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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Occurrence of neonicotinoid insecticides in finished drinking water and fate during drinking water treatment

Neonicotinoid insecticides are widespread in surface waters across the agriculturally-intensive Midwestern US. We report for the first time the presence of three neonicotinoids in finished drinking water and demonstrate their general persistence during conventional water treatment. Periodic tap water grab samples were collected at the University of Iowa over seven weeks in 2016 (May-July) after ma
Authors
Kathryn L. Klarich, Nicholas C. Pflug, Eden M. DeWald, Michelle L. Hladik, Dana W. Kolpin, David M. Cwiertny, Gergory H. LeFevre

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine, Arizona (USA)

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area
Authors
Kimberly R. Beisner, Nicholas V. Paretti, Fred D. Tillman, David L. Naftz, Donald J. Bills, Katherine Walton-Day, Tanya J. Gallegos

Processing protocol for soil samples potentially contaminated with Bacillus anthracis spores [HS7.52.02 - 514]

This protocol describes the processing steps for 45 g and 9 g soil samples potentially contaminated with Bacillus anthracis spores. The protocol is designed to separate and concentrate the spores from bulk soil down to a pellet that can be used for further analysis. Soil extraction solution and mechanical shaking are used to disrupt soil particle aggregates and to aid in the separation of spores f
Authors
Erin E. Silvestri, Dale W. Griffin

Water-quality, bed-sediment, and biological data (October 2014 through September 2015) and statistical summaries of data for streams in the Clark Fork Basin, Montana

Water, bed sediment, and biota were sampled in selected streams from Butte to near Missoula, Montana, as part of a monitoring program in the upper Clark Fork Basin of western Montana. The sampling program was led by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to characterize aquatic resources in the Clark Fork Basin, with emphasis on trace elements ass
Authors
Kent A. Dodge, Michelle I. Hornberger, Matthew A. Turner

Improved vertical streambed flux estimation using multiple diurnal temperature methods in series

Analytical solutions that use diurnal temperature signals to estimate vertical fluxes between groundwater and surface water based on either amplitude ratios (Ar) or phase shifts (Δϕ) produce results that rarely agree. Analytical solutions that simultaneously utilize Ar and Δϕ within a single solution have more recently been derived, decreasing uncertainty in flux estimates in some applications. Be
Authors
Dylan J. Irvine, Martin A. Briggs, Ian Cartwright, Courtney R. Scruggs, Laura K. Lautz

Pharmaceuticals and personal care products (PPCPs) are ecological disrupting compounds (EcoDC)

Pharmaceuticals and personal care products (PPCPs) are ubiquitous in freshwater ecosystems worldwide and are recognized as contaminants of concern. Currently, contaminants of concern are classified for their persistence, bioaccumulation, and toxicity (PBT criteria). PPCPs are not classified as persistent organic pollutants (POPs), although some PPCPs share characteristics similar to POPs. For exam
Authors
Erinn Richmond, Michael R. Grace, John R. Kelly, Andrew Reisinger, Emma J. Rosi, David M. Walters

Assessment of dreissenid biodeposits as a potential food resource for invasive Asian carp

Silver carp (Hypophthalmichthys molitrix) and bighead carp (H. nobilis) are poised to invade the Laurentian Great Lakes. Zebra mussels (Dreissena polymorpha) and quagga mussels (D. rostriformis bugensis) have shifted nutrient pathways towards the benthos, partly through deposition of feces and rejected food particles called biodeposits. When biodeposit material was fed to bighead and silver carp,
Authors
Karl R. Anderson, Duane Chapman, Cari-Ann Hayer

Exposure to the contraceptive progestin, gestodene, alters reproductive behavior, arrests egg deposition, and masculinizes development in the fathead minnow (Pimephales promelas)

Endogenous progestogens and pharmaceutical progestins enter the environment through wastewater treatment plant effluent and agricultural field runoff. Lab studies demonstrate strong, negative exposure effects of these chemicals on aquatic vertebrate reproduction. Behavior can be a sensitive, early indicator of exposure to environmental contaminants associated with altered reproduction yet is rarel
Authors
Tyler E. Frankel, Michael T. Meyer, Dana W. Kolpin, Amanda B. Gillis, David A. Alvarez, Edward F. Orlando

Molecular-level evidence provided by ultrahigh resolution mass spectrometry for oil-derived doc in groundwater at Bemidji, Minnesota

Dissolved organic matter samples extracted from ground water at the USGS Bemidji oil spill site in Minnesota were investigated by ultrahigh resolution mass spectrometry. Principle component analysis (PCA) of the elemental composition assignments of the samples showed that the score plots for the contaminated sites were well separated from those for the uncontaminated sites. Additionally, spectra o
Authors
Ananna Islam, Arif Ahmed, Manhoi Hur, Kevin A. Thorn, Sunghwan Kim

Prediction of fish and sediment mercury in streams using landscape variables and historical mining

Widespread mercury (Hg) contamination of aquatic systems in the Sierra Nevada of California, U.S., is associated with historical use to enhance gold (Au) recovery by amalgamation. In areas affected by historical Au mining operations, including the western slope of the Sierra Nevada and downstream areas in northern California, such as San Francisco Bay and the Sacramento River–San Joaquin River Del
Authors
Charles N. Alpers, Julie L. Yee, Joshua T. Ackerman, James L. Orlando, Darrell G. Slotton, Mark C. Marvin-DiPasquale

Nitrapyrin in streams: The first study documenting off-field transport of a nitrogen stabilizer compound

Nitrapyrin is a bactericide that is co-applied with fertilizer to prevent nitrification and enhance corn yields. While there have been studies of the environmental fate of nitrapyrin, there is no documentation of its off-field transport to streams. In 2016, 59 water samples from 11 streams across Iowa were analyzed for nitrapyrin and its degradate, 6-chloropicolinic acid (6-CPA), along with three
Authors
Emily Woodward, Michelle Hladik, Dana W. Kolpin

Occurrence of triclocarban and triclosan in an agro-ecosystem following application of biosolids

Triclocarban (TCC) and triclosan (TCS), two of the most commonly used antimicrobial compounds, can be introduced into ecosystems by applying wastewater treatment plant biosolids to agricultural fields. Concentrations of TCC and TCS were measured in different trophic levels within a terrestrial food web encompassing land-applied biosolids, soil, earthworms (Lumbricus), deer mice (Peromyscus manicul
Authors
Jessica J. Sherburne, Amanda M. Anaya, Kimberly J. Fernie, Jennifer S. Forbey, Edward T. Furlong, Dana W. Kolpin, Alfred M. Dufty, Chad A. Kinney