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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Mortality of centrarchid fishes in the Potomac drainage: Survey results and overview of potential contributing factors

Skin lesions and spring mortality events of smallmouth bass Micropterus dolomieu and selected other species were first noted in the South Branch of the Potomac River in 2002. Since that year morbidity and mortality have also been observed in the Shenandoah and Monocacy rivers. Despite much research, no single pathogen, parasite, or chemical cause for the lesions and mortality has been identified.
Authors
Vicki Blazer, Luke R. Iwanowicz, Clifford E. Starliper, Steven D. Zaugg, Mark R. Burkhardt, P. Barbash, J.D. Hedrick, S.J. Reeser, J.E. Mullican, J. Kelble

Caution on the use of liquid nitrogen traps in stable hydrogen isotope-ratio mass spectrometry

An anomalous stable hydrogen isotopic fractionation of 4 ‰ in gaseous hydrogen has been correlated with the process of adding liquid nitrogen (LN2) to top off the dewar of a stainless-steel water trap on a gaseous hydrogen-water platinum equilibration system. Although the cause of this isotopic fractionation is unknown, its effect can be mitigated by (1) increasing the capacity of any dewars so th
Authors
Tyler B. Coplen, Haiping Qi

Measurement of dissolved organic matter fluorescense in aquatic environments: An interlaboratory comparison

The fluorescent properties of dissolved organic matter (DOM) are often studied in order to infer DOM characteristics in aquatic environments, including source, quantity, composition, and behavior. While a potentially powerful technique, a single widely implemented standard method for correcting and presenting fluorescence measurements is lacking, leading to difficulties when comparing data collect
Authors
Kathleen R. Murphy, Kenna D. Butler, Robert G. M. Spencer, Colin A. Stedmon, Jennifer R. Boehme, George R. Aiken

Stimulation of methane generation from nonproductive coal by addition of nutrients or a microbial consortium

Biogenic formation of methane from coal is of great interest as an underexploited source of clean energy. The goal of some coal bed producers is to extend coal bed methane productivity and to utilize hydrocarbon wastes such as coal slurry to generate new methane. However, the process and factors controlling the process, and thus ways to stimulate it, are poorly understood. Subbituminous coal from
Authors
Elizabeth J.P. Jones, Mary A. Voytek, M.D. Corum, William H. Orem

A role for analytical chemistry in advancing our understanding of the occurrence, fate, and effects of Corexit Oil Dispersants

On April 24, 2010, the sinking of the Deepwater Horizon oil rig resulted in the release of oil into the Gulf of Mexico. As of July 19, 2010, the federal government's Deepwater Horizon Incident Joint Information Center estimates the cumulative range of oil released is 3,067,000 to 5,258,000 barrels, with a relief well to be completed in early August. By comparison, the Exxon Valdez oil spill releas
Authors
Ben Place, Brian Anderson, Abdou Mekebri, Edward T. Furlong, James L. Gray, Ron Tjeerdema, Jennifer Field

Source and fate of inorganic solutes in the Gibbon River, Yellowstone National Park, Wyoming, USA. II. Trace element chemistry

The Gibbon River in Yellowstone National Park receives inflows from several geothermal areas, and consequently the concentrations of many trace elements are elevated compared to rivers in non-geothermal watersheds. Water samples and discharge measurements were obtained from the Gibbon River and its major tributaries near Norris Geyser Basin under the low-flow conditions of September 2006 allowing
Authors
R. Blaine McCleskey, D. Kirk Nordstrom, David D. Susong, James W. Ball, Howard E. Taylor

Total mercury, methylmercury, and selected elements in soils of the Fishing Brook watershed, Hamilton County, New York, and the McTier Creek watershed, Aiken County, South Carolina, 2008

Mercury is an element of on-going concern for human and aquatic health. Mercury sequestered in upland and wetland soils represents a source that may contribute to mercury contamination in sensitive ecosystems. An improved understanding of mercury cycling in stream ecosystems requires identification and quantification of mercury speciation and transport dynamics in upland and wetland soils within a
Authors
Laurel G. Woodruff, William F. Cannon, Christopher D. Knightes, Francis H. Chapelle, Paul M. Bradley, Douglas A. Burns, Mark E. Brigham, Mark A. Lowery

Applying dispersive changes to Lagrangian particles in groundwater transport models

Method-of-characteristics groundwater transport models require that changes in concentrations computed within an Eulerian framework to account for dispersion be transferred to moving particles used to simulate advective transport. A new algorithm was developed to accomplish this transfer between nodal values and advecting particles more precisely and realistically compared to currently used method
Authors
Leonard F. Konikow

Zn and Cu isotopes as tracers of anthropogenic contamination in a sediment core from an urban lake

In this work, we use stable Zn and Cu isotopes to identify the sources and timing of the deposition of these metals in a sediment core from Lake Ballinger near Seattle, Washington, USA. The base of the Lake Ballinger core predates settlement in the region, while the upper sections record the effects of atmospheric emissions from a nearby smelter and rapid urbanization of the watershed. δ66Zn and δ
Authors
Anita Thapalia, David M. Borrok, Peter C. Van Metre, MaryLynn Musgrove, Edward R. Landa

Flood hydrology and methylmercury availability in Coastal Plain rivers

Mercury (Hg) burdens in top-predator fish differ substantially between adjacent South Carolina Coastal Plain river basins with similar wetlands coverage. In the Congaree River, floodwaters frequently originate in the Blue Ridge and Piedmont regions, where wetlands coverage and surface water dissolved methylmercury (MeHg) concentrations are low. Piedmont-driven flood events can lead to downward hyd
Authors
Paul M. Bradley, Celeste A. Journey, Francis H. Chapelle, Mark A. Lowery, Paul Conrads

Hydrogeologic framework of fractured sedimentary rock, Newark Basin, New Jersey

The hydrogeologic framework of fractured sedimentary bedrock at the former Naval Air Warfare Center (NAWC), Trenton, New Jersey, a trichloroethylene (TCE)-contaminated site in the Newark Basin, is developed using an understanding of the geologic history of the strata, gamma-ray logs, and rock cores. NAWC is the newest field research site established as part of the U.S. Geological Survey Toxic Subs
Authors
Pierre J. Lacombe, William C. Burton

Assessment of PDMS-water partition coefficients: implications for passive environmental sampling of hydrophobic organic compounds

Solid-phase microextraction (SPME) has shown potential as an in situ passive-sampling technique in aquatic environments. The reliability of this method depends upon accurate determination of the partition coefficient between the fiber coating and water (Kf). For some hydrophobic organic compounds (HOCs), Kf values spanning 4 orders of magnitude have been reported for polydimethylsiloxane (PDMS) an
Authors
Erica L. DiFilippo, Robert P. Eganhouse