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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

A comparison of pre- and post-remediation water quality, Mineral Creek, Colorado

Pre- and post-remediation data sets are used herein to assess the effectiveness of remedial measures implemented in the headwaters of the Mineral Creek watershed, where contamination from hard rock mining has led to elevated metal concentrations and acidic pH. Collection of pre- and post-remediation data sets generally followed the synoptic mass balance approach, in which numerous stream and inflo
Authors
R.L. Runkel, K.E. Bencala, B. A. Kimball, K. Walton-Day, P. L. Verplanck

Elevated naturally occurring arsenic in a semiarid oxidizing system, Southern High Plains aquifer, Texas, USA

High groundwater As concentrations in oxidizing systems are generally associated with As adsorption onto hydrous metal (Al, Fe or Mn) oxides and mobilization with increased pH. The objective of this study was to evaluate the distribution, sources and mobilization mechanisms of As in the Southern High Plains (SHP) aquifer, Texas, relative to those in other semiarid, oxidizing systems. Elevated grou
Authors
Bridget R. Scanlon, J.-P. Nicot, R.C. Reedy, D. Kurtzman, A. Mukherjee, D. Kirk Nordstrom

Enantiomer fractions of chlordane components in sediment from U.S. Geological Survey sites in lakes and rivers

Spatial, temporal, and sediment-type trends in enantiomer signatures were evaluated for cis- and trans-chlordane (CC, TC) in archived core, suspended, and surficial-sediment samples from six lake, reservoir, and river sites across the United States. The enantiomer fractions (EFs) measured in these samples are in good agreement with those reported for sediment, soil, and air samples in previous stu
Authors
E.M. Ulrich, W.T. Foreman, P. C. Van Metre, J.T. Wilson, S.A. Rounds

Rapid changes in small fish mercury concentrations in estuarine wetlands: Implications for wildlife risk and monitoring programs

Small fish are commonly used to assess mercury (Hg) risk to wildlife and monitor Hg in wetlands. However, limited research has evaluated short-term Hg variability in small fish, which can have important implications for monitoring programs and risk assessment. We conducted a time-series study of Hg concentrations in two small fish species representing benthic (longjaw mudsuckers [Gillichthys mirab
Authors
Collin A. Eagles-Smith, Joshua T. Ackerman

Polybrominated diphenyl ether flame retardants in eggs may reduce reproductive success of ospreys in Oregon and Washington, USA

Spatial and temporal assessments and reports of polybrominated diphenyl ether (PBDE) flame retardants in birds remain sparse. In the present study, PBDEs were detected in all 120 osprey (Pandion haliaetus) eggs collected. The eggs were collected from nests along the Columbia, Willamette and Yakima rivers of Oregon (OR) and Washington (WA) and in Puget Sound (WA) between 2002 and 2007. PBDE congene
Authors
C. J. Henny, J.L. Kaiser, R. A. Grove, B. L. Johnson, R.J. Letcher

Contrasting residence times and fluxes of water and sulfate in two small forested watersheds in Virginia, USA

Watershed mass balances for solutes of atmospheric origin may be complicated by the residence times of water and solutes at various time scales. In two small forested headwater catchments in the Appalachian Mountains of Virginia, USA, mean annual export rates of SO4= differ by a factor of 2, and seasonal variations in SO4= concentrations in atmospheric deposition and stream water are out of phase.
Authors
J.K. Böhlke, R. L. Michel

High-quality unsaturated zone hydraulic property data for hydrologic applications

In hydrologic studies, especially those using dynamic unsaturated zone moisture modeling, calculations based on property transfer models informed by hydraulic property databases are often used in lieu of measured data from the site of interest. Reliance on database-informed predicted values has become increasingly common with the use of neural networks. High-quality data are needed for databases u
Authors
Kimberlie Perkins, John R. Nimmo

Obtaining parsimonious hydraulic conductivity fields using head and transport observations: A Bayesian geostatistical parameter estimation approach

Flow path delineation is a valuable tool for interpreting the subsurface hydrogeochemical environment. Different types of data, such as groundwater flow and transport, inform different aspects of hydrogeologic parameter values (hydraulic conductivity in this case) which, in turn, determine flow paths. This work combines flow and transport information to estimate a unified set of hydrogeologic para
Authors
Michael N. Fienen, R. Hunt, D. Krabbenhoft, T. Clemo

Geoelectrical measurement and modeling of biogeochemical breakthrough behavior during microbial activity

We recorded bulk electrical conductivity (σb) along a soil column during microbially-mediated selenite oxyanion reduction. Effluent fluid electrical conductivity and early time σb were modeled according to classic advective-dispersive transport of the nutrient medium. However, σb along the column exhibited strongly bimodal breakthrough which cannot be explained by changes in the electrical conduct
Authors
L.D. Slater, Frederick D. Day-Lewis, D. Ntarlagiannis, M. O'Brien, N. Yee

Fate of sulfamethoxazole, 4-nonylphenol, and 17β-estradiol in groundwater contaminated by wastewater treatment plant effluent

Organic wastewater contaminants (OWCs) were measured in samples collected from monitoring wells located along a 4.5-km transect of a plume of groundwater contaminated by 60 years of continuous rapid infiltration disposal of wastewater treatment plant effluent. Fifteen percent of the 212 OWCs analyzed were detected, including the antibiotic sulfamethoxazole (SX), the nonionic surfactant degradation
Authors
Larry B. Barber, Steffanie H. Keefe, Denis R. LeBlanc, Paul M. Bradley, Francis H. Chapelle, Michael T. Meyer, Keith A. Loftin, Dana W. Koplin, Fernando Rubio

Predicting dietborne metal toxicity from metal influxes

Dietborne metal uptake prevails for many species in nature. However, the links between dietary metal exposure and toxicity are not well understood. Sources of uncertainty include the lack of suitable tracers to quantify exposure for metals such as copper, the difficulty to assess dietary processes such as food ingestion rate, and the complexity to link metal bioaccumulation and effects. We charact
Authors
M.-N. Croteau, S. N. Luoma

Gene and antigen markers of Shiga-toxin producing E. coli from Michigan and Indiana river water: Occurrence and relation to recreational water quality criteria

The relation of bacterial pathogen occurrence to fecal indicator bacteria (FIB) concentrations used for recreational water quality criteria (RWQC) is poorly understood. This study determined the occurrence of Shiga-toxin producing Escherichia coli (STEC) markers and their relation to FIB concentrations in Michigan and Indiana river water. Using 67 fecal coliform (FC) bacteria cultures from 41 rive
Authors
J.W. Duris, S.K. Haack, L.R. Fogarty