Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 3746
A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models
A controlled field pilot has been developed in Bozeman, Montana, USA, to study near surface CO2 transport and detection technologies. A slotted horizontal well divided into six zones was installed in the shallow subsurface. The scale and CO2 release rates were chosen to be relevant to developing monitoring strategies for geological carbon storage. The field site was characterized before injection,
Authors
L.H. Spangler, L.M. Dobeck, K.S. Repasky, A.R. Nehrir, S.D. Humphries, C.J. Keith, J.A. Shaw, J.H. Rouse, A.B. Cunningham, S.M. Benson, C.M. Oldenburg, J.L. Lewicki, A.W. Wells, J.R. Diehl, B.R. Strazisar, J.E. Fessenden, T.A. Rahn, J.E. Amonette, J.L. Barr, W.L. Pickles, J.D. Jacobson, E. A. Silver, E.J. Male, H.W. Rauch, K.S. Gullickson, R. Trautz, Yousif K. Kharaka, J. Birkholzer, L. Wielopolski
Phosphorus dynamics in soils irrigated with reclaimed waste water or fresh water - A study using oxygen isotopic composition of phosphate
Transformations of phosphate (Pi) in different soil fractions were tracked using the stable isotopic composition of oxygen in phosphate (δ18Op) and Pi concentrations. Clay soil from Israel was treated with either reclaimed waste water (secondary, low grade) or with fresh water amended with a chemical fertilizer of a known isotopic signature. Changes of δ18Opand Pi within different soil fractions,
Authors
I. Zohar, A. Shaviv, M. Young, Carol Kendall, Steven R. Silva, A. Paytan
Anthropogenic tracers, endocrine disrupting chemicals, and endocrine disruption in Minnesota lakes
Concentrations of endocrine disrupting chemicals and endocrine disruption in fish were determined in 11 lakes across Minnesota that represent a range of trophic conditions and land uses (urban, agricultural, residential, and forested) and in which wastewater treatment plant discharges were absent. Water, sediment, and passive polar organic integrative samplers (POCIS) were analyzed for steroidal h
Authors
J.H. Writer, L. B. Barber, G.K. Brown, Howard E. Taylor, R.L. Kiesling, M.L. Ferrey, N.D. Jahns, S.E. Bartell, H.L. Schoenfuss
A methodology for ecosystem-scale modeling of selenium
The main route of exposure for selenium (Se) is dietary, yet regulations lack biologically based protocols for evaluations of risk. We propose here an ecosystem-scale model that conceptualizes and quantifies the variables that determinehow Se is processed from water through diet to predators. This approach uses biogeochemical and physiological factors from laboratory and field studies and consider
Authors
Theresa S. Presser, Samuel N. Luoma
Hurricane storm surge and amphibian communities in coastal wetlands of northwestern Florida
Isolated wetlands in the Southeastern United States are dynamic habitats subject to fluctuating environmental conditions. Wetlands located near marine environments are subject to alterations in water chemistry due to storm surge during hurricanes. The objective of our study was to evaluate the effect of storm surge overwash on wetland amphibian communities. Thirty-two wetlands in northwestern Flor
Authors
Margaret S. Gunzburger, William B. Hughes, William J. Barichivich, Jennifer S. Staiger
Development of a new toxic-unit model for the bioassessment of metals in streams
Two toxic-unit models that estimate the toxicity of trace-metal mixtures to benthic communities were compared. The chronic criterion accumulation ratio (CCAR), a modification of biotic ligand model (BLM) outputs for use as a toxic-unit model, accounts for the modifying and competitive influences of major cations (Ca2+, Mg2+, Na+, K+, H+), anions (HCO3−, CO32−,SO42−, Cl−, S2−) and dissolved organic
Authors
Travis S. Schmidt, W.H. Clements, K.A. Mitchell, Stanley E. Church, Richard B. Wanty, David L. Fey, Philip L. Verplanck, Carma A. San Juan
Natural chlorate in the environment: Application of a new IC-ESI/MS/MS method with a Cl18O3- internal standard
A new ion chromatography electrospray tandem mass spectrometry (IC-ESI/MS/MS) method has been developed for quantification and confirmation of chlorate (ClO3−) in environmental samples. The method involves the electro-chemical generation of isotopically labeled chlorate internal standard (Cl18O3−) using 18O water (H218O). The standard was added to all samples prior to analysis thereby minimizing t
Authors
Balaji Rao, Paul B. Hatzinger, John K. Böhlke, Neil C. Sturchio, Brian J. Andraski, Frank D. Eckardt, W. Andrew Jackson
An approach to quantify sources, seasonal change, and biogeochemical processes affecting metal loading in streams: Facilitating decisions for remediation of mine drainage
Historical mining has left complex problems in catchments throughout the world. Land managers are faced with making cost-effective plans to remediate mine influences. Remediation plans are facilitated by spatial mass-loading profiles that indicate the locations of metal mass-loading, seasonal changes, and the extent of biogeochemical processes. Field-scale experiments during both low- and high-flo
Authors
B. A. Kimball, R.L. Runkel, K. Walton-Day
Redox transformations and transport of cesium and iodine (-1, 0, +5) in oxidizing and reducing zones of a sand and gravel aquifer
Tracer tests were performed in distinct biogeochemical zones of a sand and gravel aquifer in Cape Cod, MA, to study the redox chemistry (I) and transport (Cs, I) of cesium and iodine in a field setting. Injection of iodide (I -) into an oxic zone of the aquifer resulted in oxidation of I - to molecular iodine (I2) and iodate (IO3-) over transport distances of several meters. Oxidation is attribute
Authors
Patricia M. Fox, Douglas B. Kent, James A. Davis
Microbial arsenic metabolism: New twists on an old poison
Phylogenetically diverse microorganisms metabolize arsenic despite its toxicity and are part of its robust iogeochemical cycle. Respiratory arsenate reductase is a reversible enzyme, functioning in some microbes as an arsenate reductase but in others as an arsenite oxidase. As(III) can serve as an electron donor for anoxygenic photolithoautotrophy and chemolithoautotrophy. Organoarsenicals, such a
Authors
J.F. Stolz, P. Basu, Ronald S. Oremland
Mineralogical and chemical characteristics of some natural jarosites
This paper presents a detailed study of the mineralogical, microscopic, thermal, and spectral characteristics of jarosite and natrojarosite minerals. Systematic mineralogic and chemical examination of a suite of 32 natural stoichiometric jarosite and natrojarosite samples from diverse supergene and hydrothermal environments indicates that there is only limited solid solution between Na and K at lo
Authors
George A. Desborough, Kathleen S. Smith, Heather A. Lowers, Gregg A. Swayze, Jane M. Hammarstrom, Sharon F. Diehl, Reinhard W. Leinz, Rhonda L. Driscoll
Book review: Thermodynamics and kinetics of water-rock interaction
No abstract available.
Authors
D. Kirk Nordstrom