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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Slough evolution and legacy mercury remobilization induced by wetland restoration in South San Francisco Bay

Coastal wetlands have a long history of degradation and destruction due to human development. Now recognized as one of the most productive ecosystems in the world, substantial efforts are being made to restore this critical habitat. While wetland restoration efforts are generally viewed as beneficial in terms of providing wildlife habitat and flood control, they are often accompanied by dramatic p
Authors
Amy C. Foxgrover, Mark C. Marvin-DiPasquale, Bruce E. Jaffe, Theresa A. Fregoso

The dual‐domain porosity apparatus: Characterizing dual porosity at the sediment/water interface

The characterization of pore-space connectivity in porous media at the sediment/water interface is critical to understanding contaminant transport and reactive biogeochemical processes in zones of groundwater and surface-water exchange. Previous in situ studies of dual-domain (i.e., mobile/less-mobile porosity) studies have been limited to solute tracer injections at scales of meters to 100s
Authors
Courtney R. Scruggs, Martin A. Briggs, Frederick D. Day-Lewis, Dale D. Werkema, John W. Lane

Rapid pre-concentration of mercury in solids and water for isotopic analysis

The precise quantification of mercury (Hg) stable isotope compositions in low concentration or dilute samples poses analytical challenges due to Hg mass limitations. Common Hg pre-concentration procedures require extended processing times, making rapid Hg stable isotope measurements challenging. Here we present a modified pre-concentration method that combines commonly used Hg reduction and gold t
Authors
Sarah E. Janssen, Ryan F. Lepak, Michael T. Tate, Jacob M. Ogorek, John F. DeWild, Christopher L. Babiarz, James P. Hurley, David P. Krabbenhoft

Identifying natural and anthropogenic variability of uranium at the well scale, Homestake Superfund site, near Milan, New Mexico, USA

The San Mateo Creek Basin in New Mexico, USA is located within the Grants Mineral Belt-an area with numerous uranium (U) ore deposits, mines, and milling operations. Six monitoring wells set in an alluvial aquifer near the Homestake Mining Co. Superfund site in the lower San Mateo Creek Basin were logged with a suite of borehole geophysical tools including spectral gamma-ray (SGR), vertically prof
Authors
Philip T. Harte, Johanna M. Blake, Jonathan V. Thomas, Kent Becher

Critical review: Grand challenges in assessing the adverse effects of contaminants of emerging concern on aquatic food webs

Much progress has been made in the past few decades in understanding the sources, transport, fate, and biological effects of contaminants of emerging concern (CECs) in aquatic ecosystems. Despite these advancements, significant obstacles still prevent comprehensive assessments of the environmental risks associated with the presence of CECs. Many of these obstacles center around the extrapolation o
Authors
Elena Nilsen, Kelly L. Smalling, Lutz Ahrens, Meritxell Gros, Karina S. B. Miglioranza, Yolanda Picó, Heiko L. Schoenfuss

Behavioral effects of copper on larval white sturgeon

Early–life stage white sturgeon are sensitive to copper (Cu), with adverse behavioral responses observed during previous studies. The objectives of the present study were to quantify the effects of Cu exposure on white sturgeon swimming and feeding behaviors and determine their time to response. Larval sturgeon (1–2, 28, or 35 d posthatch [dph]) were exposed to Cu (0.5–8 μg/L) for 4 to 14 d. Abnor
Authors
Holly J. Puglis, Robin Calfee, Edward E. Little

Chlorinated byproducts of neonicotinoids and their metabolites: An unrecognized human exposure potential?

We recently reported the initial discovery of neonicotinoid pesticides in drinking water and their potential for transformation through chlorination and alkaline hydrolysis during water treatment. The objectives of this research were: (1) to determine if neonicotinoid metabolites are relevant to drinking water exposure and (2) to identify the products formed from chlorination of neonicotinoids and
Authors
Kathryn L. Klarich Wong, Danielle T. Webb, Matthew R. Nagorzanski, Dana W. Kolpin, Michelle L. Hladik, David M. Cwiertny, Gregory H. LeFevre

Potential toxicity of complex mixtures in surface waters from a nationwide survey of United States streams: Identifying in vitro bioactivities and causative chemicals

While chemical analysis of contaminant mixtures remains an essential component of environmental monitoring, bioactivity-based assessments using in vitro systems increasingly play a role in the detection of biological effects. Historically, in vitro assessments focused on a few biological pathways, e.g., aryl hydrocarbon receptor (AhR) or estrogen receptor (ER) activities. High-throughput screening
Authors
Brett R. Blackwell, Gerald T. Ankley, Paul M. Bradley, Keith A. Houck, Sergei S. Makarov, Alexander V. Medvedev, Joe Swintek, Daniel L. Villeneuve

UZIG research: Measurement and characterization of unsaturated zone processes under wide-ranging climates and changing conditions

Unsaturated zone properties and processes are central to understanding the interacting effects of land-use change, contamination, and hydroclimate on our ability to grow food, sustain clean water supplies, and minimize loss of life and property. Advances in unsaturated zone science are being achieved through collaborations across traditional boundaries where information from biological, physical,
Authors
Jared J. Trost, Benjamin B. Mirus, Kimberlie Perkins, Wesley R. Henson, John R. Nimmo, Rafael Munoz-Carpena

Efficient hydrogeological characterization of remote stream corridors using drones

This project demonstrates the successful use of small unoccupied aircraft system (sUASs) for hydrogeological characterization of a remote stream reach in a rugged mountain terrain. Thermal infrared, visual imagery, and derived digital surface models are used to inform conceptual models of groundwater/surface‐water exchange and efficiently geolocate zones of preferential groundwater discharge that
Authors
Martin A. Briggs, Cian B. Dawson, Christopher Holmquist-Johnson, Kenneth H. Williams, John W. Lane

Mixed-chemical exposure and predicted effects potential in wadeable southeastern USA streams

Complex chemical mixtures have been widely reported in larger streams but relatively little work has been done to characterize them and assess their potential effects in headwaterstreams. In 2014, the United States Geological Survey (USGS) sampled 54 Piedmont streams over ten weeks and measured 475 unique organic compounds using five analytical methods. Maximum and median exposure conditions were
Authors
Paul M. Bradley, Celeste A. Journey, Jason P. Berninger, Daniel T. Button, Jimmy M. Clark, Steven R. Corsi, Laura A. DeCicco, Kristina G. Hopkins, Bradley J. Huffman, Naomi Nakagaki, Julia E. Norman, Lisa H. Nowell, Sharon L. Qi, Peter C. Van Metre, Ian R. Waite

A diverse suite of pharmaceuticals contaminates stream and riparian food webs

A multitude of biologically active pharmaceuticals contaminate surface waters globally, yet their presence in aquatic food webs remain largely unknown. Here, we show that over 60 pharmaceutical compounds can be detected in aquatic invertebrates and riparian spiders in six streams near Melbourne, Australia. Similar concentrations in aquatic invertebrate larvae and riparian predators suggest direct
Authors
Erinn K. Richmond, Emma J. Rosi, David M. Walters, Jerker Fikk, Stephen K. Hamilton, Tomas Brodin, Anna Sundelin, Michael R. Grace