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Chemical loading into surface water along a hydrological, biogeochemical, and land use gradient: A holistic watershed approach

Identifying the sources and impacts of organic and inorganic contaminants at the watershed scale is a complex challenge because of the multitude of processes occurring in time and space. Investigation of geochemical transformations requires a systematic evaluation of hydrologic, landscape, and anthropogenic factors. The 1160 km2 Boulder Creek Watershed in the Colorado Front Range encompasses a gra
Authors
L. B. Barber, S.F. Murphy, P. L. Verplanck, Mark W. Sandstrom, Howard E. Taylor, E. T. Furlong

Speciation of volatile arsenic at geothermal features in Yellowstone National Park

Geothermal features in the Yellowstone National Park contain up to several milligram per liter of aqueous arsenic. Part of this arsenic is volatilized and released into the atmosphere. Total volatile arsenic concentrations of 0.5–200 mg/m3 at the surface of the hot springs were found to exceed the previously assumed nanogram per cubic meter range of background concentrations by orders of magnitude
Authors
B. Planer-Friedrich, C. Lehr, J. Matschullat, B.J. Merkel, D. Kirk Nordstrom, Mark W. Sandstrom

Quality management system, U.S. Geological Survey National Water Quality Laboratory

A quality management system (QMS) is a document that describes the quality policy, system, and practices of an organization. The document may include by reference other publications relating to the laboratory's arrangements.The U.S. Geological Survey QMS describes the policies, objectives, principles, organizational authority, responsibilities, accountability, and implementation plan of the Nation

Widespread detection of N, N-diethyl-m-toluamide in U.S. streams: Comparison with concentrations of pesticides, personal care products, and other organic wastewater compounds

One of the most frequently detected organic chemicals in a nationwide study concerning the effects of wastewater on stream water quality conducted in the year 2000 was the widely used insect repellant N,N-diethyl-m-toluamide (DEET). It was detected at levels of 0.02 μg/L or greater in 73% of the stream sites sampled, with the selection of sampling sites being biased toward streams thought to be su
Authors
Mark W. Sandstrom, D.W. Kolpin, E. M. Thurman, S.D. Zaugg

Glyphosate, other herbicides, and transformation products in Midwestern streams, 2002

 The use of glyphosate has increased rapidly, and there is limited understanding of its environmental fate. The objective of this study was to document the occurrence of glyphosate and the transformation product aminomethylphosphonic acid (AMPA) in Midwestern streams and to compare their occurrence with that of more commonly measured herbicides such as acetochlor, atrazine, and metolachlor. Water
Authors
William A. Battaglin, Dana W. Kolpin, Elisabeth A. Scribner, Kathryn M. Kuivila, Mark W. Sandstrom

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of polycyclic aromatic hydrocarbon compounds in sediment by gas chromatography/mass spectrometry

A method for the determination of 28 polycyclic aromatic hydrocarbons (PAHs) and 25 alkylated PAH homolog groups in sediment samples is described. The compounds are extracted from sediment by solvent extraction, followed by partial isolation using high-performance gel permeation chromatography. The compounds are identified and uantitated using capillary-column gas chromatography/mass spectrometr
Authors
Mary C. Olson, Jana L. Iverson, Edward T. Furlong, Michael P. Schroeder

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of organochlorine pesticides and polychlorinated biphenyls in bottom and suspended sediment by gas chromatography with electron-capture detection

A method applicable for the determination of 19 organochlorine (OC) pesticides, including total toxaphene as a complex mixture, and 3 polychlorinated biphenyl (PCB) mixtures as Aroclor equivalents--Aroclor 1016/1242, 1254, and 1260--in soil, aquatic bottom sediment, and suspended sediment is described. Method performance data are presented. The solvent system is designed to extract simultaneousl
Authors
Mary C. Noriega, Duane S. Wydoski, William T. Foreman

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of organophosphate pesticides in whole water by continuous liquid-liquid extraction and capillary-column gas chromatography with flame photometric detection

A method for the isolation of 20 parent organophosphate pesticides and 5 organophosphate pesticide degradates from natural-water samples is described. Compounds are extracted from water samples with methylene chloride using a continuous liquid-liquid extractor for 6 hours. The solvent is evaporated using heat and a flow of nitrogen to a volume of 1 milliliter and solvent exchanged to ethyl acetate
Authors
Virendra K. Jha, Duane S. Wydoski

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Evaluation of alkaline persulfate digestion as an alternative to Kjeldahl digestion for determination of total and dissolved nitrogen and phosphorus in water

Alkaline persulfate digestion was evaluated and validated as a more sensitive, accurate, and less toxic alternative to Kjeldahl digestion for routine determination of nitrogen and phosphorus in surface- and ground-water samples in a large-scale and geographically diverse study conducted by U.S. Geological Survey (USGS) between October 1, 2001, and September 30, 2002. Data for this study were obtai
Authors
Charles J. Patton, Jennifer R. Kryskalla

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of gasoline oxygenates, selected degradates, and BTEX in water by heated purge and trap/gas chromatography/mass spectrometry

A method for determination of the alkyl ethers u sed as gasoline oxygenates [ethyl tert-butyl ether (ETBE), methyl tert-butyl ether (MTBE), diisopropyl ether (DIPE), and tert-amyl methyl ether (TAME)], some of their main degradates [acetone, methyl acetate, tert-butyl alcohol (tBA), and tert-amyl alcohol (tAA)], and BTEX (benzene, toluene, ethylbenzene, and xylenes) at low concentrations (<5 micro
Authors
Donna L. Rose, Mark W. Sandstrom