Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 4094
Assessing uranium and select trace elements associated with breccia pipe uranium deposits in the Colorado River and main tributaries in Grand Canyon, USA
Assessing chemical loading from streams in remote, difficult-to-access watersheds is challenging. The Grand Canyon area in northern Arizona, an international tourist destination and sacred place for many Native Americans, is characterized by broad plateaus divided by canyons as much as two-thousand meters deep and hosts some of the highest-grade uranium deposits in the U.S. From 2015–2018 major su
Authors
Fred D. Tillman, Jessica R. Anderson, Joel A. Unema, Thomas Chapin
Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota
A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This additional remedi
Authors
Geoffrey N. Delin, William N. Herkelrath, Jared J. Trost
Transport and speciation of uranium in groundwater-surface water systems impacted by legacy milling operations
Growing worldwide concern over uranium contamination of groundwater resources has placed an emphasis on understanding uranium transport dynamics and potential toxicity in groundwater-surface water systems. In this study, we utilized novel in-situ sampling methods to establish the location and magnitude of contaminated groundwater entry into a receiving surface water environment, and to investigate
Authors
Patrick A. Byrne, Christopher C. Fuller, David L. Naftz, Robert L. Runkel, Niklas J Lehto, William L Dam
Differences in neonicotinoid and metabolite sorption to activated carbon are driven by alterations to the insecticidal pharmacophore
Widespread application of neonicotinoids has led to their proliferation in waters. Despite low neonicotinoid hydrophobicity, our prior studies implicated granular activated carbon (GAC) in neonicotinoid removal. Based on known receptor binding characteristics, we hypothesized that the insecticidal pharmacophore influences neonicotinoid sorption. Our objectives were to illuminate drivers of neonico
Authors
Danielle T. Webb, Matthew R. Nagorzanski, Megan M Powers, David M. Cwiertny, Michelle Hladik, Gregory H. LeFevre
Geochemical and geophysical indicators of oil and gas wastewater can trace potential exposure pathways following releases to surface waters
Releases of oil and gas (OG) wastewaters can have complex effects on stream-water quality and downstream organisms, due to sediment-water interactions and groundwater/surface water exchange. Previously, elevated concentrations of sodium (Na), chloride (Cl), barium (Ba), strontium (Sr), and lithium (Li), and trace hydrocarbons were determined to be key markers of OG wastewater releases when combine
Authors
Isabelle M. Cozzarelli, Douglas B. Kent, Martin A. Briggs, Mark A Engle, Adam Benthem, Katherine Skalak, Adam Mumford, Jeanne B. Jaeschke, Aida Farag, John W. Lane, Denise M. Akob
Groundwater discharges as a source of phytoestrogens and other agriculturally derived contaminants to streams
Groundwater discharge zones in streams are important habitats for aquatic organisms. The use of discharge zones for thermal refuge and spawning by fish and other biota renders them susceptible to potential focused discharge of groundwater contamination. Currently, there is a paucity of information about discharge zones as a potential exposure pathway of chemicals to stream ecosystems. Using therma
Authors
Tyler J. Thompson, Martin A. Briggs, Patrick J. Phillips, Vicki S. Blazer, Kelly L. Smalling, Dana W. Kolpin, Tyler Wagner
Effects of early life stage exposure of largemouth bass to atrazine or a model estrogen (17α-ethinylestradiol)
Endocrine disrupting contaminants are of continuing concern for potentially contributing to reproductive dysfunction in largemouth and smallmouth bass in the Chesapeake Bay watershed (CBW) and elsewhere. Exposures to atrazine (ATR) have been hypothesized to have estrogenic effects on vertebrate endocrine systems. The incidence of intersex in male smallmouth bass from some regions of CBW has been c
Authors
Jessica Kristin Leet, Catherine A. Richter, Robert S. Cornman, Jason P. Berninger, Ramji K. Bhandari, Diane K. Nicks, James L. Zajicek, Vicki S. Blazer, Donald E. Tillitt
Occurrence and spatiotemporal dynamics of pharmaceuticals in a temperate-region wastewater effluent-dominated stream: Variable inputs and differential attenuation yield evolving complex exposure mixtures
Effluent-dominated streams are becoming increasingly common in temperate regions and generate complex pharmaceutical mixture exposure conditions that may impact aquatic organisms via drug–drug interactions. Here, we quantified spatiotemporal pharmaceutical exposure concentrations and composition mixture dynamics during baseflow conditions at four sites in a temperate-region effluent-dominated stre
Authors
Hui Zhi, Dana W. Kolpin, R. D. Klaper, Luke R. Iwanowicz, Shannon M. Meppelink, Gregory H. LeFevre
Hydrocarbons to carboxyl-rich alicyclic molecules: A continuum model to describe biodegradation of petroleum-derived dissolved organic matter in contaminated groundwater plumes
Relationships between dissolved organic matter (DOM) reactivity and chemical composition in a groundwater plume containing petroleum-derived DOM (DOMHC) were examined by quantitative and qualitative measurements to determine the source and chemical composition of the compounds that persist downgradient. Samples were collected from a transect down the core of the plume in the direction of groundwat
Authors
David C. Podgorski, Phoebe Zito, Anne M. Kellerman, Barbara A. Bekins, Isabelle M. Cozzarelli, Donald F. Smith, Xiaoyan Cao, Klaus Schmidt-Rohr, Sasha Wagner, Aron Stubbins, Robert G. M. Spencer
Endocrine and physiological responses of hatchling American kestrels (Falco sparverius) following embryonic exposure to technical short-chain chlorinated paraffins (C10-13)
Short chain chlorinated paraffins (SCCPs) are complex mixtures of polychlorinated n-alkanes, shown to bioaccumulate but with unknown effects in wild birds. The present study examined development-related effects of SCCPs on captive American kestrels (Falco sparverius) treated in ovo on embryonic day (ED) 5 by injection with technical Chloroparaffin® (C10-13, 55.5% Cl) at environmentally relevant no
Authors
Kim J. Fernie, Natalie K. Karouna-Renier, R. J. Letcher, Sandra L. Schultz, L. E. Peters, V. Palace, Paula F. P. Henry
Endocrine disrupting activities and geochemistry of water resources associated with unconventional oil and gas activity
The rise of hydraulic fracturing and unconventional oil and gas (UOG) exploration in the United States has increased public concerns for water contamination induced from hydraulic fracturing fluids and associated wastewater spills. Herein, we collected surface and groundwater samples across Garfield County, Colorado, a drilling-dense region, and measured endocrine bioactivities, geochemical tracer
Authors
Christopher D. Kassotis, Jennifer S. Harkness, Phuc H. Vo, Danh C. Vu, Kate Hoffman, Katelyn M. Cinnamon, Jennifer N. Cornelius-Green, Avner Vengosh, Chung-Ho Lin, Donald E. Tillitt, Robin L. Kruse, Jane A. McElroy, Susan C. Nagel
Rapid-assessment test strips: Effectiveness forcyanotoxin monitoring in a northern temperate lake
Precise and rapid methods of determining toxin levels are needed in lakes used for recreation and drinking water to facilitate a quick risk assessment during cyanobacteria blooms. Therefore, we evaluated rapid-assessment test strips, a newer technology for estimating the toxicity of cyanobacterial blooms, in Kabetogama Lake, a popular recreational area of Voyageurs National Park in northern Minnes
Authors
Jaime F. LeDuc, Victoria Christensen, Ryan P. Maki