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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3746

Enzymatic and histopathologic biomarkers as indicators of contaminant exposure and effect in Asian clam (Potamocorbula amurensis)

Enzymatic and histopathologic alterations of the digestive gland, gill, gonad, and kidney were studied in Asian clam (Potamocorbula amurensis) in April, 1997 from each of four United States Geological Survey (USGS) stations in the San Francisco Estuary. Stations were selected based on differing body burdens of metallic contaminants in clams (Stn 4.1>6.1>8.1>12.5) observed over 7 years. Because no
Authors
S.J. Teh, S.L. Clark, C. L. Brown, S. N. Luoma, D.E. Hinton

Occurrence and transport of acetochlor in streams of the Mississippi River Basin

The herbicide acetochlor [2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl) acetamide] was first used on corn (Zea mays L.) in the USA during the growing season of 1994. By 1996, it was the third most heavily used corn herbicide in the midwestern USA. During the growing season of 1997, 78% of 375 samples collected at 32 stream sites in the Mississippi River Basin contained detectable concentrat
Authors
G. M. Clark, D. A. Goolsby

Characterizing a sewage plume using the 3H-3He dating technique

An extensive 3H-3He study was performed to determine detailed characteristics of a regional flow system and a sewage plume over a distance of 4 km in a sand and gravel aquifer at Otis Air Base in Falmouth, Massachusetts. 3H-3He ages increase with depth in individual piezometer clusters and with distance along flowpaths. However, the age gradient with depth (Δt/Δz) is smaller in the plume than that
Authors
Stephanie Dunkle Shapiro, Denis LeBlanc, Peter Schlosser, Andrea Ludin

Bacterial respiration of arsenic and selenium

Oxyanions of arsenic and selenium can be used in microbial anaerobic respiration as terminal electron acceptors. The detection of arsenate and selenate respiring bacteria in numerous pristine and contaminated environments and their rapid appearance in enrichment culture suggest that they are widespread and metabolically active in nature. Although the bacterial species that have been isolated and c
Authors
J.F. Stolz, R.S. Oremland

Mercury methylation in periphyton of the Florida Everglades

Trophic accumulation of mercury (Hg) in aquatic ecosystems is of global concern due to health effects associated with eating fish with elevated Hg levels. The methylated form of Hg bioaccumulates so it is important to understand how inorganic Hg is transformed to methylmercury in the environment. Here, a new site for Hg methylation, the periphyton communities that are prevalent in the Florida Ever
Authors
L.B. Cleckner, C.C. Gilmour, J.P. Hurley, D. P. Krabbenhoft

Importance of microscopy in durability studies of solidified and stabilized contaminated soils

Solidification/stabilization (S/S) is recognized by the U.S. EPA as a best demonstrated available technology for the containment of contaminated soils and other hazardous wastes that cannot be destroyed by chemical, thermal, or biological means. Despite the increased use of S/S technologies, little research has been conducted on the weathering and degradation of solidified and stabilized wastes on
Authors
I. Klich, L.P. Wilding, L.R. Drees, E. R. Landa

Role for acetotrophic methanogens in methanogenic biodegradation of vinyl chloride

Under methanogenic conditions, stream-bed sediment microorganisms rapidly degraded [1,2-14C]vinyl chloride to 14CH4 and 14CO2. Amendment with 2-bromoethanesulfonic acid eliminated 14CH4 production and decreased 14CO2 recovery by an equal molar amount. Results obtained with [14C]ethene, [14C]acetate, or 14CO2 as substrates indicated that acetotrophic methanogens were responsible for the production
Authors
Paul M. Bradley, Francis H. Chapelle

Selenium isotope ratios as indicators of selenium sources and oxyanion reduction

Selenium stable isotope ratio measurements should serve as indicators of sources and biogeochemical transformations of Se. We report measurements of Se isotope fractionation during selenate reduction, selenite sorption, oxidation of reduced Se in soils, and Se volatilization by algae and soil samples. These results, combined with previous work with Se isotopes, indicate that reduction of soluble o
Authors
T. M. Johnson, M.J. Herbel, T.D. Bullen, P.T. Zawislanski

Robowell: An automated process for monitoring ground water quality using established sampling protocols

Robowell is an automated process for monitoring selected ground water quality properties and constituents by pumping a well or multilevel sampler. Robowell was developed and tested to provide a cost-effective monitoring system that meets protocols expected for manual sampling. The process uses commercially available electronics, instrumentation, and hardware, so it can be configured to monitor gro
Authors
G.E. Granato, K.P. Smith

Molecular aggregation of humic substances

Humic substances (HS) form molecular aggregates in solution and on mineral surfaces. Elucidation of the mechanism of formation of these aggregates is important for an understanding of the interactions of HS in soils arid natural waters. The HS are formed mainly by enzymatic depolymerization and oxidation of plant biopolymers. These reactions transform the aromatic and lipid plant components into a
Authors
Robert L. Wershaw

Agrichemicals in ground water of the midwestern USA: Relations to soil characteristics

A comprehensive set of soil characteristics were examined to determine the effect of soil on the transport of agrichemicals to ground water. This paper examines the relation of local soil characteristics to concentrations and occurrence of nitrate, atrazine (2-chloro-4 ethylamino-6-isopropylamino-s-trazine), and atrazine residue [atrazine + deethylatrazine (2-amino-4-chloro-6-isopropylamino-s-tria
Authors
M. R. Burkart, D.W. Kolpin, R.J. Jaquis, K.J. Cole

Simultaneous reduction of nitrate and selenate by cell suspensions of selenium-respiring bacteria

Washed-cell suspensions of Sulfurospirillum barnesiireduced selenate [Se(VI)] when cells were cultured with nitrate, thiosulfate, arsenate, or fumarate as the electron acceptor. When the concentration of the electron donor was limiting, Se(VI) reduction in whole cells was approximately fourfold greater in Se(VI)-grown cells than was observed in nitrate-grown cells; correspondingly, nitrate reducti
Authors
R.S. Oremland, J.S. Blum, A.B. Bindi, P.R. Dowdle, M. Herbel, J.F. Stolz