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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Estimating virus occurrence using Bayesian modeling in multiple drinking water systems of the United States

Drinking water treatment plants rely on purification of contaminated source waters to provide communities with potable water. One group of possible contaminants are enteric viruses. Measurement of viral quantities in environmental water systems are often performed using polymerase chain reaction (PCR) or quantitative PCR (qPCR). However, true values may be underestimated due to challenges involved
Authors
Eunice A. Varughese, Nichole E Brinkman, Emily M Anneken, Jennifer S Cashdollar, G. Shay Fout, Edward T. Furlong, Dana W. Kolpin, Susan T. Glassmeyer, Scott P Keely

Estimating the high-arsenic domestic-well population in the conterminous United States

Arsenic concentrations from 20 450 domestic wells in the U.S. were used to develop a logistic regression model of the probability of having arsenic >10 μg/L (“high arsenic”), which is presented at the county, state, and national scales. Variables representing geologic sources, geochemical, hydrologic, and physical features were among the significant predictors of high arsenic. For U.S. Census bloc
Authors
Joseph D. Ayotte, Laura Medalie, Sharon L. Qi, Lorraine C. Backer, Bernard T. Nolan

Widespread legacy brine contamination from oil production reduces survival of chorus frog larvae

Advances in drilling techniques have facilitated a rapid increase in hydrocarbon extraction from energy shales, including the Williston Basin in central North America. This area overlaps with the Prairie Pothole Region, a region densely populated with wetlands that provide numerous ecosystem services. Historical (legacy) disposal practices often released saline co-produced waters (brines) with hig
Authors
Blake R. Hossack, Holly J. Puglis, William A. Battaglin, Chauncey W. Anderson, R. Ken Honeycutt, Kelly L. Smalling

A comparison of four porewater sampling methods for metal mixtures and dissolved organic carbon and the implications for sediment toxicity evaluations

Evaluations of sediment quality conditions are commonly conducted using whole-sediment chemistry analyses but can be enhanced by evaluating multiple lines of evidence, including measures of the bioavailable forms of contaminants. In particular, porewater chemistry data provide information that is directly relevant for interpreting sediment toxicity data. Various methods for sampling porewater for
Authors
Danielle M. Cleveland, William G. Brumbaugh, Donald D. MacDonald

2.3. Global-scale atmospheric dispersion of microorganisms

This chapter addresses long-range dispersion and the survival of microorganisms across a wide range of altitudes in Earth's atmosphere. Topics include mechanisms of dispersion, survivability of microorganisms known to be associated with long-range transport, natural and artificial sources of bioaerosols, residence time estimation through the use of proxy aerosols, transport and emission models, an
Authors
Dale W. Griffin, Cristina Gonzalez-Martin, C. Hoose, D.J. Smith

Effects of sulfide concentration and dissolved organic matter characteristics on the structure of nanocolloidal metacinnabar

Understanding the speciation of divalent mercury (Hg(II)) in aquatic systems containing dissolved organic matter (DOM) and sulfide is necessary to predict the conversion of Hg(II) to bioavailable methylmercury. We used X-ray absorption spectroscopy to characterize the structural order of mercury in Hg(II)–DOM–sulfide systems for a range of sulfide concentration (1–100 μM), DOM aromaticity (specifi
Authors
Brett Poulin, Chase A. Gerbig, Christopher S. Kim, John P. Stegemeier, Joseph N. Ryan, George R. Aiken

Uptake and disposition of select pharmaceuticals by bluegill exposed at constant concentrations in a flow-through aquatic exposure system

The increasing use of pharmaceuticals has led to their subsequent input into and release from wastewater treatment plants, with corresponding discharge into surface waters that may subsequently exert adverse effects upon aquatic organisms. Although the distribution of pharmaceuticals in surface water has been extensively studied, the details of uptake, internal distribution, and kinetic processing
Authors
Jian-Liang Zhao, Edward T. Furlong, Heiko L. Schoenfuss, Dana W. Kolpin, Kyle L. Bird, David J. Feifarek, Eric A. Schwab, Guang-Guo Ying

Degradation of crude 4-MCHM (4-methylcyclohexanemethanol) in sediments from Elk River, West Virginia

In January 2014, approximately 37 800 L of crude 4-methylcyclohexanemethanol (crude MCHM) spilled into the Elk River, West Virginia. To understand the long-term fate of 4-MCHM, we conducted experiments under environmentally relevant conditions to assess the potential for the 2 primary compounds in crude MCHM (1) to undergo biodegradation and (2) for sediments to serve as a long-term source of 4-MC
Authors
Isabelle M. Cozzarelli, Denise M. Akob, Mary Jo Baedecker, Tracey Spencer, Jeanne B. Jaeschke, Darren S. Dunlap, Adam C. Mumford, Amisha T. Poret-Peterson, Douglas B. Chambers

Effects of an extreme flood on trace elements in river water—From urban stream to major river basin

Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the Sou
Authors
Larry B. Barber, Suzanne Paschke, William A. Battaglin, Chris Douville, Kevin C. Fitzgerald, Steffanie H. Keefe, David A. Roth, Alan M. Vajda

Future research needs involving pathogens in groundwater

Contamination of groundwater by enteric pathogens has commonly been associated with disease outbreaks. Proper management and treatment of pathogen sources are important prerequisites for preventing groundwater contamination. However, non-point sources of pathogen contamination are frequently difficult to identify, and existing approaches for pathogen detection are costly and only provide semi-quan
Authors
Scott A. Bradford, Ronald W. Harvey

Geochemical characterization of groundwater discharging from springs north of the Grand Canyon, Arizona, 2009–2016

A geochemical study was conducted on 37 springs discharging from the Toroweap Formation, Coconino Sandstone, Hermit Formation, Supai Group, and Redwall Limestone north of the Grand Canyon near areas of breccia-pipe uranium mining. Baseline concentrations were established for the elements As, B, Li, Se, SiO2, Sr, Tl, U, and V. Three springs exceeded U.S. Environmental Protection Agency drinking wat
Authors
Kimberly R. Beisner, Fred D. Tillman, Jessica R. Anderson, Ronald C. Antweiler, Donald J. Bills

Density-driven free-convection model for isotopically fractionated geogenic nitrate in sabkha brine

Subsurface brines with high nitrate (NO3−) concentration are common in desert environments as atmospheric nitrogen is concentrated by the evaporation of precipitation and little nitrogen uptake. However, in addition to having an elevated mean concentration of ∼525 mg/L (as N), NO3− in the coastal sabkhas of Abu Dhabi is enriched in 15N (mean δ15N ∼17‰), which is an enigma. A NO3− solute mass balan
Authors
Warren W. Wood, John K. Böhlke