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Variations in pesticide leaching related to land use, pesticide properties, and unsaturated zone thickness

Pesticide leaching through variably thick soils beneath agricultural fields in Morgan Creek, Maryland was simulated for water years 1995 to 2004 using LEACHM (Leaching Estimation and Chemistry Model). Fifteen individual models were constructed to simulate five depths and three crop rotations with associated pesticide applications. Unsaturated zone thickness averaged 4.7 m but reached a maximum of
Authors
R.M.T. Webb, M.E. Wieczorek, B. T. Nolan, T.C. Hancock, Mark W. Sandstrom, J.E. Barbash, E.R. Bayless, R. W. Healy, J. Linard

Comparative study of transport processes of nitrogen, phosphorus, and herbicides to streams in five agricultural basins, USA

Agricultural chemical transport to surface water and the linkage to other hydrological compartments, principally ground water, was investigated at five watersheds in semiarid to humid climatic settings. Chemical transport was affected by storm water runoff, soil drainage, irrigation, and how streams were linked to shallow ground water systems. Irrigation practices and timing of chemical use greatl
Authors
Joseph L. Domagalski, S. Ator, R. Coupe, K. McCarthy, D. Lampe, Mark W. Sandstrom, N. Baker

Pesticide fate and transport throughout unsaturated zones in five agricultural settings, USA

Pesticide transport through the unsaturated zone is a function of chemical and soil characteristics, application, and water recharge rate. The fate and transport of 82 pesticides and degradates were investigated at five different agricultural sites. Atrazine and metolachlor, as well as several of the degradates of atrazine, metolachlor, acetochlor, and alachlor, were frequently detected in soil wa
Authors
T.C. Hancock, Mark W. Sandstrom, J. R. Vogel, R.M.T. Webb, E.R. Bayless, J.E. Barbash

Occurrence and fate of pesticides in four contrasting agricultural settings in the United States

Occurrence and fate of 45 pesticides and 40 pesticide degradates were investigated in four contrasting agricultural settings—in Maryland, Nebraska, California, and Washington. Primary crops included corn at all sites, soybeans in Maryland, orchards in California and Washington, and vineyards in Washington. Pesticides and pesticide degradates detected in water samples from all four areas were predo
Authors
G. V. Steele, H.M. Johnson, Mark W. Sandstrom, P. D. Capel, J.E. Barbash

Is there a risk associated with the insect repellent DEET (N,N-diethyl-m-toluamide) commonly found in aquatic environments?

DEET (N,N-diethyl-m-toluamide) is the active ingredient of most commercial insect repellents. This compound has commonly been detected in aquatic water samples from around the world indicating that DEET is both mobile and persistent, despite earlier assumptions that DEET was unlikely to enter aquatic ecosystems. DEET's registration category does not require an ecological risk assessment, thus info
Authors
S.D. Costanzo, A.J. Watkinson, E.J. Murby, Dana W. Kolpin, Mark W. Sandstrom

Mineralogy and Morphology of Amphiboles Observed in Soils and Rocks in El Dorado Hills, California

From the Executive Summary: At the request of the U.S. Environmental Protection Agency (USEPA), the U.S. Geological Survey (USGS) has conducted an independent study of amphiboles in rocks and soils in the El Dorado Hills, California, area. The purpose of this study is to investigate specific issues regarding the presence of 'naturally occurring asbestos' raised by an USEPA activity-based sampling
Authors
G.P. Meeker, H.A. Lowers, G.A. Swayze, B. S. Van Gosen, S. J. Sutley, I. K. Brownfield

Determination of wastewater compounds in whole water by continuous liquid-liquid extraction and capillary-column gas chromatography/mass spectrometry

A method for the determination of 69 compounds typically found in domestic and industrial wastewater is described. The method was developed in response to increasing concern over the impact of endocrine-disrupting chemicals on aquatic organisms in wastewater. This method also is useful for evaluating the effects of combined sanitary and storm-sewer overflow on the water quality of urban streams. T
Authors
Steven D. Zaugg, Steven G. Smith, Michael P. Schroeder

Occurrence of organic wastewater compounds in drinking water, wastewater effluent, and the Big Sioux River in or near Sioux Falls, South Dakota, 2001-2004

The U.S. Geological Survey (USGS) in cooperation with the city of Sioux Falls conducted several rounds of sampling to determine the occurrence of organic wastewater compounds (OWCs) in the city of Sioux Falls drinking water and waste-water effluent, and the Big Sioux River in or near Sioux Falls during August 2001 through May 2004. Water samples were collected during both base-flow and storm-runof
Authors
Steven K. Sando, Edward T. Furlong, James L. Gray, Michael T. Meyer

Results of analyses of the fungicide Chlorothalonil, its degradation products, and other selected pesticides at 22 surface-water sites in five Southern states, 2003-04

In accordance with the mission of the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program, a pesticide study was conducted during 2003–04 to determine the occurrence of the fungicide chlorothalonil and its degradation products at 22 surface-water sites in five Southern States. Water-quality samples were collected during the peanut-growing season (June–September) in 2003. During the pe
Authors
Elisabeth A. Scribner, James L. Orlando, William A. Battaglin, Mark W. Sandstrom, Kathryn Kuivila, Michael T. Meyer

Section 3. The SPARROW Surface Water-Quality Model—Theory, application and user documentation

SPARROW (SPAtially Referenced Regressions On Watershed attributes) is a watershed modeling technique for relating water-quality measurements made at a network of monitoring stations to attributes of the watersheds containing the stations. The core of the model consists of a nonlinear regression equation describing the non-conservative transport of contaminants from point and diffuse sources on lan
Authors
Gregory Schwarz, Anne B. Hoos, R. B. Alexander, R. A. Smith

Chapter 3. Determination of semivolatile organic compounds and polycyclic aromatic hydrocarbons in solids by gas chromatography/mass spectrometry

A method for the determination of 38 polycyclic aromatic hydrocarbons (PAHs) and semivolatile organic compounds in solid samples is described. Samples are extracted using a pressurized solvent extraction system. The compounds of interest are extracted from the solid sample twice at 13,800 kilopascals; first at 120 degrees Celsius using a water/isopropyl alcohol mixture (50:50, volume-to-volume rat
Authors
Steven D. Zaugg, Mark R. Burkhardt, Teresa L. Burbank, Mary C. Olson, Jana L. Iverson, Michael P. Schroeder