. A. Goolsby, W.A. Battaglin

Carbon and nitrogen isotopic compositions of particulate organic matter in four large river systems across the United States

Riverine particulate organic matter (POM) samples were collected bi‐weekly to monthly from 40 sites in the Mississippi, Colorado, Rio Grande, and Columbia River Basins (USA) in 1996–97 and analysed for carbon and nitrogen stable isotopic compositions. These isotopic compositions and C : N ratios were used to identify four endmember sources of POM: plankton, fresh terrestrial plant material, aquati
Authors
C. Kendall, S. R. Silva, V.J. Kelly

Effects of acidic recharge on groundwater at the St. Kevin Gulch site, Leadville, Colorado

The acid rock drainage-affected stream of St. Kevin Gulch recharges the Quaternary sand and gravel aquifer of Tennessee Park, near Leadville, Colorado, lowering pH and contributing iron, cadmium, copper, zinc and sulphate to the ground-water system. Dissolved metal mobility is controlled by the seasonal spring runoff as well as oxidation/reduction (redox) reactions in the aquifer. Oxidizing condit
Authors
S.S. Paschke, W.J. Harrison, K. Walton-Day

Transient storage assessments of dye-tracer injections in rivers of the Willamette Basin, Oregon

Rhodamine WT dye-tracer injections in rivers of the Willamette Basin yield concentration-time curves with characteristically long recession times suggestive of active transient storage processes. The scale of drainage areas contributing to the stream reaches studied in the Willamette Basin ranges from 10 to 12,000 km2. A transient storage assessment of the tracer studies has been completed using t
Authors
A. Laenen, K.E. Bencala

Identification of methyl halide-utilizing genes in strain IMB-1, a methyl bromide-utilizing bacterium suggests a high degree of conservation of methyl halide-specific genes in gram-negative bacteria

Strain IMB-1, an aerobic methylotrophic member of the alpha subgroup of the Proteobacteria, can grow with methyl bromide as a sole carbon and energy source. A single cmu gene cluster was identified in IMB-1 that contained six open reading frames: cmuC, cmuA, orf146, paaE, hutI, and partial metF. CmuA from IMB-1 has high sequence homology to the methyltransferase CmuA from Methylobacterium chlorome
Authors
C.A. Woodall, K.L. Warner, R.S. Oremland, J.C. Murrell, I.R. McDonald

Widespread potential for microbial MTBE degradation in surface-water sediments

Microorganisms indigenous to stream and lake bed sediments, collected from 11 sites throughout the United States, demonstrated significant mineralization of the fuel oxygenate, methyl-tert-butyl ether (MTBE). Mineralization of [U-14C]MTBE to 14CO2 ranged from 15 to 66% over 50 days and did not differ significantly between sediments collected from MTBE contaminated sites and from sites with no hist
Authors
P. M. Bradley, J. E. Landmeyer, F. H. Chapelle

Analysis of streambed temperatures in ephemeral channels to determine streamflow frequency and duration

Spatial and temporal patterns in streamflow are rarely monitored for ephemeral streams. Flashy, erosive streamflows common in ephemeral channels create a series of operational and maintenance problems, which makes it impractical to deploy a series of gaging stations along ephemeral channels. Streambed temperature is a robust and inexpensive parameter to monitor remotely, leading to the possibility
Authors
James E. Constantz, David A. Stonestrom, Amy E. Stewart, Richard G. Niswonger, Tyson R. Smith

A functional relation for field-scale nonaqueous phase liquid dissolution developed using a pore network model

A pore network model with cubic chambers and rectangular tubes was used to estimate the nonaqueous phase liquid (NAPL) dissolution rate coefficient, Kdissai, and NAPL/water total specific interfacial area, ai. Kdissai was computed as a function of modified Peclet number(Pe′) for various NAPL saturations (SN) and ai during drainage and imbibition and during dissolution without displacement. The lar
Authors
L.A. Dillard, H.I. Essaid, M.J. Blunt