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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Inter-annual changes in the benthic community structure of riffles and pools in reaches of contrasting gradient

The inter-annual variation in the structure of the benthic community of riffles and pools was evaluated in contrasting geomorphic settings. The community structure of riffles and pools was a function of habitat, reach gradient, and discharge and was taxon specific. In years of below average peak discharge, riffles had higher taxon richness than pools (66 versus 47) but richness was similar between
Authors
J.L. Carter, S.V. Fend

Trace metal concentrations in shallow ground water

Trace metal clean sampling and analysis techniques were used to examine the temporal patterns of Hg, Cu, and Zn concentrations in shallow ground water, and the relationships between metal concentrations in ground water and in a hydrologically connected river. Hg, Cu, and Zn concentrations in ground water ranged from 0.07 to 4.6 ng L−1, 0.07 to 3.10 μg L−1, and 0.17 to 2.18 μg L−1, respectively. Th
Authors
L.M. Zelewski, D. P. Krabbenhoft, D.E. Armstrong

Assessing an open-well aquifer test in fractured crystalline rock

Use of open wells to conduct aquifer tests in fractured crystalline rock aquifers is potentially problematic, because open wells can hydraulically connect highly permeable fracture zones at different depths within the rock. Because of this effect, it is questionable whether estimates of the hydraulic properties of the rock obtained from analysis of an open-well aquifer test in fractured crystallin
Authors
C. R. Tiedeman, P. A. Hsieh

Methyl t-Butyl Ether Mineralization in Surface-Water Sediment Microcosms under Denitrifying Conditions

Mineralization of [U-14C] methyl t-butyl ether (MTBE) to 14CO2 without accumulation of t-butyl alcohol (TBA) was observed in surface-water sediment microcosms under denitrifying conditions. Methanogenic activity and limited transformation of MTBE to TBA were observed in the absence of denitrification. Results indicate that bed sediment microorganisms can effectively degrade MTBE to nontoxic produc
Authors
P. M. Bradley, F. H. Chapelle, J. E. Landmeyer

Spectroscopic evidence for ternary surface complexes in the lead(II)-malonic acid-hematite system

Using extended X-ray absorption fine structure (EXAFS) and attenuated total reflectance Fourier-transform infrared (ATR-FTIR) measurements, we examined the sorption of Pb(II) to hematite in the presence of malonic acid. Pb LIII-edge EXAFS measurements performed in the presence of malonate indicate the presence of both Fe and C neighbors, suggesting that a major fraction of surface-bound malonate i
Authors
J.J. Lenhart, J.R. Bargar, J.A. Davis

A partition-limited model for the plant uptake of organic contaminants from soil and water

In dealing with the passive transport of organic contaminants from soils to plants (including crops), a partition-limited model is proposed in which (i) the maximum (equilibrium) concentration of a contaminant in any location in the plant is determined by partition equilibrium with its concentration in the soil interstitial water, which in turn is determined essentially by the concentration in the
Authors
C. T. Chiou, G. Sheng, M. Manes

Potential artifacts in interpretation of differential breakthrough of colloids and dissolved tracers in the context of transport in a zero-valent iron permeable reactive barrier

Many published studies have used visual comparison of the timing of peak breakthrough of colloids versus conservative dissolved tracers (hereafter referred to as dissolved tracers or tracers) in subsurface media to determine whether they are advected differently, and to elucidate the mechanisms of differential advection. This purely visual approach of determining differential advection may have ar
Authors
P. Zhang, W.P. Johnson, M.J. Piana, C. C. Fuller, D. L. Naftz

Distribution of inorganic mercury in Sacramento River water and suspended colloidal sediment material

The concentration and distribution of inorganic Hg was measured using cold-vapor atomic fluorescence spectrometry in samples collected at selected sites on the Sacramento River from below Shasta Dam to Freeport, CA, at six separate times between 1996 and 1997. Dissolved (ultrafiltered, 0.005 μm equivalent pore size) Hg concentrations remained relatively constant throughout the system, ranging from
Authors
D.A. Roth, Howard E. Taylor, Joseph L. Domagalski, Peter D. Dileanis, D.B. Peart, Ronald C. Antweiler, Charles N. Alpers

Identification of alkyl dimethylbenzylammonium surfactants in water samples by solid-phase extraction followed by ion trap LC/MS and LC/MS/MS

A novel methodology was developed for the determination of alkyl (C12, C14, and C16) dimethylbenzylammonium chloride (benzalkonium chloride or BAC, Chemical Abstract Service number: 8001-54-5) in water samples. This method is based on solid-phase extraction (SPE) using polymeric cartridges, followed by high-performance liquid chromatography/ion trap mass spectrometry (LC/MS) and tandem mass spectr
Authors
I. Ferrer, E. T. Furlong

Changes in the Onset of Spring in the Western United States

Fluctuations in spring climate in the western United States over the last 4-5 decades are described by examining changes in the blooming of plants and the timing of snowmelt-runoff pulses. The two measures of spring's onset that are employed are the timing of first bloom of lilac and honeysuckle bushes from a long-term cooperative phonological network, and the timing of the first major pulse of sn
Authors
D.R. Cayan, Susan A. Kammerdiener, M. D. Dettinger, Joseph M. Caprio, D.H. Peterson

Interaction of surface water and ground water in the Dutch Flats area, western Nebraska, 1995-99

No abstract available.
Authors
Ingrid M. Verstraeten, G. V. Steele, J. C. Cannia, D.E. Hitch, K.G. Scripter, J.K. Böhlke, T. F. Kraemer, J.S. Stanton

Quantification of metal loads by tracer injection and synoptic sampling in Daisy Creek and the Stillwater River, Park County, Montana, August 1999

A metal-loading study using tracer-injection and synoptic-sampling methods was conducted in Daisy Creek and a short reach of the Stillwater River during baseflow in August 1999 to quantify the metal inputs from acid rock drainage in the New World Mining District near Yellowstone National Park and to examine the downstream transport of these metals into the Stillwater River. Loads were calculated f
Authors
David A. Nimick, Thomas E. Cleasby