Karen R Murray, Ph.D. (Former Employee)
Science and Products
Mercury Bioaccumulation in Fish in New York's Streams and Rivers
Background Although New York State has more than 70,000 miles of streams and rivers, little is known about the status, distribution, and trends of mercury (Hg) levels in stream fish, or the environmental drivers of these patterns. Streams and their riparian zones provide critical habitat for fish, birds, mammals, reptiles and amphibians, and serve as the interface between aquatic and...
Effects of flow alteration on ecological health of streams across the Atlantic Highlands Ecoregion
Problem: The Clean Water Act (PL 92-500) requires that the health of the Nation’s rivers and streams be assessed on a regular basis, and in the Northeast such assessments often use information from aquatic biological communities that live in the stream. Biomonitoring programs implemented by individual states evaluate biological data to assess stream health on the premise that certain...
The Effectiveness of Total Mercury as a Surrogate for Methylmercury in Aquatic Invertebrates
A. BACKGROUND Aquatic macroinvertebrates, such as dragonfly larvae or crayfish have great potential for Mercury (Hg) monitoring, both as indicator organisms (or "sentinels'), and to provide critical information on Hg in lower food webs to assist in interpreting fish Hg levels. Despite these advantages, macroinvertebrates are not widely used in Hg monitoring because of the current need to...
Mercury Cycling and Bioaccumulation in the Upper Hudson River Basin--Fishing Brook
BackgroundDetailed investigations of mercury cycling and bioaccumulation have been done in the Upper Hudson River basin (upstream of the Hudson River near Newcomb, in New York's Adirondack Mountains, with a focus on the Fishing Brook sub-basin, part of the western headwaters of the Hudson River. This study is part of a National mercury study that includes a concurrent study of McTier...
The Effects of Watershed and Stream Liming on Mercury Dynamics at Honnedaga Lake
Problem The Adirondack region of New York has 128 lakes that are listed as impaired by acidity under section 303(d) of the Clean Water Act. Acidity can limit the survival and reproduction of native fishes such as brook trout (Salvelinus fontinalis). Chronic and episodic acidification also stresses fish, aquatic macroinvertebrates, and other biota of inflowing tributaries of these and...
Potential Recovery of Water Chemistry and Stream Biota from Reduced Levels of Acid Deposition at a Sensitive Watershed in the Catskill Mountains, New York
The Catskill Mountains of southeastern New York receive among the highest loads of acid deposition in New York and the northeastern U.S. Additionally, the Catskills are underlain by sandstone and conglomerate, which is base poor and weathers slowly. Thus, the Catskills contain numerous streams with low (< 50 µeq/L) acid-neutralizing capacity (ANC) and are sensitive to impacts from...
Methylmercury and associated data in macroinvertebrates from tributaries of Honnedaga Lake and from the Middle Branch Black River in New York.
Macroinvertebrate samples were collected from streams tributary to Honnedaga Lake and from the Middle Branch of the Black River during 2012-2016 and analyzed for methylmercury concentrations and for stable isotope ratios of nitrogen and carbon. Macroinvertebrates were identified in the field, and the level of taxonomic resolution varied from order to species; most taxa were identified to...
Fish mercury concentration data and ancillary data for streams and rivers across New York States (United States), 1969-2016, including environmental characteristics of selected locations sampled during 2007-16
Fish mercury (Hg) data were compiled for 392 unique locations on freshwater streams and rivers in New York State for the period 1969-2016. A total of 7620 records were compiled from state, federal, and non-governmental organization databases. The compiled data were for samples of 65 non-anadromous species or species groups in which Hg was analyzed in whole fish or edible flesh, and for...
Filter Total Items: 38
Identifying monitoring information needs that support the management of fish in large rivers
Management actions intended to benefit fish in large rivers can directly or indirectly affect multiple ecosystem components. Without consideration of the effects of management on non-target ecosystem components, unintended consequences may limit management efficacy. Monitoring can help clarify the effects of management actions, including on non-target ecosystem components, but only if...
Authors
Timothy D. Counihan, Kristen L. Bouska, Shannon K. Brewer, Robert B. Jacobson, Andrew F. Casper, Colin G. Chapman, Ian R. Waite, Kenneth R. Sheehan, Mark Pyron, Elise R. Irwin, Karen Riva-Murray, Alexa McKerrow, Jennifer M. Bayer
Ratios of methylmercury to total mercury in predator and primary consumer insects from Adirondack streams in New York State
Mercury (Hg) is a global pollutant that affects aquatic biota in otherwise pristine settings such as the Adirondack region of New York State. Bioaccumulation of Hg is especially problematic in sensitive landscapes, where inorganic mercury from atmospheric deposition is readily converted, via natural processes, to methylmercury (MeHg), the toxic form that is taken up and biomagnified in...
Authors
Karen Riva-Murray
The impact of lime additions on mercury dynamics in stream chemistry and macroinvertebrates: A comparison of watershed and direct stream addition management strategies
Acid deposition has declined across eastern North America and northern Europe due to reduced emissions of sulfur and nitrogen oxides. Ecosystem recovery has been slow with limited improvement in surface water chemistry. Delayed recovery has encouraged acid-neutralization strategies to accelerate recovery of impaired biological communities. Lime application has been shown to increase pH...
Authors
Geoffrey D. Millard, Karen Riva-Murray, Douglas A. Burns, Mario S. Montesdeoca, Charles T. Driscoll
Mercury in fish from streams and rivers in New York State: Spatial patterns, temporal changes, and environmental drivers
Mercury (Hg) concentrations in freshwater fish across the state of New York frequently exceed guidelines considered harmful to humans and wildlife, but statewide distribution and temporal changes are not well known for the state’s streams and rivers. We analyzed existing data to describe recent spatial patterns, identify key environmental drivers, and assess temporal changes. Size...
Authors
Karen Riva-Murray, Wayne Richter, N. Roxanna Razavi, Douglas A. Burns, Lisa B Cleckner, Mark Burton, Scott George, Douglas A. Freehafer
Methylmercury-Total mercury ratios in predator and primary consumer insects from Adirondack streams (New York, USA)
Mercury (Hg) is a global pollutant that affects biota in remote settings due to atmospheric deposition of inorganic Hg, and its conversion to methylmercury (MeHg), the bioaccumulating and toxic form. Characterizing biotic MeHg is important for evaluating aquatic ecosystem responses to changes in Hg inputs. Aquatic insects possess many qualities desired for MeHg biomonitoring, but are not...
Authors
Karen Riva-Murray, Paul M. Bradley, Mark E. Brigham
Chemical and physical controls on mercury source signatures in stream fish from the northeastern United States
Streams in the northeastern U.S. receive mercury (Hg) in varying proportions from atmospheric deposition and legacy point sources, making it difficult to attribute shifts in fish concentrations directly back to changes in Hg source management. Mercury stable isotope tracers were utilized to relate sources of Hg to co-located fish and bed sediments from 23 streams across a forested to...
Authors
Sarah Elizabeth Janssen, Karen Riva-Murray, John F. DeWild, Jacob M. Ogorek, Michael Tate, Peter C. Van Metre, David Krabbenhoft, James F. Coles
Design and methods of the U.S. Geological Survey Northeast Stream Quality Assessment (NESQA), 2016
During 2016, as part of the National Water-Quality Assessment Project (NAWQA), the U.S. Geological Survey conducted the Northeast Stream Quality Assessment (NESQA) to investigate stream quality in the northeastern United States. The goal of the NESQA was to assess the health of wadeable streams in the region by characterizing multiple water-quality factors that are stressors to aquatic...
Authors
James F. Coles, Karen Riva-Murray, Peter C. Van Metre, Daniel T. Button, Amanda H. Bell, Sharon L. Qi, Celeste A. Journey, Rich W. Sheibley
Response of mercury in an Adirondack (NY, USA) forest stream to watershed lime application
Surface waters in Europe and North America previously impacted by acid deposition are recovering in conjunction with declining precursor emissions since the 1980s. Lime has been applied to some impacted watersheds to accelerate recovery. The response to liming can be considered a proxy for future recovery from acid deposition. Increases in dissolved organic carbon concentrations have...
Authors
Geoffrey D. Millard, Charles T. Driscoll, Douglas A. Burns, Mario S. Montesdeoca, Karen Riva-Murray
Variation in fish mercury concentrations in streams of the Adirondack region, New York: A simplified screening approach using chemical metrics
Simple screening approaches for the neurotoxicant methylmercury (MeHg) in aquatic ecosystems may be helpful in risk assessments of natural resources. We explored the development of such an approach in the Adirondack Mountains of New York, USA, a region with high levels of MeHg bioaccumulation. Thirty-six perennial streams broadly representative of 1st and 2nd order streams in the region...
Authors
Douglas A. Burns, Karen Riva-Murray
A new look at liming as an approach to accelerate recovery from acidic deposition effects
Acidic deposition caused by fossil fuel combustion has degraded aquatic and terrestrial ecosystems in North America for over four decades. The only management option other than emissions reductions for combating the effects of acidic deposition has been the application of lime to neutralize acidity after it has been deposited on the landscape. For this reason, liming has been a part of...
Authors
Gregory Lawrence, Douglas A. Burns, Karen Riva-Murray
The Northeast Stream Quality Assessment
In 2016, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) is assessing stream quality in the northeastern United States. The goal of the Northeast Stream Quality Assessment (NESQA) is to assess the quality of streams in the region by characterizing multiple water-quality factors that are stressors to aquatic life and evaluating the relation between these...
Authors
Peter C. Van Metre, Karen Riva-Murray, James F. Coles
Hydraulic and biochemical gradients limit wetland mercury supply to an Adirondack stream
Net fluxes (change between upstream and downstream margins) for water, methylmercury (MeHg), total mercury (THg), dissolved organic carbon (DOC), and chloride (Cl) were assessed twice in an Adirondack stream reach (Sixmile Brook, USA), to test the hypothesized importance of wetland-stream hydraulic and chemical gradients as fundamental controls on fluvial mercury (Hg) supply. The 500 m...
Authors
Paul M. Bradley, Douglas A. Burns, Judson Harvey, Celeste A. Journey, Mark E. Brigham, Karen Riva-Murray
Science and Products
Mercury Bioaccumulation in Fish in New York's Streams and Rivers
Background Although New York State has more than 70,000 miles of streams and rivers, little is known about the status, distribution, and trends of mercury (Hg) levels in stream fish, or the environmental drivers of these patterns. Streams and their riparian zones provide critical habitat for fish, birds, mammals, reptiles and amphibians, and serve as the interface between aquatic and...
Effects of flow alteration on ecological health of streams across the Atlantic Highlands Ecoregion
Problem: The Clean Water Act (PL 92-500) requires that the health of the Nation’s rivers and streams be assessed on a regular basis, and in the Northeast such assessments often use information from aquatic biological communities that live in the stream. Biomonitoring programs implemented by individual states evaluate biological data to assess stream health on the premise that certain...
The Effectiveness of Total Mercury as a Surrogate for Methylmercury in Aquatic Invertebrates
A. BACKGROUND Aquatic macroinvertebrates, such as dragonfly larvae or crayfish have great potential for Mercury (Hg) monitoring, both as indicator organisms (or "sentinels'), and to provide critical information on Hg in lower food webs to assist in interpreting fish Hg levels. Despite these advantages, macroinvertebrates are not widely used in Hg monitoring because of the current need to...
Mercury Cycling and Bioaccumulation in the Upper Hudson River Basin--Fishing Brook
BackgroundDetailed investigations of mercury cycling and bioaccumulation have been done in the Upper Hudson River basin (upstream of the Hudson River near Newcomb, in New York's Adirondack Mountains, with a focus on the Fishing Brook sub-basin, part of the western headwaters of the Hudson River. This study is part of a National mercury study that includes a concurrent study of McTier...
The Effects of Watershed and Stream Liming on Mercury Dynamics at Honnedaga Lake
Problem The Adirondack region of New York has 128 lakes that are listed as impaired by acidity under section 303(d) of the Clean Water Act. Acidity can limit the survival and reproduction of native fishes such as brook trout (Salvelinus fontinalis). Chronic and episodic acidification also stresses fish, aquatic macroinvertebrates, and other biota of inflowing tributaries of these and...
Potential Recovery of Water Chemistry and Stream Biota from Reduced Levels of Acid Deposition at a Sensitive Watershed in the Catskill Mountains, New York
The Catskill Mountains of southeastern New York receive among the highest loads of acid deposition in New York and the northeastern U.S. Additionally, the Catskills are underlain by sandstone and conglomerate, which is base poor and weathers slowly. Thus, the Catskills contain numerous streams with low (< 50 µeq/L) acid-neutralizing capacity (ANC) and are sensitive to impacts from...
Methylmercury and associated data in macroinvertebrates from tributaries of Honnedaga Lake and from the Middle Branch Black River in New York.
Macroinvertebrate samples were collected from streams tributary to Honnedaga Lake and from the Middle Branch of the Black River during 2012-2016 and analyzed for methylmercury concentrations and for stable isotope ratios of nitrogen and carbon. Macroinvertebrates were identified in the field, and the level of taxonomic resolution varied from order to species; most taxa were identified to...
Fish mercury concentration data and ancillary data for streams and rivers across New York States (United States), 1969-2016, including environmental characteristics of selected locations sampled during 2007-16
Fish mercury (Hg) data were compiled for 392 unique locations on freshwater streams and rivers in New York State for the period 1969-2016. A total of 7620 records were compiled from state, federal, and non-governmental organization databases. The compiled data were for samples of 65 non-anadromous species or species groups in which Hg was analyzed in whole fish or edible flesh, and for...
Filter Total Items: 38
Identifying monitoring information needs that support the management of fish in large rivers
Management actions intended to benefit fish in large rivers can directly or indirectly affect multiple ecosystem components. Without consideration of the effects of management on non-target ecosystem components, unintended consequences may limit management efficacy. Monitoring can help clarify the effects of management actions, including on non-target ecosystem components, but only if...
Authors
Timothy D. Counihan, Kristen L. Bouska, Shannon K. Brewer, Robert B. Jacobson, Andrew F. Casper, Colin G. Chapman, Ian R. Waite, Kenneth R. Sheehan, Mark Pyron, Elise R. Irwin, Karen Riva-Murray, Alexa McKerrow, Jennifer M. Bayer
Ratios of methylmercury to total mercury in predator and primary consumer insects from Adirondack streams in New York State
Mercury (Hg) is a global pollutant that affects aquatic biota in otherwise pristine settings such as the Adirondack region of New York State. Bioaccumulation of Hg is especially problematic in sensitive landscapes, where inorganic mercury from atmospheric deposition is readily converted, via natural processes, to methylmercury (MeHg), the toxic form that is taken up and biomagnified in...
Authors
Karen Riva-Murray
The impact of lime additions on mercury dynamics in stream chemistry and macroinvertebrates: A comparison of watershed and direct stream addition management strategies
Acid deposition has declined across eastern North America and northern Europe due to reduced emissions of sulfur and nitrogen oxides. Ecosystem recovery has been slow with limited improvement in surface water chemistry. Delayed recovery has encouraged acid-neutralization strategies to accelerate recovery of impaired biological communities. Lime application has been shown to increase pH...
Authors
Geoffrey D. Millard, Karen Riva-Murray, Douglas A. Burns, Mario S. Montesdeoca, Charles T. Driscoll
Mercury in fish from streams and rivers in New York State: Spatial patterns, temporal changes, and environmental drivers
Mercury (Hg) concentrations in freshwater fish across the state of New York frequently exceed guidelines considered harmful to humans and wildlife, but statewide distribution and temporal changes are not well known for the state’s streams and rivers. We analyzed existing data to describe recent spatial patterns, identify key environmental drivers, and assess temporal changes. Size...
Authors
Karen Riva-Murray, Wayne Richter, N. Roxanna Razavi, Douglas A. Burns, Lisa B Cleckner, Mark Burton, Scott George, Douglas A. Freehafer
Methylmercury-Total mercury ratios in predator and primary consumer insects from Adirondack streams (New York, USA)
Mercury (Hg) is a global pollutant that affects biota in remote settings due to atmospheric deposition of inorganic Hg, and its conversion to methylmercury (MeHg), the bioaccumulating and toxic form. Characterizing biotic MeHg is important for evaluating aquatic ecosystem responses to changes in Hg inputs. Aquatic insects possess many qualities desired for MeHg biomonitoring, but are not...
Authors
Karen Riva-Murray, Paul M. Bradley, Mark E. Brigham
Chemical and physical controls on mercury source signatures in stream fish from the northeastern United States
Streams in the northeastern U.S. receive mercury (Hg) in varying proportions from atmospheric deposition and legacy point sources, making it difficult to attribute shifts in fish concentrations directly back to changes in Hg source management. Mercury stable isotope tracers were utilized to relate sources of Hg to co-located fish and bed sediments from 23 streams across a forested to...
Authors
Sarah Elizabeth Janssen, Karen Riva-Murray, John F. DeWild, Jacob M. Ogorek, Michael Tate, Peter C. Van Metre, David Krabbenhoft, James F. Coles
Design and methods of the U.S. Geological Survey Northeast Stream Quality Assessment (NESQA), 2016
During 2016, as part of the National Water-Quality Assessment Project (NAWQA), the U.S. Geological Survey conducted the Northeast Stream Quality Assessment (NESQA) to investigate stream quality in the northeastern United States. The goal of the NESQA was to assess the health of wadeable streams in the region by characterizing multiple water-quality factors that are stressors to aquatic...
Authors
James F. Coles, Karen Riva-Murray, Peter C. Van Metre, Daniel T. Button, Amanda H. Bell, Sharon L. Qi, Celeste A. Journey, Rich W. Sheibley
Response of mercury in an Adirondack (NY, USA) forest stream to watershed lime application
Surface waters in Europe and North America previously impacted by acid deposition are recovering in conjunction with declining precursor emissions since the 1980s. Lime has been applied to some impacted watersheds to accelerate recovery. The response to liming can be considered a proxy for future recovery from acid deposition. Increases in dissolved organic carbon concentrations have...
Authors
Geoffrey D. Millard, Charles T. Driscoll, Douglas A. Burns, Mario S. Montesdeoca, Karen Riva-Murray
Variation in fish mercury concentrations in streams of the Adirondack region, New York: A simplified screening approach using chemical metrics
Simple screening approaches for the neurotoxicant methylmercury (MeHg) in aquatic ecosystems may be helpful in risk assessments of natural resources. We explored the development of such an approach in the Adirondack Mountains of New York, USA, a region with high levels of MeHg bioaccumulation. Thirty-six perennial streams broadly representative of 1st and 2nd order streams in the region...
Authors
Douglas A. Burns, Karen Riva-Murray
A new look at liming as an approach to accelerate recovery from acidic deposition effects
Acidic deposition caused by fossil fuel combustion has degraded aquatic and terrestrial ecosystems in North America for over four decades. The only management option other than emissions reductions for combating the effects of acidic deposition has been the application of lime to neutralize acidity after it has been deposited on the landscape. For this reason, liming has been a part of...
Authors
Gregory Lawrence, Douglas A. Burns, Karen Riva-Murray
The Northeast Stream Quality Assessment
In 2016, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) is assessing stream quality in the northeastern United States. The goal of the Northeast Stream Quality Assessment (NESQA) is to assess the quality of streams in the region by characterizing multiple water-quality factors that are stressors to aquatic life and evaluating the relation between these...
Authors
Peter C. Van Metre, Karen Riva-Murray, James F. Coles
Hydraulic and biochemical gradients limit wetland mercury supply to an Adirondack stream
Net fluxes (change between upstream and downstream margins) for water, methylmercury (MeHg), total mercury (THg), dissolved organic carbon (DOC), and chloride (Cl) were assessed twice in an Adirondack stream reach (Sixmile Brook, USA), to test the hypothesized importance of wetland-stream hydraulic and chemical gradients as fundamental controls on fluvial mercury (Hg) supply. The 500 m...
Authors
Paul M. Bradley, Douglas A. Burns, Judson Harvey, Celeste A. Journey, Mark E. Brigham, Karen Riva-Murray