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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Suburbanization, estrogen contamination, and sex ratio in wild amphibian populations

Research on endocrine disruption in frog populations, such as shifts in sex ratios and feminization of males, has predominantly focused on agricultural pesticides. Recent evidence suggests that suburban landscapes harbor amphibian populations exhibiting similar levels of endocrine disruption; however the endocrine disrupting chemical (EDC) sources are unknown. Here, we show that sex ratios of meta
Authors
Max R. Lambert, Geoffrey S. J. Giller, Larry B. Barber, Kevin C. Fitzgerald, David K. Skelly

Biogeochemical aspects of uranium mineralization, mining, milling, and remediation

Natural uranium (U) occurs as a mixture of three radioactive isotopes: 238U, 235U, and 234U. Only 235U is fissionable and makes up about 0.7% of natural U, while 238U is overwhelmingly the most abundant at greater than 99% of the total mass of U. Prior to the 1940s, U was predominantly used as a coloring agent, and U-bearing ores were mined mainly for their radium (Ra) and/or vanadium (V) content;
Authors
Kate M. Campbell, Tanya J. Gallegos, Edward R. Landa

Diel cycling of trace elements in streams draining mineralized areas: a review

Many trace elements exhibit persistent diel, or 24-h, concentration cycles in streams draining mineralized areas. These cycles can be caused by various physical and biogeochemical mechanisms including streamflow variation, photosynthesis and respiration, as well as reactions involving photochemistry, adsorption and desorption, mineral precipitation and dissolution, and plant assimilation. Iron is
Authors
Christopher H. Gammons, David A. Nimick, Stephen R. Parker

AMDTreat 5.0+ with PHREEQC titration module to compute caustic chemical quantity, effluent quality, and sludge volume

Alkaline chemicals are commonly added to discharges from coal mines to increase pH and decrease concentrations of acidity and dissolved aluminum, iron, manganese, and associated metals. The annual cost of chemical treatment depends on the type and quantities of chemicals added and sludge produced. The AMDTreat computer program, initially developed in 2003, is widely used to compute such costs on t
Authors
Charles A. Cravotta, Brent P Means, Willam Arthur, Robert M McKenzie, David L. Parkhurst

Experimental dosing of wetlands with coagulants removes mercury from surface water and decreases mercury bioaccumulation in fish

Mercury pollution is widespread globally, and strategies for managing mercury contamination in aquatic environments are necessary. We tested whether coagulation with metal-based salts could remove mercury from wetland surface waters and decrease mercury bioaccumulation in fish. In a complete randomized block design, we constructed nine experimental wetlands in California’s Sacramento–San Joaquin D
Authors
Joshua T. Ackerman, Tamara E.C. Kraus, Jacob A. Fleck, David P. Krabbenhoft, William R. Horwarth, Sandra M. Bachand, Mark P. Herzog, C. Alex Hartman, Philip A.M. Bachand

Groundwater movement, recharge, and perchlorate occurrence in a faulted alluvial aquifer in California (USA)

Perchlorate from military, industrial, and legacy agricultural sources is present within an alluvial aquifer in the Rialto-Colton groundwater subbasin, 80 km east of Los Angeles, California (USA). The area is extensively faulted, with water-level differences exceeding 60 m across parts of the Rialto-Colton Fault separating the Rialto-Colton and Chino groundwater subbasins. Coupled well-bore flow a
Authors
John A. Izbicki, Nicholas F. Teague, Paul B. Hatzinger, John Karl Böhlke, Neil C. Sturchio

Genes indicative of zoonotic and swine pathogens are persistent in stream water and sediment following a swine manure spill

Manure spills to streams are relatively frequent, but no studies have characterized stream contamination with zoonotic and veterinary pathogens, or fecal chemicals, following a spill. We tested stream water and sediment over 25 days and downstream for 7.6 km for: fecal indicator bacteria (FIB); the fecal indicator chemicals cholesterol and coprostanol; 20 genes for zoonotic and swine-specific bact
Authors
Sheridan K. Haack, Joseph W. Duris, Dana W. Kolpin, Lisa R. Fogarty, Heather E. Johnson, Kristen E. Gibson, Michael J. Focazio, Kellogg J. Schwab, Laura E. Hubbard, William T. Foreman

Females exceed males in mercury concentrations of burbot Lota lota

Examination of differences in contaminant concentrations between sexes of fish, across several fish species, may reveal clues for important behavioral and physiological differences between the sexes. We determined whole-fish total mercury (Hg) concentrations of 25 male and 25 female adult burbot Lota lota captured in Lake Erie during summer 2011, and of 14 male and 18 female adult burbot captured
Authors
Charles P. Madenjian, Martin A. Stapanian, Peter A. Cott, David P. Krabbenhoft, William Edwards, Lynn M. Ogilvie, Justin G. Mychek-Londer, John F. DeWild

Characterization of hydraulic fracturing flowback water in Colorado: Implications for water treatment

A suite of analytical tools was applied to thoroughly analyze the chemical composition of an oil/gas well flowback water from the Denver–Julesburg (DJ) basin in Colorado, and the water quality data was translated to propose effective treatment solutions tailored to specific reuse goals. Analysis included bulk quality parameters, trace organic and inorganic constituents, and organic matter characte
Authors
Yaal Lester, Imma Ferrer, E. Michael Thurman, Kurban A. Sitterley, Julie A. Korak, George R. Aiken, Karl G. Linden

Biokinetics of different-shaped copper oxide nanoparticles in the freshwater gastropod, Potamopyrgus antipodarum

Sediment is recognized as a major environmental sink for contaminants, including engineered nanoparticles (NPs). Consequently, sediment-living organisms are likely to be exposed to NPs. There is evidence that both accumulation and toxicity of metal NPs to sediment-dwellers increase with decreasing particle size, although NP size does not always predict effects. In contrast, not much is known about
Authors
Tina Ramskov, Marie Noële Croteau, Valery E. Forbes, Henriette Selck

Endocrine disrupting alkylphenolic chemicals and other contaminants in wastewater treatment plant effluents, urban streams, and fish in the Great Lakes and Upper Mississippi River Regions

Urban streams are an integral part of the municipal water cycle and provide a point of discharge for wastewater treatment plant (WWTP) effluents, allowing additional attenuation through dilution and transformation processes, as well as a conduit for transporting contaminants to downstream water supplies. Domestic and commercial activities dispose of wastes down-the-drain, resulting in wastewater c
Authors
Larry B. Barber, Jorge E. Loyo-Rosales, Clifford P. Rice, Thomas A. Minarik, Ali K. Oskouie

Advances in interpretation of subsurface processes with time-lapse electrical imaging

Electrical geophysical methods, including electrical resistivity, time-domain induced polarization, and complex resistivity, have become commonly used to image the near subsurface. Here, we outline their utility for time-lapse imaging of hydrological, geochemical, and biogeochemical processes, focusing on new instrumentation, processing, and analysis techniques specific to monitoring. We review da
Authors
Kaminit Singha, Frederick D. Day-Lewis, Tim B. Johnson, Lee D. Slater